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Simultaneous voltammetry of paracetamol, ascorbic acid, and codeine on a palladium-plated aluminum electrode: oxidation pathway and kinetics

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Abstract

In the present work, the aluminum electrode surface was modified with a thin layer of palladium by dipping its polished surface in a 25% ammonia solution of PdCl2. The electrocatalytic ability of the modified electrode towards the paracetamol (PCT), ascorbic acid (AA), and codeine (CO) oxidation was investigated using cyclic voltammetry, chronoamperometry. The number of electrons for rate-determining step and diffusion coefficient of PCT, AA, and CO were determined. The electro-oxidation pathway and kinetics, including transfer coefficient α and diffusion coefficient D, are estimated. The results indicated that the simultaneous voltammetry of the three compounds was possible in a mixture solution.

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Authors and Affiliations

  1. Electroanalytical Chemistry Laboratory, Faculty of Chemistry, University of Tabriz, Bd. 29 Bahman, Tabriz, Iran

    Mohammad Hossein Pournaghi-Azar, Shahla Kheradmandi & Afsaneh Saadatirad

  2. Center of Excellence of New Materials and Clean Chemistry, University of Tabriz, Tabriz, Iran

    Mohammad Hossein Pournaghi-Azar

Authors
  1. Mohammad Hossein Pournaghi-Azar
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  2. Shahla Kheradmandi
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  3. Afsaneh Saadatirad
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Correspondence to Mohammad Hossein Pournaghi-Azar.

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Pournaghi-Azar, M.H., Kheradmandi, S. & Saadatirad, A. Simultaneous voltammetry of paracetamol, ascorbic acid, and codeine on a palladium-plated aluminum electrode: oxidation pathway and kinetics. J Solid State Electrochem 14, 1689–1695 (2010). https://doi.org/10.1007/s10008-010-1011-2

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  • DOI: https://doi.org/10.1007/s10008-010-1011-2

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