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Poly(N,N-dimethylaminoethyl methacrylate) grafted poly(vinyl chloride)s synthesized via ATRP process and their membranes for dye separation

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Abstract

To functionalize poly(vinyl chloride) (PVC) for various applications, monomers containing tertiary amine group are incorporated into PVC via atom transfer radical polymerization (ATRP) initiated by the labile chlorines in their backbones. The kinetics of synthesis was carefully investigated, and it is proven that the grafting polymerization process can be effectively controlled by regulating the reaction time. The membranes are fabricated using PVC and copolymers by non-solvent induced phase separation (NIPS) process. The hydrophilicity and pore structure of copolymer membranes were enhanced as well, these membranes are endowed with positive charge. When PDMA% (i.e., the PDMA weight percentage in copolymer) is 31.1%, the flux and Victoria blue B rejection are 26.0 L·m-2·h-1 (0.5 MPa) and 91.2%, respectively. Thus, the newly synthesized polymer is proven to be a promising material for dye separation with positive charges.

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Authors and Affiliations

  1. Key Laboratory of Macromolecular Synthesis and Functionalization (Ministry of Education), Engineering Research Center of Membrane and Water Treatment (Ministry of Education), Department of Polymer Science and Engineering, Zhejiang University, Hangzhou, 310027, China

    Li-feng Fang, Na-chuan Wang, Ming-yong Zhou, Bao-ku Zhu  (朱宝库), Li-ping Zhu & Angelin Ebanezar John

Authors
  1. Li-feng Fang
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  2. Na-chuan Wang
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  3. Ming-yong Zhou
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  4. Bao-ku Zhu  (朱宝库)
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  5. Li-ping Zhu
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  6. Angelin Ebanezar John
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Corresponding author

Correspondence to Bao-ku Zhu  (朱宝库).

Additional information

This work was financially supported by the National 863 Program (No. 2012AA03A602), National 973 Program (No. 2009CB623402) and the National Natural Science Foundation of China (No. U1134002).

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Fang, Lf., Wang, Nc., Zhou, My. et al. Poly(N,N-dimethylaminoethyl methacrylate) grafted poly(vinyl chloride)s synthesized via ATRP process and their membranes for dye separation. Chin J Polym Sci 33, 1491–1502 (2015). https://doi.org/10.1007/s10118-015-1701-4

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  • DOI: https://doi.org/10.1007/s10118-015-1701-4

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