nach oben

Cellulose

Erschienen in:

02.11.2017 | Original Paper

Cellulose nanofibers/silk fibroin nanohybrid sponges with highly ordered and multi-scale hierarchical honeycomb structure

verfasst von: Kezheng Gao, Yaqing Guo, Qingyuan Niu, Lifeng Han, Linsen Zhang, Yong Zhang, Lizhen Wang

Erschienen in: Cellulose | Ausgabe 1/2018

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Highly ordered cellulose nanofibers/silk fibroin nanohybrid (CSN) honeycomb materials with multi-scale hierarchical architectures are successfully prepared from CSN hydrogel precursors using unidirectional freeze-drying technique. Cellulose nanofibers have an outstanding highly ordered honeycomb structure-directing function in composite hydrogel. However, silk fibroin does not have such function. Therefore, the properties of the CSN sponges can be effectively adjusted by simple changing the ratio of cellulose nanofibers to silk fibroin. When the content of silk fibroin reaches 50%, the CSN-50 sponge exhibits a nearly perfect highly ordered honeycomb structure with multi-scale hierarchical architectures. And the Brunauer–Emmett–Teller specific surface area is about 120 m² g⁻¹.

Vorheriger Artikel Nanofibrous alginate membrane coated with cellulose nanowhiskers for water purification

Nächster Artikel Mechanisms contributing to mechanical property changes in composites of polypropylene reinforced with spray-dried cellulose nanofibrils

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Nur mit Berechtigung zugänglich

Besbes I, Alila S, Boufi S (2011) Nanofibrillated cellulose from TEMPO-oxidized eucalyptus fibres: effect of the carboxyl content. Carbohydr Polym 84(3):975–983CrossRef

Chen J, Zhuang A, Shao H, Hu X, Zhang Y (2017) Robust silk fibroin/bacterial cellulose nanoribbon composite scaffolds with radial lamellae and intercalation structure for bone regeneration. J Mater Chem B 5(20):3640–3650CrossRef

Cote F, Russell BP, Deshpande VS, Fleck NA (2009) The through-thickness compressive strength of a composite sandwich panel with a hierarchical square honeycomb sandwich core. J Appl Mech T ASME. https://doi.org/10.1115/1.3086436 CrossRef

Deville S (2008) Freeze-casting of porous ceramics: a review of current achievements and issues. Adv Eng Mater 10(3):155–169CrossRef

Deville S, Saiz E, Nalla RK, Tomsia AP (2006) Freezing as a path to build complex composites. Science 311(5760):515–518CrossRef

Fratzl P, Weinkamer R (2007) Nature’s hierarchical materials. Prog Mater Sci 52(8):1263–1334CrossRef

Fujisawa S, Okita Y, Fukuzumi H, Saito T, Isogai A (2011) Preparation and characterization of TEMPO-oxidized cellulose nanofibril films with free carboxyl groups. Carbohydr Polym 84(1):579–583CrossRef

Gao K, Shao Z, Li J, Wang X, Peng X, Wang W, Wang F (2013a) Cellulose nanofiber–graphene all solid-state flexible supercapacitors. J Mater Chem A 1(1):63–67CrossRef

Gao K, Shao Z, Wang X, Zhang Y, Wang W, Wang F (2013b) Cellulose nanofibers/multi-walled carbon nanotube nanohybrid aerogel for all-solid-state flexible supercapacitors. RSC Adv 3(35):15058–15064CrossRef

Habibi MK, Lu Y (2014) Crack propagation in Bamboo’s hierarchical cellular structure. Sci Rep. https://doi.org/10.1038/srep05598 CrossRefPubMedPubMedCentral

Isogai A, Saito T, Fukuzumi H (2011) TEMPO-oxidized cellulose nanofibers. Nanoscale 3(1):71–85CrossRef

