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Adsorption

Erschienen in:

01.02.2013

On the description of isotherms of CH₄ and C₂H₄ adsorption on graphite from subcritical to supercritical conditions

Reconciliation between computer simulation and experimental data

verfasst von: Mus’ab Abdul Razak, D. D. Do, Toshihide Horikawa, Keita Tsuji, D. Nicholson

Erschienen in: Adsorption | Ausgabe 1/2013

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Abstract

Different potential models for methane and ethylene are tested for their suitability for the description of bulk phase behavior, including coexistence, and adsorption on a graphite surface under sub- and super-critical conditions using GCMC simulation. Under sub-critical conditions, those intermolecular potential models that describe correctly the vapor–liquid equilibria were found to be adequate for the description of surface adsorption. These potential models can also give a good account of adsorption under supercritical conditions or near-critical conditions, provided the experimental data (in terms of excess) are correctly obtained with the reliably determined void volume as illustrated in this paper with methane adsorption.

Vorheriger Artikel Multilayer adsorption equilibrium model for gas adsorption on solids

Nächster Artikel Adsorption of ammonia and water on functionalized edge-rich carbon nanofibers

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Titel: On the description of isotherms of CH4 and C2H4 adsorption on graphite from subcritical to supercritical conditions
Reconciliation between computer simulation and experimental data
verfasst von: Mus’ab Abdul Razak
D. D. Do
Toshihide Horikawa
Keita Tsuji
D. Nicholson
Publikationsdatum: 01.02.2013
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 1/2013
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-012-9433-z

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