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Thermal stability and thermal aging of poly(vinyl chloride)/MgAl layered double hydroxides composites

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Abstract

MgAl-LDH (layered double hydroxides) were prepared with CO(NH2)2, NH4Cl and NH3·H2O by the coprecipitation method, respectively. Corresponding composite membranes were prepared by the coating method. LDHs were characterized by WAXS, CO2-TPD and SEM. The morphology of the PVC/LDHs composite membranes were characterized by means of SEM. The thermal stability of the membranes was analyzed by air aging box and TGA-FTIR. The SEM results show that nano-particles can be compatible with poly(vinyl chloride) (PVC) matrix homogeneously by the stirring-ultrasound blend method with two steps. Furthermore, the air aging box results proved that MgAl-CO(NH2)2-LDH has the best effect on thermal stability of PVC. TGA-FTIR results show that MgAl-CO(NH2)2-LDH could adsorb more HCl that resulted from the degradation of PVC and improve the pyrolysis temperature of the first degradation stage by 15 K compared with PVC.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China

    Hong-mei Zhang & Shu-hua Zhang  (张书华)

  2. Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, 94720, USA

    Polite Stewart, Chen-hui Zhu, Alexander Hexemer, Eric Schaible & Cheng Wang  (王成)

  3. College of Mechanical Engineering, Shanghai University of Engineering Science, Shanghai, 201620, China

    Wei-jun Liu

Authors
  1. Hong-mei Zhang
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  2. Shu-hua Zhang  (张书华)
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  3. Polite Stewart
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  4. Chen-hui Zhu
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  5. Wei-jun Liu
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  6. Alexander Hexemer
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  7. Eric Schaible
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  8. Cheng Wang  (王成)
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Corresponding authors

Correspondence to Shu-hua Zhang  (张书华) or Cheng Wang  (王成).

Additional information

This work was financially supported by the Shanghai Municipal Education Commission with “Twelfth Five” scientific connotation construction project (No. nhky-2012-05), foreign visiting scholar fellowship program (No. B-8938-12-0406) and Opening Project of Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering.

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Zhang, Hm., Zhang, Sh., Stewart, P. et al. Thermal stability and thermal aging of poly(vinyl chloride)/MgAl layered double hydroxides composites. Chin J Polym Sci 34, 542–551 (2016). https://doi.org/10.1007/s10118-016-1778-4

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  • DOI: https://doi.org/10.1007/s10118-016-1778-4

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