Kim KN, Chun J, Chae SA, Ahn CW, Kim IW, Kim S-W, Wang ZL, Baik JM (2015) Silk fibroin-based biodegradable piezoelectric composite nanogenerators using lead-free ferroelectric nanoparticles. Nano Energy 14:87–94CrossRef

Lasseuguette E, Roux D, Nishiyama Y (2008) Rheological properties of microfibrillar suspension of TEMPO-oxidized pulp. Cellulose 15(3):425–433CrossRef

Lee JM, Kim JH, Lee OJ, Park CH (2013) The fixation effect of a silk fibroin–bacterial cellulose composite plate in segmental defects of the zygomatic arch an experimental study. JAMA Otolaryngol 139(6):629–635

Li X-G, Wu LY, Huang MR, Shao H-L, Hu X-C (2008) Conformational transition and liquid crystalline state of regenerated silk fibroin in water. Biopolymers 89(6):497–505CrossRef

Li WL, Lu K, Walz JY (2012) Freeze casting of porous materials: review of critical factors in microstructure evolution. Int Mater Rev 57(1):37–60CrossRef

Lin N, Cao L, Huang Q, Wang C, Wang Y, Zhou J, Liu X-Y (2016) Functionalization of silk fibroin materials at mesoscale. Adv Funct Mater 26(48):8885–8902CrossRef

Matsubara EY, Lala SM, Rosolen JM (2010) Lithium storage into carbonaceous materials obtained from sugarcane bagasse. J Braz Chem Soc 21(10):1877–1884CrossRef

Montanari S, Rountani M, Heux L, Vignon MR (2005) Topochemistry of carboxylated cellulose nanocrystals resulting from TEMPO-mediated oxidation. Macromolecules 38(5):1665–1671CrossRef

Niu QY, Guo YQ, Gao KZ, Shao ZQ (2016) Polypyrrole/cellulose nanofiber aerogel as a supercapacitor electrode material. RSC Adv 6(110):109143–109149CrossRef

Ochi A, Hossain KS, Magoshi J, Nemoto N (2002) Rheology and dynamic light scattering of silk fibroin solution extracted from the middle division of Bombyx mori silkworm. Biomacromol 3(6):1187–1196CrossRef

Okita Y, Saito T, Isogai A (2009) TEMPO-mediated oxidation of softwood thermomechanical pulp. Holzforschung 63(5):529–535CrossRef

Okita Y, Saito T, Isogai A (2010) Entire surface oxidation of various cellulose microfibrils by TEMPO-mediated oxidation. Biomacromol 11(6):1696–1700CrossRef

Oliveira Barud HG, Barud HDS, Cavicchioli M, do Amaral TS, de Oliveira Junior OB, Santos DM, de Oliveira Almeida Petersen AL, Celes F, Borges VM, de Oliveira CI, de Oliveira PF, Furtado RA, Tavares DC, Ribeiro SJL (2015) Preparation and characterization of a bacterial cellulose/silk fibroin sponge scaffold for tissue regeneration. Carbohydr Polym 128:41–51CrossRef

Pan Z-Z, Nishihara H, Iwamura S, Sekiguchi T, Sato A, Isogai A, Kang F, Kyotani T, Yang Q-H (2016) Cellulose nanofiber as a distinct structure-directing agent for xylem-like microhoneycomb monoliths by unidirectional freeze-drying. ACS Nano 10(12):10689–10697CrossRef

Qin DC, Zhang F, Dong SY, Zhao YZ, Xu GY, Zhang XG (2016) Analogous graphite carbon sheets derived from corn stalks as high performance sodium-ion battery anodes. RSC Adv 6(108):106218–106224CrossRef

Qiu L, Liu JZ, Chang SLY, Wu Y, Li D (2012) Biomimetic superelastic graphene-based cellular monoliths. Nat Commun. https://doi.org/10.1038/ncomms2251 CrossRefPubMedPubMedCentral

