Abstract
A kind of novel mesoporous, electrochemical active material, amorphous MnO2 has been synthesized by an improved reduction reaction and using supramolecular as template. The synthesized sample was characterized physically by thermogravimetric analysis, X-ray diffraction, transmission electron microscope (TEM), and Brunauer–Emmett–Teller (BET) surface area measurement, respectively. Electrochemical characterization was performed using cyclic voltammetry and chronopotentiometry in 2 mol/l KOH aqueous solution electrolyte. The results of BET and TEM analysis indicated that supramolecular template plays an important role in the process of big specific surface area mesoporous material forming. After sintering at 200 °C, the sample still remained an amorphous structure, and its specific capacitance reached 298.7 F/g and presented a very stable capacitance after 500 cycles. In addition, the electrochemical process, such as ion transfer and electrical condition, was also investigated with electrochemical impedance spectroscopy.
Similar content being viewed by others
References
Srinivasan V, Weinder JW (2000) J Electrochem Soc 147:880
Lin C, Ritter JA, Popov BN (1998) J Electrochem Soc 145:4097
Hu CC, Tsou TW (2003) J Power Sources 115:179
Wu MQ, Snook GA, Chen GZ, Fray DJ (2004) Electrochem Commun 6:499
Reddy RN, Reddy RG (2003) J Power Sources 124:330
Long JW, Young AL, Rolison DR (2003) J Electrochem Soc 150:A1161
Moore TE, Ellis M, Selwood PW (1950) J Am Chem Soc 72:856
Pang SC, Anderson MA, Chapman TW (2000) J Electrochem Soc 147:444
WangYQ, Yin LX, Palchik O, Hacohen YR, Koitypin Y, Gedanken A (2001) Langmuir 17:4131
Lee B, Lu D, Kondo JN, Domen K (2002) J Am Chem Soc 124:11256
Reddy RN, Reddy RG (2004) J Power Sources 132:315
Jiang JH, Kucernak A (2002) Electrochim Acta 47:2381
Takahashi T (1981) Electrochim Acta 26:1467
Kim H, Popov BN (2003) J Electrochem Soc 150:D56
Messaoudi B, Joiret S, Keddam M, Takenouti H (2001) Electrochim Acta 46:2487
Zhang SS, Xu K, Jow TR (2004) Electrochim Acta 49:1057
Bao SJ, Liang YY, Zhou WJ, He BL, Li HL (2006) J Power Sources 154:239
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xu, MW., Zhao, DD., Bao, SJ. et al. Mesoporous amorphous MnO2 as electrode material for supercapacitor. J Solid State Electrochem 11, 1101–1107 (2007). https://doi.org/10.1007/s10008-006-0246-4
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10008-006-0246-4