Abstract
Improved hybrid solar cells consisting of vertical aligned cadmium sulfide (CdS) nanorod arrays and interpenetrating polythiophene (P3HT) have been achieved via modification of CdS nanorod surface by using conjugated N719 dye. The complete infiltration of P3HT between CdS nanorods interspacing was verified by scanning electron microscopy. By employing absorption and photoluminescence spectra, and current-voltage characterization the interaction between N719 molecules and CdS nanorods/P3HT interface was explored, and the role of N719 dye on the improvement of device performance was discussed.
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Huynh, W.U., Dittmer, J.J. and Alivisatos, A.P., Science, 2002, 295: 2425H
Helgesen, M., Sondergaard, R. and Krebs, F.C., J. Mater. Chem., 2010, 20: 36
Huynh, W.U., Dittmer, J.J., Libby, W.C., Whiting, G.L. and Alivisatos, A.P., Adv. Funct. Mater., 2003, 13: 73
Beek, W.J., Wienk, M.M. and Janssen, R.A., Adv. Funct. Mater., 2006, 16: 1112
Gonzalez-Valls, I. and Lira-Cantu, M., Energy Environ. Sci., 2009, 2: 19
Kuo, C.Y., Tang, W.C., Gau, C., Guo, T.F. and Jeng, D.Z., Appl. Phys. Lett., 2008, 93: 033307
Lira-Cantu, M. and Krebs, F.C., Sol. Energy Mater. Sol. Cells, 2006, 90: 2076
Qian, L., Yang, J., Zhou, R., Tang, A., Zheng, Y., Tseng, T.K., Bera, D., Xue, J. and Holloway, P.H., J. Mater. Chem., 2011, 21: 3814
Olson, D.C., Shaheen, S.E., Collins, R.T. and Ginley, D.S., J. Phys. Chem. C., 2007, 111: 16670
Nan, Y.X., Chen, F., Yang, L.G., Jiang, X.X., Zuo, L.J., Zhang, J.L., Yan, Q.X., Shi, M.M. and Chen, H.Z., Sol. Energy Mater. Sol. Cells, 2011, 95: 3233
Gnes, S., Neugebauer, H. and Sariciftci, N.S., Chem. Rev., 2007, 107: 1324
Hochbaum, A.I. and Yang, P., Chem. Rev., 2010, 110: 527
Chen, F., Qiu, W., Chen, X., Yang, L., Jiang, X., Wang, M. and Chen, H.Z., Solar Energy, 2011, 85: 2122
Fu, W., Shi, Y., Qiu, W., Wang, L., Nan, Y., Shi, M., Li, H. and Chen, H.Z., Phys. Chem. Chem. Phys., 2012, 14: 12094
Wang, L., Liu, Y., Jiang, X., Qin, D. and Cao, Y., J. Phys. Chem. C., 2007, 111: 9538
Lin, Y.Y., Chu, T.H., Chen, C.W. and Su, W.F., Appl. Phys. Lett., 2008, 92: 053312
Ravirajan, P., Peir, A.M., Nazeeruddin, M.K., Graetzel, M., Bradley, D.D., Durrant, J.R. and Nelson, J., J. Phys. Chem. B., 2006, 110: 7635
Goh, C., Scully, S.R. and McGehee, M.D., J. Appl. Phys., 2007, 101: 114503
Lin, Y.Y., Chu, T.H., Li, S.S., Chuang, C.H., Chang, C.H., Su, W.F., Chang, C.P., Chu, M.W. and Chen, C.W., J. Am. Chem. Soc., 2009, 131: 3644
Jiang, X., Chen, F., Qiu, W., Yan, Q., Nan, Y., Xu, H., Yang, L. and Chen, H.Z., Sol. Energy Mater. Sol. Cells, 2010, 94: 2223
Chen, F., Zhou, R., Yang, L., Shi, M., Wu, G., Wang, M. and Chen, H.Z., J. Phys. Chem. C, 2008, 112: 13457
Lin, Y.Y., Lee, Y.Y., Chang, L., Wu, J.J. and Chen, C.W., Appl. Phys. Lett., 2009, 94: 063308
Band, B.P., Burk, D.P. and Forrest, S.R., Phys. Rev. B, 2007, 75: 115327
Tai, Q., Zhao, X. and Yan, F., J. Mater. Chem., 2010, 20: 7366
Jiang, X., Chen, F., Xu, H., Yang, L., Qiu, W., Shi, M., Wang, M. and Chen, H.Z., Sol. Energy Mater. Sol. Cells, 2010, 94: 338
Thompson, B.C. and Fréchet, J.M. J., Angew. Chem. Int. Ed., 2008, 47: 58
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Invited paper dedicated to Professor Fosong Wang on the occasion of his 80th birthday
This work was financially supported by the National Natural Science Foundation of China (Nos. 50990063, 51261130582 and 91233114).
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Nan, Yx., Li, Jj., Fu, Wf. et al. Performance enhancement of CdS nanorod arrays/P3HT hybrid solar cells via N719 dye interface modification. Chin J Polym Sci 31, 879–884 (2013). https://doi.org/10.1007/s10118-013-1274-z
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DOI: https://doi.org/10.1007/s10118-013-1274-z