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A green and simple method for preparation of an efficient palladium adsorbent based on cysteine functionalized 2,3-dialdehyde cellulose

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Abstract

A green and efficient adsorbent for adsorption of palladium ions was prepared from 2,3-dialdehyde cellulose (DAC) originating from nanocellulose from the green algae Cladophora. The DAC was functionalized with cysteine via reductive amination in a convenient one-pot procedure to provide the adsorbent. The adsorption properties for adsorbing palladium(II) ions, including capacity, adsorption isotherm and kinetics, were studied. The successful reductive amination of cysteine with 2,3-dialdehyde cellulose was confirmed by FT-IR, elemental analysis and XPS. The adsorbent was characterized by SEM, XRD, gas adsorption and TGA. The adsorbent had a high adsorption capacity (130 mg palladium per gram adsorbent) and enabled fast adsorption of palladium(II) ions from solution (80 % of maximum capacity reached in 2 h). Adsorbent materials suitable for both filters (fibrous) and column matrixes (spherical particles) could be obtained in an efficient manner by controlling the degree of oxidation while producing the DAC material.

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Acknowledgments

Ollie and Elof Ericsson´s Foundation as well as the Bo Rydin Foundation are gratefully acknowledged for their financial support. Changqing Ruan thanks the China Scholarship Council (CSC) for financial support.

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  1. Nanotechnology and Functional Materials, Department of Engineering Sciences, Uppsala University, Box 534, 75121, Uppsala, Sweden

    Changqing Ruan, Maria Strømme & Jonas Lindh

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  1. Changqing Ruan
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  2. Maria Strømme
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  3. Jonas Lindh
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Correspondence to Jonas Lindh.

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Ruan, C., Strømme, M. & Lindh, J. A green and simple method for preparation of an efficient palladium adsorbent based on cysteine functionalized 2,3-dialdehyde cellulose. Cellulose 23, 2627–2638 (2016). https://doi.org/10.1007/s10570-016-0976-0

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