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Adsorption of arsenic (V) by iron (III)-modified natural zeolitic tuff

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Abstract

Adsorption of arsenic (V) by natural zeolitic tuff, modified with iron (III), was investigated. Also, the iron (III) adsorption characteristics by natural zeolitic tuff was evaluated. It was determined that iron (III) adsorption by starting zeolitic tuff was best represented by the Freundlich type of isotherm, having correlation coefficient (r 2) of 0.990. Arsenic (V) adsorption by iron (III)-modified zeolitic tuff followed a nonlinear type of isotherm. The best fit of the experimental data was obtained using the Langmuir–Freundlich model (r 2 = 0.99), with the estimated maximum of arsenic (V) adsorption to iron (III)-modified zeolitic tuff of 1.55 mg/g.

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References

  • Altundoğan HS, Altundoğan S, Tümen F, Bildik M (2002) Arsenic adsorption from aqueous solutions by activated red mud. Waste Manag 22:357–363

    Article  Google Scholar 

  • Bruce AM, Scott EF, Sabine G (1998) Surface structures and stability of arsenic (III) on goethite: spectroscopic evidence for inner-sphere complexes. Environ Sci Technol 32:2383–2388

    Article  Google Scholar 

  • Doušová B, Machovič V, Koloušek D, Kovanda F, Dorničák V (2003) Sorption of As(V) species from aqueous systems. Water Air Soil Pollut 149:251–267

    Article  Google Scholar 

  • Doušová B, Grygar T, Martaus A, Fuitová L, Koloušek D, Machovič V (2006) Sorption of AsV on aluminosilicates treated with FeII nanoparticles. J Colloid Interface Sci 302:424–431

    Article  Google Scholar 

  • Elizalde-González MP, Mattusch J, Einicke WD, Wennrich R (2001a) Sorption on natural solids for arsenic removal. Chem Eng J 81:187–195

    Article  Google Scholar 

  • Elizalde-González MP, Mattusch J, Wennrich R (2001b) Application of natural zeolites for preconcentration of arsenic species in water samples. J Environ Monit 3:22–26

    Article  Google Scholar 

  • Elizalde-González MP, Mattusch J, Wennrich R, Morgenstern P (2001c) Uptake of arsenite and arsenate by clinoptilolite-rich tuffs. Microporous Mesoporous Mater 46:277–286

    Article  Google Scholar 

  • Harper TR, Kingham NW (1992) Removal of arsenic from wastewater using chemical precipitation methods. Water Environ Res 64(3):200–203

    Article  CAS  Google Scholar 

  • Jaroniec M (1983) Current state in adsorption from multicomponent solutions of nonelectrolytes on solids. Adv Colloid Interface Sci 18:149–225

    Article  CAS  Google Scholar 

  • Karim MM (2000) Arsenic in groundwater and health problems in Bangladesh. Water Res 34:304–310

    Article  CAS  Google Scholar 

  • Lemić J, Kovačević D, Tomašević-Čanović M, Kovačević D, Stanić T, Pfend R (2006) Removal of atrazine, lindane and diazinone from water by organo-zeolites. Water Res 40:1079–1085

    Article  Google Scholar 

  • Onyango MS, Matsuda H, Ogada T (2003) Sorption kinetics of arsenic onto iron-conditioned zeolite. J Chem Eng Jpn 36(4):477–485

    Article  CAS  Google Scholar 

  • Payne KB, Abdel-Fattah TM (2005) Adsorption of arsenate and arsenite by iron-treated activated carbon and zeolites: effects of pH, temperature, and ionic strength. J Environ Sci Health Part A 40(4):423–749

    Article  Google Scholar 

  • Sheta AS, Falatah AM, Al-Sewailem MS, Khaled EM, Sallam ASH (2003) Sorption characteristics of zinc and iron by natural zeolite and bentonite. Microporous Mesoporous Mater 61:127–136

    Article  CAS  Google Scholar 

  • Thirunavukkarasu OS, Viraraghavan T, Subramanian KS (2001) Removal of arsenic in drinking water by iron oxide-coated sand and ferrihydrite-batch studies. Water Qual Res J Can 36:55–70

    CAS  Google Scholar 

  • Viraraghavan T, Jin YC, Tonita PM (1992) Arsenic in water supplies. Int J Environ Stud 41:159–167

    Article  CAS  Google Scholar 

  • Xu YH, Nakajima T, Ohki A (2002) Adsorption and removal of arsenic (V) from drinking water by aluminium-loaded Shirasu-zeolite. J Hazard Mater B92:275–287

    Article  Google Scholar 

Download references

Acknowledgments

Funding for this research was provided by the Ministry of Science of the Republic of Serbia under the project 6702.

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Correspondence to Tanja Stanić.

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Stanić, T., Daković, A., Živanović, A. et al. Adsorption of arsenic (V) by iron (III)-modified natural zeolitic tuff. Environ Chem Lett 7, 161–166 (2009). https://doi.org/10.1007/s10311-008-0152-3

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  • DOI: https://doi.org/10.1007/s10311-008-0152-3

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