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02.07.2018 | Original Paper

Green acid-free one-step hydrothermal ammonium persulfate oxidation of viscose fiber wastes to obtain carboxylated spherical cellulose nanocrystals for oil/water Pickering emulsion

verfasst von: Shounuan Ye, Hou-Yong Yu, Duanchao Wang, Jiaying Zhu, Jiping Gu

Erschienen in: Cellulose | Ausgabe 9/2018

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Abstract

Textile manufacturing industries produce large amounts of viscose fiber wastes (VFW), causing serious environmental pollution. This study presents an acid-free approach to prepare spherical cellulose nanocrystals (SCNs) with carboxyl groups from industrial VFW by one-step hydrothermal ammonium persulfate (APS) oxidation. Novel double-response surface methodology was employed to optimize the reaction conditions. A maximum yield (37.89%) of carboxylated SCN was obtained at reaction time of 4 h, APS concentration of 1 M and temperature of 80 °C, while the SCNs showed gradual size reductions along with increase of carboxyl contents as reaction time and APS concentration increased. Interestingly, it was possible to obtain carboxylated SCNs in only 2 h of reaction with an increase of 16.5% in the crystallinity index, which was attributed to efficient swelling of cellulose chains and oxidation interaction of surface groups under hydrothermal condition. Compared with SCN-2 h, the crystallinity index and maximum degradation temperature of SCN-10 h were improved by 5.5% and 17.9 °C, respectively. Moreover, SCN-10 h exhibited excellent emulsifying capacity to stabilize soybean oil/water Pickering emulsion droplets and emulsion volume were increased with decreased mean diameter of emulsion droplets as SCN-10 h concentration increased. These results indicate that VFW is an attractive source to produce carboxylated SCNs by APS oxidation, making SCN extraction as value-added alternatives to recycle this waste. Such carboxylated SCNs have great potentials as green food Pickering emulsion stabilizers and nanofillers in high-performance composites.

Vorheriger Artikel Preparation and characterization of a bi-layered nano-filtration membrane from a chitosan hydrogel and bacterial cellulose nanofiber for dye removal

Nächster Artikel Use of sulfated cellulose nanocrystals towards stability enhancement of gelatin-encapsulated tea polyphenols

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Titel: Green acid-free one-step hydrothermal ammonium persulfate oxidation of viscose fiber wastes to obtain carboxylated spherical cellulose nanocrystals for oil/water Pickering emulsion
verfasst von: Shounuan Ye
Hou-Yong Yu
Duanchao Wang
Jiaying Zhu
Jiping Gu
Publikationsdatum: 02.07.2018
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 9/2018
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-018-1917-x

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