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Erschienen in: Adsorption 4-6/2016

19.12.2015

New developments on carbon dioxide capture using amine-impregnated silicas

verfasst von: E. S. Sanz-Pérez, A. Arencibia, R. Sanz, G. Calleja

Erschienen in: Adsorption | Ausgabe 4-6/2016

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Abstract

A series of representative amines were impregnated on SBA-15 mesostructured silica. Ethylenediamine, 1,6-diaminohexane, hexamethyleneimine, tetraethylenepentamine (TEPA), branched polyethyleneimine (PEI), piperazine (PZ), and 4-amino-2-hydroxy-6-methylpyrimidine (PD) were used as impregnating agents. Impregnated materials were characterized by N2 adsorption–desorption, elemental analysis and CO2 adsorption–desorption. CO2 analyses were performed at 45 °C with the aim of reproducing industrial post-combustion conditions. Relevant differences in CO2 uptake were assigned to the kind of amino group used and their position in the molecule (i.e., primary, secondary or tertiary, isolated, close to aromatic rings…). PEI, TEPA and PZ were also impregnated over SBA-AP, i.e., SBA-15 grafted with aminopropyl-trimethoxysilane (AP), by using a double functionalization method. CO2 uptake and amine efficiency (CO2/N molar ratio) were found to depend on the nature of the impregnating molecule. Improved stability and CO2 capture properties were obtained for samples impregnated over SBA-AP, achieving a CO2 adsorption capacity of 104 mg CO2/g ads (2.4 mmol CO2/g ads) for SBA-AP–TEPA (45 °C, 1 bar), with an amine efficiency of 0.32 mol CO2/mol N (SBA-AP–TEPA, 45 °C, 1 bar).

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Metadaten
Titel
New developments on carbon dioxide capture using amine-impregnated silicas
verfasst von
E. S. Sanz-Pérez
A. Arencibia
R. Sanz
G. Calleja
Publikationsdatum
19.12.2015
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 4-6/2016
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-015-9740-2

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