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Erschienen in: Cellulose 5/2016

05.08.2016 | Original Paper

Modification of microcrystalline cellulose with pyridone derivatives for removal of cationic dyes from aqueous solutions

verfasst von: Chang Sun, Zhiyong Huang, Jiaxin Wang, Liming Rao, Jingjing Zhang, Jiao Yu, Jinmei Du, Changhai Xu

Erschienen in: Cellulose | Ausgabe 5/2016

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Abstract

Microcrystalline cellulose (MCC) was modified with pyridone derivatives such as pyridone diester (PDE) and pyridone diacid (PDA) by using succinic acid anhydride as a linker. The modified MCCs were characterized by the fourier transform infrared spectroscopy, scanning electron microscopy, thermal gravimetric analysis, elemental analysis and solid state 13C NMR. The adsorption capacities of the modified MCCs to cationic dyes were examined by using methylene blue (MB) as a model dye. It was found that the kinetic adsorption data followed the pseudo-second-order kinetic model, and the adsorption equilibriums were reached less than 10 min. The isothermal adsorption data were fitted with the Langmuir isotherm model very well, from which the maximum adsorption capacities of the MCCs modified with PDE and PDA were determined to be 101.01 and 142.86 mg/g, respectively. Further investigation showed that the modified MCCs were pH-dependent for adsorption of MB in aqueous solutions. The modified MCCs could be used for removal of MB from an aqueous solution at pH 8, and reused by regeneration in an acidic solution. It was tested that the modified MCCs had a high reusability for removal of MB from aqueous solutions, and still maintained high adsorption capacities even after multiple cycles of desorption–adsorption processes. Hence, the MCCs modified with PDE and PDA could be an effective and efficient approach to removal of cationic dyes from aqueous solutions.

