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13.11.2017 | Original Paper

Chitosan/partially sulfonated poly(vinylidene fluoride) blends as polymer electrolyte membranes for direct methanol fuel cell applications

verfasst von: V. Vijayalekshmi, Dipak Khastgir

Erschienen in: Cellulose | Ausgabe 1/2018

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Abstract

A novel proton exchange membranes composed of a blend of chitosan and sulfonated polyvinylidene fluoride (SPVDF) was prepared by solution casting technique. The PVDF was sulfonated using direct sulfonation method with sulfonation degree of 6.1%. The membranes with different fractions of SPVDF were prepared and 10 wt% SPVDF exhibits the best performance in terms of ion exchange capacity, conductivity, water uptake and membrane selectivity. The prepared blend membranes show excellent combination of thermal stability, mechanical properties, dimensional stability and methanol barrier properties. Chitosan (CS)-SPVDF-90/10 membrane shows the highest proton conductivity of 2.85 × 10⁻² S cm⁻¹ at 90 °C.

Vorheriger Artikel TiO2-grafted cellulose via click reaction: an efficient heavy metal ions bioadsorbent from aqueous solutions

Nächster Artikel Towards a new generation of functional fiber-based packaging: cellulose nanofibers for improved barrier, mechanical and surface properties

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Titel: Chitosan/partially sulfonated poly(vinylidene fluoride) blends as polymer electrolyte membranes for direct methanol fuel cell applications
verfasst von: V. Vijayalekshmi
Dipak Khastgir
Publikationsdatum: 13.11.2017
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 1/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-017-1565-6

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