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Adsorption

Erschienen in:

05.07.2018

Adsorption of arsenic on iron modified attapulgite (Fe/ATP): surface complexation model and DFT studies

verfasst von: Hong Pan, Huijie Hou, Jing Chen, Hongbo Li, Linling Wang

Erschienen in: Adsorption | Ausgabe 5/2018

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Abstract

The adsorption behaviors of arsenic As(V) on the iron modified attapulgite (Fe/ATP) were studied. Two types of Fe/ATP nanoparticles, including Fe(III)/ATP and Fe(II,III)/ATP were prepared by ultrasonic co-precipitation method and characterized using SEM, XRD, XPS, FT-IR and zeta potential analyses. The adsorption isotherms of As(V) on Fe/ATP were well fitted by Freundlich model. The adsorption kinetics data were followed by the pseudo-second-order model with the pseud-second-order rate constant (k, min⁻¹) of − 0.033 for Fe(III)/ATP and − 0.037 for Fe(II,III)/ATP, respectively. Adsorption capacities of Fe/ATP were 5–6 times higher than ATP (5.2 mg g^‒1). The Fe–O(H) groups on Fe/ATP contributed to the strong interaction for As(V), confirmed with FT-IR and XPS analyses. The higher adsorption capacity of Fe(III)/ATP than that of Fe(II,III)/ATP was attributed to more surface hydroxyl groups on Fe(III)/ATP. Surface complexation models and density functional theory calculations demonstrated that As(V) sorption on Fe/ATP was by virtue of the formation of monodentate complexes.

Vorheriger Artikel Interaction of sulfur trioxide molecules with armchair and zigzag stanene-based nanotubes: electronic properties exploration by DFT calculations

Nächster Artikel A DFT study of penicillamine adsorption over pure and Al-doped C60 fullerene

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Titel: Adsorption of arsenic on iron modified attapulgite (Fe/ATP): surface complexation model and DFT studies
verfasst von: Hong Pan
Huijie Hou
Jing Chen
Hongbo Li
Linling Wang
Publikationsdatum: 05.07.2018
Verlag: Springer US
Erschienen in: Adsorption / Ausgabe 5/2018
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI: https://doi.org/10.1007/s10450-018-9959-9

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