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Literatur
Zurück zum Zitat Batmaz R, Mohammed N, Zaman M, Minhas G, Berry RM, Tam KC (2014) Cellulose nanocrystals as promising adsorbents for the removal of cationic dyes. Cellulose 21:1655–1665CrossRef Batmaz R, Mohammed N, Zaman M, Minhas G, Berry RM, Tam KC (2014) Cellulose nanocrystals as promising adsorbents for the removal of cationic dyes. Cellulose 21:1655–1665CrossRef
Zurück zum Zitat Chan CH, Chia CH, Zakaria S, Sajab MS, Chin SX (2015) Cellulose nanofibrils: a rapid adsorbent for the removal of methylene blue. RSC Adv 5:18204–18212CrossRef Chan CH, Chia CH, Zakaria S, Sajab MS, Chin SX (2015) Cellulose nanofibrils: a rapid adsorbent for the removal of methylene blue. RSC Adv 5:18204–18212CrossRef
Zurück zum Zitat Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresour Technol 97:1061–1085CrossRef Crini G (2006) Non-conventional low-cost adsorbents for dye removal: a review. Bioresour Technol 97:1061–1085CrossRef
Zurück zum Zitat Duan C, Zhao N, Yu X, Zhang X, Xu J (2013) Chemically modified kapok fiber for fast adsorption of Pb2+, Cd2+, Cu2+ from aqueous solution. Cellulose 20:849–860CrossRef Duan C, Zhao N, Yu X, Zhang X, Xu J (2013) Chemically modified kapok fiber for fast adsorption of Pb2+, Cd2+, Cu2+ from aqueous solution. Cellulose 20:849–860CrossRef
Zurück zum Zitat Forgacs E, Cserháti T, Oros G (2004) Removal of synthetic dyes from wastewaters: a review. Environ Int 30:953–971CrossRef Forgacs E, Cserháti T, Oros G (2004) Removal of synthetic dyes from wastewaters: a review. Environ Int 30:953–971CrossRef
Zurück zum Zitat Gupta VK, Suhas (2009) Application of low-cost adsorbents for dye removal – a review. J Environ Manag 90:2313–2342CrossRef Gupta VK, Suhas (2009) Application of low-cost adsorbents for dye removal – a review. J Environ Manag 90:2313–2342CrossRef
Zurück zum Zitat Gurgel LVA, Júnior OK, Gil RPF, Gil LF (2008) Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by cellulose and mercerized cellulose chemically modified with succinic anhydride. Bioresour Technol 99:3077–3083CrossRef Gurgel LVA, Júnior OK, Gil RPF, Gil LF (2008) Adsorption of Cu(II), Cd(II), and Pb(II) from aqueous single metal solutions by cellulose and mercerized cellulose chemically modified with succinic anhydride. Bioresour Technol 99:3077–3083CrossRef
Zurück zum Zitat Gurgel LVA, Perin de Melo JC, de Lena JC, Gil LF (2009) Adsorption of chromium (VI) ion from aqueous solution by succinylated mercerized cellulose functionalized with quaternary ammonium groups. Bioresour Technol 100:3214–3220CrossRef Gurgel LVA, Perin de Melo JC, de Lena JC, Gil LF (2009) Adsorption of chromium (VI) ion from aqueous solution by succinylated mercerized cellulose functionalized with quaternary ammonium groups. Bioresour Technol 100:3214–3220CrossRef
Zurück zum Zitat Gurnani V, Singh AK, Venkataramani B (2003) Cellulose based macromolecular chelator having pyrocatechol as an anchored ligand: synthesis and applications as metal extractant prior to their determination by flame atomic absorption spectrometry. Talanta 61:889–903CrossRef Gurnani V, Singh AK, Venkataramani B (2003) Cellulose based macromolecular chelator having pyrocatechol as an anchored ligand: synthesis and applications as metal extractant prior to their determination by flame atomic absorption spectrometry. Talanta 61:889–903CrossRef
Zurück zum Zitat He X, Male KB, Nesterenko PN, Brabazon D, Paull B, Luong JHT (2013) Adsorption and desorption of methylene blue on porous carbon monoliths and nanocrystalline cellulose. ACS Appl Mater Interfaces 5:8796–8804CrossRef He X, Male KB, Nesterenko PN, Brabazon D, Paull B, Luong JHT (2013) Adsorption and desorption of methylene blue on porous carbon monoliths and nanocrystalline cellulose. ACS Appl Mater Interfaces 5:8796–8804CrossRef
Zurück zum Zitat Ho YS, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ 76:332–340CrossRef Ho YS, McKay G (1998) A comparison of chemisorption kinetic models applied to pollutant removal on various sorbents. Process Saf Environ 76:332–340CrossRef
Zurück zum Zitat Jin L, Li W, Xu Q, Sun Q (2015) Amino-functionalized nanocrystalline cellulose as an adsorbent for anionic dyes. Cellulose 22:2443–2456CrossRef Jin L, Li W, Xu Q, Sun Q (2015) Amino-functionalized nanocrystalline cellulose as an adsorbent for anionic dyes. Cellulose 22:2443–2456CrossRef
Zurück zum Zitat Liu X, Zhou Y, Nie W, Song L, Chen P (2015a) Fabrication of hydrogel of hydroxypropyl cellulose (HPC) composited with graphene oxide and its application for methylene blue removal. J Mater Sci 50:6113–6123CrossRef Liu X, Zhou Y, Nie W, Song L, Chen P (2015a) Fabrication of hydrogel of hydroxypropyl cellulose (HPC) composited with graphene oxide and its application for methylene blue removal. J Mater Sci 50:6113–6123CrossRef
