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01.04.2015 | Original Paper

Fibrous cellulose membrane mass produced via forcespinning^® for lithium-ion battery separators

verfasst von: Baicheng Weng, Fenghua Xu, Mataz Alcoutlabi, Yuanbing Mao, Karen Lozano

Erschienen in: Cellulose | Ausgabe 2/2015

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Abstract

In this study, fibrous cellulose membranes were successfully mass produced by forcespinning^® cellulose acetate, followed by alkaline hydrolysis treatment. Its performance as lithium-ion battery separator was evaluated. The cellulose membrane exhibits a randomly-oriented, fully-interconnected and highly porous three-dimensional fibrous network structure with a high porosity of 76 %. The developed membranes show good electrolyte wettability and high electrolyte uptake capability. Differential scanning calorimetry and thermal treatment show a superior thermal stability of the cellulose nonwoven membrane. Compared to commercially available polypropylene based separators, the developed fibrous cellulose membrane displays higher ionic conductivity, lower interfacial resistance and better electrochemical stability. Given its outstanding thermal characteristics and excellent electrochemical performance, this fibrous cellulose membrane has potential to be used as high-performance lithium-ion battery separator. This study provides a novel and feasible pathway for developing promising separators for high-performance lithium ion batteries.

Vorheriger Artikel Preparation and catalytic performance of Fe(III)-citric acid-modified cotton fiber complex as a novel cellulose fiber-supported heterogeneous photo-Fenton catalyst

Nächster Artikel Cellulose diacetate films as a solid-phase matrix for fluorescence analysis of pyrene traces in aqueous media

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Titel: Fibrous cellulose membrane mass produced via forcespinning® for lithium-ion battery separators
verfasst von: Baicheng Weng
Fenghua Xu
Mataz Alcoutlabi
Yuanbing Mao
Karen Lozano
Publikationsdatum: 01.04.2015
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 2/2015
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-015-0564-8

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