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Understanding the reinforcement and dissipation of natural rubber compounds filled with hybrid filler composed of carbon black and silica

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Abstract

The performance of reinforced rubber compounds depends on the filler composition while the reinforcement and dissipation mechanisms still remain unclear. Herein linear and nonlinear dynamic rheological responses of carbon black/silica hybrid filler filling nature rubber compounds are investigated. The rheological contributions of dynamically retarded bulk phase and filler network are revealed to be crucial at high and low frequencies, respectively, and the bulk phase is shown to be of vital importance for the occurrence of nonlinear Payne effect at mediate frequencies. A framework for simultaneously solving reinforcement and dissipation varying with filler composition and content is suggested, providing a new perspective in understanding the filling effect for manufacturing high-performance rubber materials.

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Authors and Affiliations

  1. Ministry of Education Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Key Laboratory of Adsorption and Separation Materials & Technologies of Zhejiang Province, Zhejiang University, Hangzhou, 310027, China

    Yi-hu Song  (宋义虎) & Qiang Zheng

  2. Shanghai Aerospace System Engineering Institute, Shanghai, 201110, China

    Ling-bin Zeng

Authors
  1. Yi-hu Song  (宋义虎)
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  2. Ling-bin Zeng
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  3. Qiang Zheng
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Corresponding author

Correspondence to Yi-hu Song  (宋义虎).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 51573157, 51333004 and 51373149), the Natural Science Foundation of Zhejiang Province (No. R14E030003), the Major Projects of Science and Technology Plan of Guizhou Province (No. (2013) 6016), the Open Project Foundation in Shanghai Aerospace System Engineering Institute, and the SAST Innovation Fund (No. yy-F08052015100029).

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10118_2017_1987_MOESM1_ESM.pdf

Understanding the Reinforcement and Dissipation of Natural Rubber Compounds Filled With Hybrid Filler Composed of Carbon Black and Silica

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Song, Yh., Zeng, Lb. & Zheng, Q. Understanding the reinforcement and dissipation of natural rubber compounds filled with hybrid filler composed of carbon black and silica. Chin J Polym Sci 35, 1436–1446 (2017). https://doi.org/10.1007/s10118-017-1987-5

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  • DOI: https://doi.org/10.1007/s10118-017-1987-5

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