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01.10.2014 | Original Paper

Dissolution of rayon fibers for size exclusion chromatography: a challenge

verfasst von: Martin Siller, Kyujin Ahn, Nicole Pircher, Thomas Rosenau, Antje Potthast

Erschienen in: Cellulose | Ausgabe 5/2014

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Abstract

Application of size exclusion chromatography (SEC) for the analysis of cellulose samples is often limited due to poor solubility in the solvent system N,N-dimethylacetamide/lithium chloride (DMAc/LiCl). Hence different activation or derivatization methods have been developed and published. Most of these methods are laborious, influence the molar mass distribution or do not support dissolution of manmade fibers, such as viscose rayon. In this study, we have evaluated different activation methods for their applicability in viscose rayon dissolution and we present a novel method for activation. We found that an additional solvent exchange step with dimethyl sulfoxide (DMSO) increases and accelerates solubility of viscose fibers in DMAc/LiCl for subsequent SEC analysis. The improved dissolution by DMSO activation is mainly due to increased swelling and improved action towards the outer skin of the fiber. The novel approach has also been applied to the even more difficult dissolution of oxidized viscose fibers.

Vorheriger Artikel Study of interaction between nitrogen DBD plasma-treated viscose fibers and divalent ions Ca2+ and Cu2+

Nächster Artikel In situ phosphorus K-edge X-ray absorption spectroscopy studies of calcium–phosphate formation and transformation on the surface of bacterial cellulose nanofibers

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Titel: Dissolution of rayon fibers for size exclusion chromatography: a challenge
verfasst von: Martin Siller
Kyujin Ahn
Nicole Pircher
Thomas Rosenau
Antje Potthast
Publikationsdatum: 01.10.2014
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 5/2014
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-014-0356-6

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