Niobia–silica mesoporous materials (xerogel, aerogel and MCM type) have been synthesized by sol–gel techniques using different co-solvents as templates. All materials are active catalysts in the epoxidation of cyclohexene with hydrogen peroxide, but only meso–macroporous aerogels give a stable and recyclable catalyst.
Similar content being viewed by others
References
C.T. Kresge M.E. Leonowicz W.J. Roth J.C. Vartuli J.S. Beck (1992) Nature 359 710 Occurrence Handle10.1038/359710a0 Occurrence Handle1:CAS:528:DyaK38Xms1entrs%3D
K. Schumacher M. Grun K.K. Unger (1999) Micr. Mes. Mater. 27 201 Occurrence Handle1:CAS:528:DyaK1MXit1Ogs78%3D
W. Stober A. Fink E. Bohn (1968) J. Coll. Interf. Sci. 26 62 Occurrence Handle10.1016/0021-9797(68)90272-5
(a) J.C. Vartuli, K.D. Schmitt, C.T. Kresge, W.J. Roth, M.E. Leonwicz, S.B. McCullen, S.D. Hellring, J.S. Beck, J.L. Schlenker, D.H. Olson and E.W. Sheppard, Chem. Mater. 6 (1994) 2317. (b) D. Zhao and D. Goldfarb, J. Chem. Soc., Chem. Commun. 8 (1995) 875. (c) P. Selvam, S.K. Bhatia and C.G. Sonwane, Ind. Eng. Chem. Res. 40 (2001) 3237
(a) B. Notari, Catal. Today 18 (1993) 63. (b) A. Wróblewska, J. Mol. Catal. A: Chemical 229 (2005) 207
(a) M. Morandin, R. Gavagnin, F. Pinna and G. Strukul, J. Catal. 212 (2002) 193. (b) C. Palazzi, L. Oliva, M. Signoretto and G. Strukul, J. Catal. 194 (2000) 286
(a) R. Jin, H. Li and J. Deng, J. Catal. 203 (2001) 75. (b) X. Xia, R. Jin, Y. He, J.-F. Deng and H. Li, Appl. Surf. Sci. 165 (2000) 255. (c) R. Neumann and M. Levin-Elad, J. Catal. 166 (1997) 206. (d) F. Somma and G. Strukul, J. Catal. 227 (2004) 344
M. Dusi T. Mallat A. Baiker (2000) Catal. Rev.-Sci. Eng. 42 213 Occurrence Handle1:CAS:528:DC%2BD3cXjsFyqtL0%3D
(a) I. Nowak, B. Kilos, M. Ziolek and A. Lewandowska, Catal. Today 78 (2003) 487. (b) M. Ziolek, Catal. Today 78 (2003) 47. (c) M. Ziolek, I. Sobczak, A. Lewandowska, I. Nowak, P. Decyk, M. Renn and B. Jankowska, Catal. Today 70 (2001) 169. (d) F. Somma, P. Canton and G. Strukul, J. Catal. 229 (2005) 490. (e) J.M.R. Gallo, I.S. Paulino and U. Schuchardt, Appl. Catal. A: General 266 (2004) 223
K.S.W. Sing D.H. Everett R.A. Haul L. Moscou R.A. Pierotti J. Roquerol T. Siemieniewska (1985) Pure Appl. Chem. 57 603 Occurrence Handle1:CAS:528:DyaL2MXhvFWrtb4%3D
(a) M. Ai, J. Catal. 40 (1975) 327. (b) A. Gervasini and A. Auroux, J. Catal. 131 (1991) 190. (c) A. Gervasini, J. Fanyvesi and A. Auroux, Catal. Lett. 43 (1997) 219. (d) P. Trens, V. Stathopoulos, M.J. Hudson and P. Pomonis, Appl. Catal. A: General 263 (2004) 103
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Somma, F., Strukul, G. Niobium Containing Micro-, Meso- and Macroporous Silica Materials as Catalysts for the Epoxidation of Olefins with Hydrogen Peroxide. Catal Lett 107, 73–81 (2006). https://doi.org/10.1007/s10562-005-9733-y
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10562-005-9733-y