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Preparation and characterization of nanosized nickel oxide

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Abstract

Nanosized nickel oxide was synthesized by a simple liquid-phase process to obtain the hydroxide precursor and then calcined to form the oxide. The precursor and the nickel oxide were characterized by X-ray diffraction (XRD), infrared spectroscopy (IR), thermal analysis (TG) and temperature-programmed reduction (TPR). The results indicated that the particle size of nickel oxide was controlled by the calcined temperature (TC). Mixed phases of nickel oxide and nickel hydroxide were present as the TC was lower than 300 °C. Non-stoichiometric nickel oxide (NiO x , x = 1.2) was formed between 250 °C and 400 °C and a pure nickel oxide was formed as the TC arrived 500 °C. The particle size of nickel oxide changed as the calcined temperature was controlled under 250 °C, 300 °C, 400 °C and 500 °C, the order was 5.6 nm, 6.5 nm, 11 nm and 17 nm, respectively.

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Authors and Affiliations

  1. Department of Applied Chemistry, Chung Cheng Institute of Technology, National Defense University, Tahsi, Taoyuan, 33509, Taiwan, Republic of China

    Chen-Bin Wang, Guo-Yuan Gau, Shiue-Jiun Gau, Chih-Wei Tang & Jia-Lin Bi

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  1. Chen-Bin Wang
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  2. Guo-Yuan Gau
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  3. Shiue-Jiun Gau
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  4. Chih-Wei Tang
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Correspondence to Chen-Bin Wang.

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Wang, CB., Gau, GY., Gau, SJ. et al. Preparation and characterization of nanosized nickel oxide. Catal Lett 101, 241–247 (2005). https://doi.org/10.1007/s10562-005-4899-x

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