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Erschienen in: Adsorption 6/2019

27.03.2019

Adsorption mechanism of metal ions on activated carbon

verfasst von: Ayaka Kuroki, Megumi Hiroto, Yoshitomo Urushihara, Toshihide Horikawa, Ken-Ichiro Sotowa, Jesús Rafael Alcántara Avila

Erschienen in: Adsorption | Ausgabe 6/2019

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Abstract

Environmental pollution, particularly that caused by the presence of heavy metals in wastewater, is a serious problem. Therefore, heavy metals should be prevented from reaching the natural environment or removed from polluted wastewater. Adsorption is a very economical, simple, effective, highly versatile process for removing harmful pollutants from wastewater. In this study, six commercial activated carbon (AC) samples were used to evaluate the adsorption of Pb2+, Ni2+, and Zn2+. We investigated the correlation between the adsorption of metal ions on AC and the pore or surface properties of AC. Large quantities of ions in the order [Pb2+] >> [Zn2+], [Ni2+] were adsorbed on all AC samples. The results showed that the Pb2+ adsorption capacity per unit Dubinin–Polanyi (DP) surface area (SDP) is correlated with the graphite/defect (G/D) ratio of AC; the G/D ratio was analyzed via Raman spectroscopy. The adsorbability of Pb2+ on AC per unit SDP was higher in AC with a larger G/D ratio. Moreover, we found that hard and soft acids and bases contribute to adsorption. The observed correlation facilitates the determination of the adsorption capacity of Pb2+ on AC using the G/D ratio without any adsorption test.

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Metadaten
Titel
Adsorption mechanism of metal ions on activated carbon
verfasst von
Ayaka Kuroki
Megumi Hiroto
Yoshitomo Urushihara
Toshihide Horikawa
Ken-Ichiro Sotowa
Jesús Rafael Alcántara Avila
Publikationsdatum
27.03.2019
Verlag
Springer US
Erschienen in
Adsorption / Ausgabe 6/2019
Print ISSN: 0929-5607
Elektronische ISSN: 1572-8757
DOI
https://doi.org/10.1007/s10450-019-00069-7

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