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Perovskite-type Oxide LaMnO3: An Efficient and Recyclable Heterogeneous Catalyst for the Wet Aerobic Oxidation of Lignin to Aromatic Aldehydes

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Abstract

The perovskite-type oxide catalyst LaMnO3 prepared by the sol–gel method was found to be an efficient heterogeneous and recyclable catalyst for the wet aerobic oxidation of lignin to aromatic aldehydes. The lignin conversion rate and the yield of each aromatic aldehyde were enhanced significantly by the catalytic process as compared with the non-catalyzed process. Moreover, the activity, specific surface area and perovskite-type structure of the LaMnO3 catalyst remained nearly unchanged after five successive recycles of catalytic reactions.

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Acknowledgements

The authors are grateful to the financial support from Natural Science Foundation of China (50776035, U0733001), Foundation of Scientific Research for Universities(20070561038) and Initiative Group Research Project(IRT0552) from Ministry of Education of China, National High Technology Project (863 project) (2007AA05Z408) and National Key R&D Program (2007BAD34B01) from the Ministry of Science and Technology of China.

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Authors and Affiliations

  1. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, Guangdong Province, China

    Haibo Deng, Lu Lin, Yong Sun, Chunsheng Pang & Junping Zhuang

  2. College of Medicine and Life Science, Nanjing University of Technology, Nanjing, Jiangsu Province, 210009, China

    Pingkai Ouyang & Zhenjiang Li

  3. Department of Paper and Bioprocess Engineering, State University of New York College of Environmental Science and Forestry, 1 Forestry Drive, Syracuse, NY, 13210, USA

    Shijie Liu

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  1. Haibo Deng
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  2. Lu Lin
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  4. Chunsheng Pang
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Correspondence to Lu Lin.

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Deng, H., Lin, L., Sun, Y. et al. Perovskite-type Oxide LaMnO3: An Efficient and Recyclable Heterogeneous Catalyst for the Wet Aerobic Oxidation of Lignin to Aromatic Aldehydes. Catal Lett 126, 106–111 (2008). https://doi.org/10.1007/s10562-008-9588-0

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  • DOI: https://doi.org/10.1007/s10562-008-9588-0

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