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Propane Oxidative Dehydrogenation on V–Sb/ZrO2 Catalysts

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Abstract

The catalytic properties of V–Sb/ZrO2 and bulk Sb/V catalysts for the oxidative dehydrogenation of propane were studied. Samples were characterized by nitrogen adsorption, temperature-programmed reduction, temperature-programmed pyridine desorption and photoelectron spectroscopic techniques. Vanadia promotes the transition of tetragonal to monoclinic zirconia and the formation of ZrV2O7. Surface V and Sb oxide species do not appear to interact among them below monolayer coverage, but SbVO4 forms above monolayer. Simultaneously the excess of antimony forms α-Sb2O4. Activity and selectivity show no dependence on the acidity of the catalysts. However, there is a strong dependence of activity/selectivity on composition; surface vanadium species are active for propane oxidative dehydrogenation and the presence of Sb, affording rutile VSbO4 phase makes the system selective to C3H6, this is believed to be related to the redox cycle involving dispersed V5+ species and lattice reduced vanadium site in the rutile VSbO4 phase.

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References

  1. Mars P, Van Krevelen DW (1954) Chem Eng Sci 3:41

    CAS  Google Scholar 

  2. Chen K, Khodakov A, Yang J, Bell J, Iglesia E (1999) J Catal 186:325

    Article  CAS  Google Scholar 

  3. Gao X, Jehng J, Wachs J (2002) J Catal 2009:43

    Article  CAS  Google Scholar 

  4. Garcia Cortez G, Bañares G (2002) J Catal 209:197

    Article  CAS  Google Scholar 

  5. Chen K, Bell AT, Iglesia E (2002) J Catal 209:35

    Article  CAS  Google Scholar 

  6. Khodakov A, Olthof B, Bell AT, Iglesia E (1999) J Catal 181:205

    Article  CAS  Google Scholar 

  7. Khodakov A, Yang J, Su S, Iglesia E, Bell AT (1998) J Catal 177:343

    Article  CAS  Google Scholar 

  8. Mamedov EA, Cortés corberán EA (1995) Appl Catal A 127:1

    Article  CAS  Google Scholar 

  9. Corma A, López Nieto JM, Paredes N, Peréz M, Shen M, Cao H, Suib H (1992) Stud Surf Sci Catal 72:213

    Article  CAS  Google Scholar 

  10. Blasco T, López Nieto JM (1997) Appl Catal A 157:117

    Article  CAS  Google Scholar 

  11. Siew Hew Sam D, Soenen V, Volta JC (1990) J Catal 123:417

    Article  Google Scholar 

  12. Chaar MA, Patel D, Kung MC, Kung HH (1987) J Catal 105:483

    Article  CAS  Google Scholar 

  13. Pieck CL, Bañares MA, Fierro JLG (2004) J Catal 224:1

    Article  CAS  Google Scholar 

  14. Guerrero Ruiz A, Rodriguez Ramos I, Fierro JLG, Soenen V, Herman JM, Volta JC (1992) Stud Surf Sci Catal 72:203

    Article  CAS  Google Scholar 

  15. Zhanga W, Aub C, Wan H (1999) Appl Catal A 181:63

    Article  Google Scholar 

  16. Liu W, Lai SY, Dai H, Wang S, Sun H, Au CT (2007) Catal Lett 113:147

    Article  CAS  Google Scholar 

  17. Schubert UA, Anderle F, Spengler J, Zühlke J, Eberle HJ, Grasselli RK, Knözinger H (2001) Top Catal 15:195

    Article  CAS  Google Scholar 

  18. Spengler J, Anderle F, Bosch RK, Grasselli E, Pillep E, Behrens P, Lapina OB, Shubin AA, Eberle HJ, Knözinger H (2001) J Phys Chem B 105:10772

