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Thermodynamic and Kinetic Properties of Natural Brines

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Abstract

The physical chemistry of natural brines made up of mostly NaCl has been studied over the years. In this article, the work on the thermodynamics and kinetics of processes in NaCl brines will be examined. The importance of ionic interactions of the processes will be stressed. This will include the pressure–volume–temperature and physical–chemical properties of NaCl and other brine salts from 0 to 6 m, 0 to 200°C, and 0 to 1,000 bar applied pressures. Acid–base, gas–liquid, solid–liquid, and ion–complex formation processes in NaCl are examined. Equations that can be used to estimate the equilibria in NaCl are given. Pitzer models are discussed that can be used to estimate ionic equilibria in brines. The oxidation of Fe(II) and Cu(I) with O2 and H2O2 and the reduction of Cu(II) with H2O2 in NaCl are examined in terms of ionic complexes of metals with OH− and CO3 2−. The oxidation of H2S with O2 and H2O2 is also examined in NaCl media. Equations are given that can be used to estimate the effect of ionic interactions on kinetic processes in NaCl.

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Acknowledgments

The author wishes to acknowledge the support of the Oceanographic Section of the National Science Foundation for supporting his studies on the Physical Chemistry of Natural Waters.

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  1. Rosenstiel School of Marine and Atmospheric Science, University of Miami, 4600 Rickenbacker Causeway, Miami, FL, 33149, USA

    Frank J. Millero

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Millero, F.J. Thermodynamic and Kinetic Properties of Natural Brines. Aquat Geochem 15, 7–41 (2009). https://doi.org/10.1007/s10498-008-9053-0

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