Saito T, Nishiyama Y, Putaux J-L, Vignon M, Isogai A (2006) Homogeneous suspensions of individualized microfibrils from TEMPO-catalyzed oxidation of native cellulose. Biomacromol 7(6):1687–1691CrossRef

Saito T, Kimura S, Nishiyama Y, Isogai A (2007) Cellulose nanofibers prepared by TEMPO-mediated oxidation of native cellulose. Biomacromol 8(8):2485–2491CrossRef

Saito T, Hirota M, Tamura N, Isogai A (2010) Oxidation of bleached wood pulp by TEMPO/NaClO/NaClO₂ system: effect of the oxidation conditions on carboxylate content and degree of polymerization. J Wood Sci 56(3):227–232CrossRef

Saito T, Uematsu T, Kimura S, Enomae T, Isogai A (2011) Self-aligned integration of native cellulose nanofibrils towards producing diverse bulk materials. Soft Matter 7(19):8804–8809CrossRef

Schoof H, Apel J, Heschel I, Rau G (2001) Control of pore structure and size in freeze-dried collagen sponges. J Biomed Mater Res 58(4):352–357CrossRef

Si Y, Wang X, Yan C, Yang L, Yu J, Ding B (2016) Ultralight biomass-derived carbonaceous nanofibrous aerogels with superelasticity and high pressure-sensitivity. Adv Mater 28(43):9512–9518CrossRef

Song L, Li L, Gao X, Zhao J, Lu T, Liu Z (2015) A facile synthesis of a uniform constitution of three-dimensionally ordered macroporous TiO₂-carbon nanocomposites with hierarchical pores for lithium ion batteries. J Mater Chem A 3(13):6862–6872CrossRef

Taylor CM, Smith CW, Miller W, Evans KE (2011) The effects of hierarchy on the in-plane elastic properties of honeycombs. Int J Solids Struct 48(9):1330–1339CrossRef

Terry AE, Knight DP, Porter D, Vollrath F (2004) PH induced changes in the rheology of silk fibroin solution from the middle division of Bombyx mori silkworm. Biomacromol 5(3):768–772CrossRef

Wicklein B, Kocjan A, Salazar-Alvarez G, Carosio F, Camino G, Antonietti M, Bergstrom L (2015) Thermally insulating and fire-retardant lightweight anisotropic foams based on nanocellulose and graphene oxide. Nat Nanotechnol 10(3):277–283CrossRef

Yun YS, Cho SY, Shim J, Kim BH, Chang S-J, Baek SJ, Huh YS, Tak Y, Park YW, Park S, Jin H-J (2013) Microporous carbon nanoplates from regenerated silk proteins for supercapacitors. Adv Mater 25(14):1993–1998CrossRef

Zhang F, Lu Q, Ming J, Dou H, Liu Z, Zuo B, Qin M, Li F, Kaplan DL, Zhang X (2014) Silk dissolution and regeneration at the nanofibril scale. J Mater Chem B 2(24):3879–3885CrossRef

Titel: Cellulose nanofibers/silk fibroin nanohybrid sponges with highly ordered and multi-scale hierarchical honeycomb structure
verfasst von: Kezheng Gao
Yaqing Guo
Qingyuan Niu
Lifeng Han
Linsen Zhang
Yong Zhang
Lizhen Wang
Publikationsdatum: 02.11.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1545-x

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 1/2018

Effect of lignin on the morphology and rheological properties of nanofibrillated cellulose produced from γ-valerolactone/water fractionation process

Effect of glycerol, nanoclay and graphene oxide on physicochemical properties of biodegradable nanocellulose plastic sourced from banana pseudo-stem

Water resistant nanopapers prepared by lactic acid modified cellulose nanofibers

Enhanced anti-microbial, anti-creasing and dye absorption properties of cotton fabric treated with Chitosan–Cyanuric Chloride hybrid

Understanding the interactions of cellulose fibres and deep eutectic solvent of choline chloride and urea

Modification of cellulose thin films with lysine moieties: a promising approach to achieve antifouling performance