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01.02.2014 | Original Paper

Study on effects of carboxymethyl cellulose lithium (CMC-Li) synthesis and electrospinning on high-rate lithium ion batteries

verfasst von: Lei Qiu, Ziqiang Shao, Mingshan Yang, Wenjun Wang, Feijun Wang, Junling Wan, Jianquan Wang, Yudong Bi, Hongtao Duan

Erschienen in: Cellulose | Ausgabe 1/2014

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Abstract

This study, for the first time, synthesized carboxymethyl cellulose lithium (CMC-Li) by a two-step method and applied it to modified electrode material by electrospinning and as a binder on a lithium ion battery. By electrospinning, nano CMC-Li fiber and CMC-Li/9, 10-anthraquinone (AQ) composite fiber were obtained successfully and coated AQ electrode material. AQ was uniformly distributed in fibers, and then CMC-Li/AQ composite fiber was carbonized to obtain the carbon nanofiber/AQ/Li [CAL] composite as lithium battery anode material. Also for the first time we investigated substituting aqueous CMC-Li with different degrees of substitution (DS) for oily polyvinylidene fluoride (PVDF) as a lithium battery binder to assemble the battery with CAL for electrochemical performance tests. Compared with PVDF binder, cells with CMC-Li for a binder have excellent advantages, such as higher discharge capacity (226.4 mAh g⁻¹), safer cycle performance, lower cost and being more eco-friendly. Furthermore, the cell with CMC-Li with high DS performed better than the cell with low DS. This method also applies to other electrode materials.

Vorheriger Artikel The effect of eucalypt pulp xylan content on its bleachability, refinability and drainability

Nächster Artikel Direct carbamation of cellulose fiber sheets

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Titel: Study on effects of carboxymethyl cellulose lithium (CMC-Li) synthesis and electrospinning on high-rate lithium ion batteries
verfasst von: Lei Qiu
Ziqiang Shao
Mingshan Yang
Wenjun Wang
Feijun Wang
Junling Wan
Jianquan Wang
Yudong Bi
Hongtao Duan
Publikationsdatum: 01.02.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-013-0108-z

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