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Ionic Manganese Porphyrins with S-containing Counter Anions: Mimicking Cytochrome P450 Activity for Alkene Epoxidation

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Abstract

The ionic manganese porphyrins, composed of trimethylbenzylammonium cations and S-containing anions, were designed to mimic cytochrome P450. S-containing anions could function as the stoichiometric axial ligands and counterions dually. Such ionic catalysts showed good catalytic performance in alkene epoxidation as compared with their neutral counterparts, in terms of activity, epoxide selectivity, and recyclability.

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Acknowledgments

The National Natural Science Foundation of China (Nos. 20533010, No. 20590366, No. 20673039), the Science & Technology Commission of Shanghai Municipality (No. 06JC14023, 06SR07101), China Postdoctoral Science Foundation (No. 44021220), Fudan Universtity (No. 2005KF03), and Shanghai Leading Academic Discipline Project (B409) are gratefully acknowledged for financial support.

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Authors and Affiliations

  1. Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai, 200062, China

    Yueqin Cai, Ye Liu, Yong Lu, Guohua Gao & Mingyuan He

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  1. Yueqin Cai
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  2. Ye Liu
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  3. Yong Lu
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  4. Guohua Gao
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  5. Mingyuan He
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Correspondence to Ye Liu.

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Cai, Y., Liu, Y., Lu, Y. et al. Ionic Manganese Porphyrins with S-containing Counter Anions: Mimicking Cytochrome P450 Activity for Alkene Epoxidation. Catal Lett 124, 334–339 (2008). https://doi.org/10.1007/s10562-008-9471-z

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  • DOI: https://doi.org/10.1007/s10562-008-9471-z

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