Abstract
F-doped TiO2 nanotubes were prepared by impregnation method. The prepared catalysts were characterized by XRD, TEM, and XPS. The photocatalytic activity of F-doped TiO2 nanotubes was evaluated through the photodegradation of aqueous methyl orange. The experiments demonstrated that the F-doped TiO2 nanotubes calcined at 300 °C possessed the best photocatalytic activity. Compared with pure TiO2 nanotubes, the doping with F− significantly enhanced the photocatalytic efficiency. The high photocatalytic activity was ascribed to several beneficial effects produced by F-doping: creation of oxygen vacancies, presence of Ti3+, and so on.
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Linsebigler AL, Lu GQ, Yates JT (1995) Chem Rev 95:735
Fujishima A, Rao TN, Tryk DA (2000) J Photochem Photobiol C 1:1
Diebold U (2003) Surf Sci Rep 48:53
Anpo M, Dohshi S, Kitano M, Hu Y, Takeuchi M, Matsuoka M (2005) Annu Rev Mater Res 35:1
Lindgren T, Mwabora JM, Avendano E, Jonsson J, Hoel A, Granqvist CG, Lindquist SE (2003) J Phys Chem B 107:5709
Wang H, Lewis JP (2006) J Phys: Condens Matter 18:421
Asahi R, Morikawa T, Ohwaki T, Aoki K, Taga Y (2001) Science 293:269
Sakthivel S, Kisch H (2003) Angew Chem Int Ed 42:4908
Choi Y, Umebayashi T, Yoshikawa M (2004) J Mater Sci 39:1837
Tian FH, Liu CB (2006) J Phys Chem B 110:17866
Yu HF (2007) J Phys Chem Solids 68:600
Hong XT, Wang ZP, Cai WM, Lu F, Zhang J, Yang YZ, Ma N, Liu YJ (2005) Chem Mater 17:1548
Hattori A, Yamamoto M, Tada H, Ito S (1998) Chem Lett 8:707
Hattori A, Shimoda K, Tada H, Ito S (1999) Langmuir 15:5422
Hattori A, Tada H (2001) J Sol–Gel Sci Technol 22:47
Minero C, Mariella G, Maurino V, Pelizzetti E (2000) Langmuir 16:2632
Minero C, Mariella G, Maurino V, Vione D, Pelizzetti E (2000) Langmuir 16:8964
Ayllón JA, Peiró AM, Saadoun L, Vigil E, Domènech X, Peral J (2000) J Mater Chem 10:1911
Yamaki T, Sumita T, Yamamoto S (2002) J Mater Sci Lett 21:33
Yamaki T, Umebayashi T, Sumita T, Yamamoto S, Maekawa M, Kawasuso A, Itoh H (2003) Nucl Instrum Meth Phys Res B 206:254
Yu JC, Yu JG, Ho W, Jiang ZT, Zhang LZ (2002) Chem Mater 14:3808
Yu JG, Yu JC, Cheng B, Hark SK, Iu K (2003) J Solid State Chem 174:372
Park JS, Choi W (2004) Langmuir 20:11523
Park H, Choi W (2004) J Phys Chem B 108:4086
Li D, Haneda H, Labhsetwar NK, Hishita S, Ohashi N (2005) Chem Phys Lett 401:579
Li D, Haneda H, Hishita S, Ohashi N, Labhsetwar NK (2005) J Fluorine Chem 126:69
Ho W, Yu JC, Lee S (2006) Chem Commun 10:1115
Murakami SY, Kominami H, Kera Y, keda S, Noguchi H, Uosaki K, Ohtani B (2007) Res Chem Intermed 33:285
Mori K, Maki K, Kawasaki S, Yuan S, Yamashita H, Chem Eng Sci in press
Kasuga T, Hiramatsu M, Hoson A, Sekino T, Niihara K (1998) Langmuir 14:3160
Macak JM, Tsuchiya H, Schmuki P (2005) Angew Chem Int Ed 44:2100
Yao BD, Chan YF, Zhang XY, Zhang WF, Yang ZY, Wang N (2003) Appl Phys Lett 82:281
Vitiello RP, Macak JM, Ghicov A, Tsuchiya H, Dick LFP, Schmuki P (2006) Electrochem Commun 8:544
Xu JC, Lu M, Guo XY, Li HL (2005) J Mol Catal A 226:123
Liu HM, Yang WS, Ma Y, Cao YA, Yao JN, Zhang J, Hu TD (2003) Langmuir 19:3001
Nagaveni K, Hegde MS, Ravishankar N, Subbanna GN, Madras G (2004) Langmuir 20:2900
Suriye K, Praserthdam P, Jongsomjit B (2007) Appl Surf Sci 253:3849
Hengerer R, Bolliger B, Erbudak M, Gratzel M (2000) Surf Sci 460:162
Guillemot F, Porte MC, Labrugere C, Baquey C (2002) J Colloid Interface Sci 255:75
Jun J, Shin JH, Dhayal M (2006) Appl Surf Sci 252:3871
Huang DG, Liao SJ, Liu JM, Dang Z, Petrik L (2006) J Photochem Photobiol A 184:282
Zhang M, Jin ZS, Zhang JW, Guo XY, Yang JJ, Li W, Wang XD, Zhang ZJ (2004) J Mol Catal A 217:203
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An erratum to this article can be found at http://dx.doi.org/10.1007/s10562-008-9517-2
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Yu, Y., Wu, HH., Zhu, BL. et al. Preparation, Characterization and Photocatalytic Activities of F-doped TiO2Nanotubes. Catal Lett 121, 165–171 (2008). https://doi.org/10.1007/s10562-007-9316-1
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DOI: https://doi.org/10.1007/s10562-007-9316-1