    Article  CAS  Google Scholar 

  19. Corma A, López Nieto A, Paredes N (1993) J Catal 1444:425

    Article  Google Scholar 

  20. Michalakos PM, Kung MC, Jahan I, Kung HH (1993) J Catal 140:226

    Article  CAS  Google Scholar 

  21. Argyle MD, Chen K, Bell AT, Iglesia E (2002) J Catal 208:139

    Article  CAS  Google Scholar 

  22. Lindblad T, Rebenstorf B, Yan ZG, Andersson SLT (1994) Appl Catal A 112:187

    Article  CAS  Google Scholar 

  23. Routray K, Reddy KRSK, Deo G (2004) Appl Catal A 265:103

    Article  CAS  Google Scholar 

  24. Kondratenko EV, Cherian M, Baerns M (2006) Catal Today 112:60

    Article  CAS  Google Scholar 

  25. Smits RHH, Seshan K, Leemresize H, Ross JRH (1993) Catal Today 16:513

    Article  CAS  Google Scholar 

  26. Heracleous E, Machli M, Lemonidou AA, Vasalos IA (2005) J Mol Catal A Chem 232:29

    Article  CAS  Google Scholar 

  27. Khodakov A, Yang J, Su S, Iglesia E, Bell AT (1998) J Catal 177:343

    Article  CAS  Google Scholar 

  28. Chen KD, Khodakov A, Yang J, Bell AT, Iglesia E (1999) J Catal 186:325

    Article  CAS  Google Scholar 

  29. Martínez-Huerta MV, Gao X, Tian H, Wachs IE, Fierro JLG, Bañares MA (2006) Catal Today 118:279

    Article  CAS  Google Scholar 

  30. Owens L, Kung HH (1993) J Catal 144:202

    Article  CAS  Google Scholar 

  31. Le Bars J, Auroux A, Védrine JC, Baerns M (1992) Stud Surf Sci Catal 72:181

    Article  CAS  Google Scholar 

  32. Juárez López R, Godjayeva NS, Córtes Corberán V, Fierro JLG, Manedod EA (1995) Appl Catal A 124:281

    Article  Google Scholar 

  33. Stelzer JB, Caro J, Fait M (2005) Catal Comm 6:1

    Article  CAS  Google Scholar 

  34. Chiang H, Lee M (1997) Appl Catal A 154:55

    Article  CAS  Google Scholar 

  35. Pieck CL, Del Val S, López Granados M, Bañares MA, Fierro JLG (2002) Langmuir 18:2642

    Article  CAS  Google Scholar 

  36. Bosch H, Kip BJ, van Ommen JG, Gellings PJ (1984) J Chem Soc Faraday Trans 1(80):2479

    Google Scholar 

  37. Koranne MM, Goodwin JG Jr, Marcelin G (1994) J Catal 148:369

    Article  CAS  Google Scholar 

  38. Pieck CL, Bañares MA, Vicente MA, Fierro JLG (2001) Chem Mat 13:1174

    Article  CAS  Google Scholar 

  39. Selected power difraction data for metals and alloys. Data Book, 1st edn, vol II, cards No. 13-307 and No 24-1164. International Center for Difraction Data (JCPDS), Swarthmore, USA

  40. Nilsson R, Lindblad T, Andersson A (1994) J Catal 148:501

    Article  CAS  Google Scholar 

  41. Wachs IE (1996) Catal Today 27:437

    Article  CAS  Google Scholar 

  42. Nilsson R, Lindblad T, Andersson A, Song C, Hansen S (1994) Stud Surf Sci Catal 82:293

    Article  CAS  Google Scholar 

  43. Nilsson R, Lindblad T, Andersson A (1994) J Catal 148:501

    Article  CAS  Google Scholar 

  44. Guerrero-Pérez MO, Bañares MA (2007) J Phys Chem C 111:1315

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Instituto de Investigaciones en Catálisis y Petroquímica, INCAPE (FIQ-UNL, CONICET), Santiago del Estero 2654, S3000AOJ, Santa Fe, Argentina

    Silvana A. D’Ippolito & Carlos L. Pieck

  2. Instituto de Catálisis y Petroleoquímica, CSIC, Cantoblanco, Madrid, 28049, Spain

    Miguel A. Bañares & José L. Garcia Fierro

Authors
  1. Silvana A. D’Ippolito
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  2. Miguel A. Bañares
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  3. José L. Garcia Fierro
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  4. Carlos L. Pieck
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Correspondence to Carlos L. Pieck.

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D’Ippolito, S.A., Bañares, M.A., Fierro, J.L.G. et al. Propane Oxidative Dehydrogenation on V–Sb/ZrO2 Catalysts. Catal Lett 122, 252–258 (2008). https://doi.org/10.1007/s10562-008-9437-1

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  • DOI: https://doi.org/10.1007/s10562-008-9437-1

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