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CO Oxidation over Bimetallic Au–Pd Supported on Ceria–Zirconia Catalysts: Effects of Oxidation Temperature and Au:Pd Molar Ratio

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Abstract

Au–Pd supported on ceria–zirconia catalysts, with Au:Pd molar ratios in the 1:1–10:1 range, have been prepared using deposition precipitation of Au followed by impregnation with Pd. The resulting Au–Pd supported catalysts were activated by oxidation at 350, 450 and 700 °C. The oxidation at 700 °C led to the formation of large Au–Pd alloy nanoparticles showing lower catalytic activity for CO oxidation. The Au–Pd/Ce0.62Zr0.38O2 catalyst with the highest Au:Pd ratio, 10:1, exhibited the highest CO oxidation activity.

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Acknowledgments

This work has been supported by the Ministry of Science and Innovation of Spain/FEDER Program of the EU (Project: MAT 2013-40823-R, CSD2009-00013). J. J. Delgado, A. B. Hungría and X. Chen thank the program of “Ramón y Cajal” from Ministry of Science and Innovation of Spain.

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Authors and Affiliations

  1. Departamento de Ciencia de los Materiales e Ingeniería Metalúrgica y Química Inorgánica, Facultad de Ciencias, Universidad de Cádiz, Campus Río San Pedro, Puerto Real, 11510, Cádiz, Spain

    Carol M. Olmos, Lidia E. Chinchilla, Juan J. Delgado, Ana B. Hungría, Ginesa Blanco, Jose J. Calvino & Xiaowei Chen

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  1. Carol M. Olmos
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  2. Lidia E. Chinchilla
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  3. Juan J. Delgado
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  4. Ana B. Hungría
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  5. Ginesa Blanco
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  6. Jose J. Calvino
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  7. Xiaowei Chen
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Correspondence to Xiaowei Chen.

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Olmos, C.M., Chinchilla, L.E., Delgado, J.J. et al. CO Oxidation over Bimetallic Au–Pd Supported on Ceria–Zirconia Catalysts: Effects of Oxidation Temperature and Au:Pd Molar Ratio. Catal Lett 146, 144–156 (2016). https://doi.org/10.1007/s10562-015-1641-1

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  • DOI: https://doi.org/10.1007/s10562-015-1641-1

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