Zurück zum Zitat Liu Y, Shen J, Sun C, Ren C, Zeng H (2015b) Intramolecularly hydrogen-bonded aromatic pentamers as modularly tunable macrocyclic receptors for selective recognition of metal ions. J Am Chem Soc 137:12055–12063CrossRef Liu Y, Shen J, Sun C, Ren C, Zeng H (2015b) Intramolecularly hydrogen-bonded aromatic pentamers as modularly tunable macrocyclic receptors for selective recognition of metal ions. J Am Chem Soc 137:12055–12063CrossRef
Zurück zum Zitat Mohammed N, Grishkewich N, Berry RM, Tam KC (2015) Cellulose nanocrystal–alginate hydrogel beads as novel adsorbents for organic dyes in aqueous solutions. Cellulose 22:3725–3738CrossRef Mohammed N, Grishkewich N, Berry RM, Tam KC (2015) Cellulose nanocrystal–alginate hydrogel beads as novel adsorbents for organic dyes in aqueous solutions. Cellulose 22:3725–3738CrossRef
Zurück zum Zitat O’Connell DW, Birkinshaw C, O’Dwyer TF (2006) A chelating cellulose adsorbent for the removal of Cu(II) from aqueous solutions. J Appl Polym Sci 99:2888–2897CrossRef O’Connell DW, Birkinshaw C, O’Dwyer TF (2006) A chelating cellulose adsorbent for the removal of Cu(II) from aqueous solutions. J Appl Polym Sci 99:2888–2897CrossRef
Zurück zum Zitat Qiao H, Zhou Y, Yu F, Wang E, Min Y, Huang Q, Pang L, Ma T (2015) Effective removal of cationic dyes using carboxylate-functionalized cellulose nanocrystals. Chemosphere 141:297–303CrossRef Qiao H, Zhou Y, Yu F, Wang E, Min Y, Huang Q, Pang L, Ma T (2015) Effective removal of cationic dyes using carboxylate-functionalized cellulose nanocrystals. Chemosphere 141:297–303CrossRef
Zurück zum Zitat Ren C, Maurizot V, Zhao H, Shen J, Zhou F, Ong WQ, Du Z, Zhang K, Su H, Zeng H (2011) Five-fold-symmetric macrocyclic aromatic pentamers: high-affinity cation recognition, ion-pair-induced columnar stacking, and nanofibrillation. J Am Chem Soc 133:13930–13933CrossRef Ren C, Maurizot V, Zhao H, Shen J, Zhou F, Ong WQ, Du Z, Zhang K, Su H, Zeng H (2011) Five-fold-symmetric macrocyclic aromatic pentamers: high-affinity cation recognition, ion-pair-induced columnar stacking, and nanofibrillation. J Am Chem Soc 133:13930–13933CrossRef
Zurück zum Zitat Tabakci M, Erdemir S, Yilmaz M (2007) Preparation, characterization of cellulose-grafted with calix[4]arene polymers for the adsorption of heavy metals and dichromate anions. J Hazard Mater 148:428–435CrossRef Tabakci M, Erdemir S, Yilmaz M (2007) Preparation, characterization of cellulose-grafted with calix[4]arene polymers for the adsorption of heavy metals and dichromate anions. J Hazard Mater 148:428–435CrossRef
Zurück zum Zitat Xiong J, Jiao C, Li C, Zhang D, Lin H, Chen Y (2014) A versatile amphiprotic cotton fiber for the removal of dyes and metal ions. Cellulose 21:3073–3087CrossRef Xiong J, Jiao C, Li C, Zhang D, Lin H, Chen Y (2014) A versatile amphiprotic cotton fiber for the removal of dyes and metal ions. Cellulose 21:3073–3087CrossRef
Zurück zum Zitat Yan H, Zhang W, Kan X, Dong L, Jiang Z, Li H, Yang H, Cheng R (2011) Sorption of methylene blue by carboxymethyl cellulose and reuse process in a secondary sorption. Colloids Surf A 380:143–151CrossRef Yan H, Zhang W, Kan X, Dong L, Jiang Z, Li H, Yang H, Cheng R (2011) Sorption of methylene blue by carboxymethyl cellulose and reuse process in a secondary sorption. Colloids Surf A 380:143–151CrossRef
Zurück zum Zitat Zhang G, Yi L, Deng H, Sun P (2014) Dyes adsorption using a synthetic carboxymethyl cellulose-acrylic acid adsorbent. J Env Sci 26:1203–1211CrossRef Zhang G, Yi L, Deng H, Sun P (2014) Dyes adsorption using a synthetic carboxymethyl cellulose-acrylic acid adsorbent. J Env Sci 26:1203–1211CrossRef
Zurück zum Zitat Zhou Y, Zhang M, Hu X, Wang X, Niu J, Ma T (2013) Adsorption of cationic dyes on a cellulose-based multicarboxyl adsorbent. J Chem Eng Data 58:413–421CrossRef Zhou Y, Zhang M, Hu X, Wang X, Niu J, Ma T (2013) Adsorption of cationic dyes on a cellulose-based multicarboxyl adsorbent. J Chem Eng Data 58:413–421CrossRef
Zurück zum Zitat Zhou Y, Zhang M, Wang X, Huang Q, Min Y, Ma T, Niu J (2014) Removal of crystal violet by a novel cellulose-based adsorbent: comparison with native cellulose. Ind Eng Chem Res 53:5498–5506CrossRef Zhou Y, Zhang M, Wang X, Huang Q, Min Y, Ma T, Niu J (2014) Removal of crystal violet by a novel cellulose-based adsorbent: comparison with native cellulose. Ind Eng Chem Res 53:5498–5506CrossRef
Metadaten
Titel
Modification of microcrystalline cellulose with pyridone derivatives for removal of cationic dyes from aqueous solutions
verfasst von
Chang Sun
Zhiyong Huang
Jiaxin Wang
Liming Rao
Jingjing Zhang
Jiao Yu
Jinmei Du
Changhai Xu
Publikationsdatum
05.08.2016
Verlag
Springer Netherlands
Erschienen in
Cellulose / Ausgabe 5/2016
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI
https://doi.org/10.1007/s10570-016-1024-9

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