Abstract
The aim of this work is to investigate the hydrogen-bonding interaction in poly(vinyl alcohol) (PVA)/poly(acrylic acid) (PAA) blending system and its influence on rheological properties in solution and the physical properties in solid state. Introducing PAA into PVA solutions resulted in a thickening behavior of blend solutions. The viscosity of the solutions increased with PAA content increasing, and a maximum viscosity could be obtained when the ratio of PVA/PAA was 70/30. The intermolecular hydrogen-bonding and miscibility between PVA and PAA in solid state were investigated by differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR) and mechanical measurements. The results displayed the great influence of introducing PAA on the properties of blending films. The tensile strength increased from 89.31 MPa to 119.8 MPa and Young’s modulus improved by over 300% with increasing PAA concentration compared with those of pure PVA films. By systematically studying the rheological behaviors of solutions and the physical properties of films, the influence of hydrogen-bonding in solutions and solid states were discussed.
Similar content being viewed by others
References
Paul, D.R. and Newman, S., “Polymer blends”, Academic Press, New York, 1978
Utracki, L.A., “Polymer alloys and blends: thermodynamics and rheology”, Hanser Publishers, Munich, 1989
Bailey, F.E., Lundberg, R.D. and Callard, R.W. J. Polym. Sci. Polym. Chem. Ed., 1964, 2: 845
Tsuchida, E., Osada, Y. and Ohno, H. J. Macromol. Sci. Phys., 1980, 17: 683
Desbrieres, J. and Rinaudo, M. Eur. Polym. J., 1981, 17: 1265
Lundberg, R.D., 1985, U.S. Pat., 4,526,951
Tsuchida, E. J. Macromol. Sci. Chem., 1994, A31: 1
Wang, Q., Dan, Y. and Wang, X.G. J. Macromol. Sci. Pure Appl. Chem., 1997, A34: 1155
Dan, Y., Chen, S.Y., Zhang, Y.F. and Xiang, F.R. J. Polym. Sci. Polym. Phys. Ed., 2000, 38: 1069
Lü, H., Zheng, S.X., Zhang, B. and Tang, X.Z. Macromol. Chem. Phys., 2004, 205: 834
Coleman, M.M., Narvet, L.A. and Painter, P.C. Polymer, 1998, 39: 5867
Lee, N.Y., Painter, P.C. and Coleman, M.M. Macromolecules, 1988, 21: 954
Moore, J.A. and Kaur, S. Macromolecules, 1998, 31: 328
Chan, C.K. and Chu, I.M. Polymer, 2001, 42: 6089
Prinos, J. and Panayiotou, C. Polymer, 1995, 30: 1223
Slark, A.T. Polymer, 1997, 38: 2407
Meeussen, F., Nies, E., Berghmans, H., Verbrugghe, S., Goethals, E. and du Prez, F. Polymer, 2000, 41: 8597
Zeng, M., Zhang, L.N., Wang, N.G. and Zhu, Z.C. J. Appl. Polym. Sci., 2003, 90: 1233.
Olabisi, O., Robeson, L.M. and Shaw, M.T., “Polymer-polymer miscibility”, Academic Press, New York, 1979
Vazquez-Torres, H., Cauich-Rodriguez, J.V. and Cruz-Ramos, C.A. J. Appl. Polym. Sci., 1993, 50: 777
Mano, V., Scarpelli Ribeiro E Silva, M.E., Barbani, N. and Giusti, P. J. Appl. Polym. Sci., 2004, 92: 743
Lü, H., Zheng, S.X. and Tian, G.H. Polymer, 2004, 45: 2897
Coleman, M.M., Graf, J.F. and Painter, P.C. “Specific interactions and miscibility of polymer blends”, Technomic Publishing, Lancaster, PA, 1991
Sotiropoulou, M. and Staikos, G. J. Rheol., 2004, 48: 927
Chang, M.H. and Kim, B.C. Macromol. Symp., 2007, 249: 591
Sun, S.M., Song, Y.H. and Zheng, Q. Food Hydrocolloids, 2008, 22: 1090
Akiba, I. and Akiyama, S. Polym. Networks Blends, 1997, 7: 147
Cai, H., Ait-Kadi, A. and Brisson, J. Polymer, 2003, 44: 1481
Sahlin, J.J. and Peppas, N.A. J. Appl. Polym. Sci., 1997, 63: 103
Yang, Z.Y. and Han, C.D. Macromolecules, 2008, 41: 2104
Rhim, J.W., Sohn, M.Y., Lee, K.H. and Joo, H.J. J. Appl. Polym. Sci., 1993, 50: 679
Lee, K.H., Kim, H.K. and Rhim, J.W. J. Appl. Polym. Sci., 1995, 58: 1707
Rhim, J.W., Yoon, S.W., Kim, S.W. and Lee, K.H. J. Appl. Polym. Sci., 1997, 63: 521
Rhim, J.W. and Kim, Y.K. J. Appl. Polym. Sci., 2000, 75: 1699
Vauclair, C., Tarjus, H. and Schaetzel, P. J. Membr. Sci., 1997, 125: 293
Arndt, K.F., Richter, A., Ludwig, S., Zimmermann, J., Kressler, J., Kuckling, D. and Adler, H.J. Acta Polym., 1999, 50: 383
Ottenbrite, R.M., Utracki, L.R. and Inoue, S., “Current topics in polymer science”, Hanser Publishers, Munich, 1987
Lyoo, W.S., Yeum, J.H., Kwon, O.W., Shin, D.S., Han, S.S., Kim, B.C., Jeon, H.Y. and Noh, S.K. J. Appl. Polym. Sci., 2006, 102: 3934
Nishi, T. and Wang, T.T. Macromolecules, 1975, 8: 909
Imken, R.L., Paul, D.R. and Barlow, J.W. Polym. Eng. Sci., 1976, 16: 593
Miura, K., Kimura, N., Suzuki, H., Miyashita, Y. and Nishio, Y. Carbohydr. Polym., 1999, 39: 139
Mikhail, M.F., Alexandra, R., Cédrick, C., Costantino, C. and Elena, E.D. Polymer, 2003, 44: 1819
Larrañaga, M., Mondragon, I. and Riccardi, C.C. Polym. Int., 2007, 56: 426
Parada, L.G., Cestereos, L.C., Meaurio, E. and Katime, I. Polymer, 1998, 39: 1019
Wu, G.M., Lin, S.J. and Yang, C.C. J. Membr. Sci., 2006, 275: 127
Socrates, G., “Infrared characteristic group frequencies”, 2nd ed., Wiley, New York, 1994
Williamson, G.R. and Wright, B. J. Polym. Sci. Part A, 1965, 3: 3885
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Chen, Nx., Zhang, Jh. The role of hydrogen-bonding interaction in poly(vinyl alcohol)/poly(acrylic acid) blending solutions and their films. Chin J Polym Sci 28, 903–911 (2010). https://doi.org/10.1007/s10118-010-9167-x
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10118-010-9167-x