nach oben

Cellulose

Erschienen in:

24.01.2019 | Original Research

Robust and durable superhydrophobic cotton fabrics via a one-step solvothermal method for efficient oil/water separation

verfasst von: Quan-Yong Cheng, Cheng-Shu Guan, Yi-Dong Li, Jiang Zhu, Jian-Bing Zeng

Erschienen in: Cellulose | Ausgabe 4/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config

KI-gestützte Suche

Aus

Abstract

Traditional superhydrophobic cotton fabrics (CF) demonstrate various advantages such as self-cleaning, water repelling and efficient oil/water separation capacity but limited practical applications due to their poor mechanical robustness and environmental durability. In this work, robust and durable superhydrophobic polydivinylbenzene (PDVB) coated CF (PDVB@CF) are fabricated via a simple one-step, fluorine-free, and inorganic nanoparticle-free solvothermal method. The PDVB@CF displays excellent chemical resistance without losing superhydrophobicity after immersing in various organic solvents, strong acid and alkali solutions for a long time. The PDVB@CF shows excellent mechanical robustness to resist sandpaper abrasion and ultrasonication treatment. Furthermore, the PDVB@CF exhibits outstanding high and low temperature resistances since the contact angle of either acidic or alkali droplets is greater than 150° after isothermal treatment at 200 °C or immersion in liquid nitrogen for 3 h. The PDVB@CF is very efficient in separating water mixtures with various oily compounds with separation efficiency of higher than 98% and flux up to 56 k L m⁻² h⁻¹ depending on characteristics of the oils. In addition, the PDVB@CF shows excellent recyclability with superhydrophobicity and separation efficiency that remained after 10 separation cycles. The PDVB@CF with excellent robustness and durability exhibits potential utility in oil/water separation even under some harsh conditions.

Vorheriger Artikel Facile synthesis of a novel, highly effective, more sustainable and cost-effective cationic bleach activator for cotton: N-[4-(N,N,N)-triethylammoniumchloride-butyryl] caprolactam

Nächster Artikel Functionalization of cotton fabric with bismuth oxyiodide nanosheets: applications for photodegrading organic pollutants, UV shielding and self-cleaning

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

über 67.000 Bücher
über 390 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Maschinenbau + Werkstoffe

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

über 102.000 Bücher
über 537 Zeitschriften

aus folgenden Fachgebieten:

Automobil + Motoren
Bauwesen + Immobilien
Business IT + Informatik
Elektrotechnik + Elektronik
Energie + Nachhaltigkeit
Finance + Banking
Management + Führung
Marketing + Vertrieb
Maschinenbau + Werkstoffe
Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Bellanger H, Darmanin T, Givenchy ET, Guittard F (2014) Chemical and physical pathways for the preparation of superoleophobic surfaces and related wetting theories. Chem Rev 114:2694–2716. https://doi.org/10.1021/cr400169m CrossRefPubMed

Cao CY, Ge MZ, Huang JY, Li SH, Deng S, Zhang SN, Chen Z, Zhang KQ, Al-Deyab SS, Lai YK (2016) Robust fluorine-free superhydrophobic PDMS–ormosil@ fabrics for highly effective self-cleaning and efficient oil–water separation. J Mater Chem A 4:12179–12187. https://doi.org/10.1039/c6ta04420d CrossRef

Chen JT, Shen CH, Yang SD, Rana M, Ma PC (2017) Acid and temperature dual-responsive cotton fabrics with polymer coating. Compos Commun 4:10–15. https://doi.org/10.1016/j.coco.2017.03.003 CrossRef

Chen DZ, Mai ZH, Liu X, Ye DZ, Zhang HW, Yin XZ, Zhou YS, Liu M, Xu WL (2018) UV-blocking, superhydrophobic and robust cotton fabrics fabricated using polyvinylsilsesquioxane and nano-TiO₂. Cellulose 25:3635–3647. https://doi.org/10.1007/s10570-018-1790-7 CrossRef

Cheng QY, An XP, Li YD, Huang CL, Zeng JB (2017) Sustainable and biodegradable superhydrophobic coating from epoxidized soybean oil and ZnO nanoparticles on cellulosic substrates for efficient oil/water. ACS Sustain Chem Eng 5:11440–11450. https://doi.org/10.1021/acssuschemeng.7b02549 CrossRef

Cheng QY, Guan CS, Wang M, Li YD, Zeng JB (2018a) Cellulose nanocrystal coated cotton fabric with superhydrophobicity for efficient oil/water separation. Carbohydr Polym 199:390–396. https://doi.org/10.1016/j.carbpol.2018.07.046 CrossRefPubMed

Cheng QY, Liu MC, Li YD, Zhu J, Du AK, Zeng JB (2018b) Biobased super-hydrophobic coating on cotton fabric fabricated by spray-coating for efficient oil/water separation. Polym Test 66:41–47. https://doi.org/10.1016/j.polymertesting.2018.01.005 CrossRef

Chu ZL, Feng YJ, Seeger S (2015) Oil/water separation with selective superantiwetting/superwetting surface materials. Angew Chem Int Ed 54:2328–2338. https://doi.org/10.1002/anie.201405785 CrossRef

Dou YH, Tian DL, Sun ZQ, Liu QN, Zhang N, Kim JH, Jiang L, Dou SX (2017) Fish gill inspired crossflow for efficient and continuous collection of spilled oil. ACS Nano 11:2477–2485. https://doi.org/10.1021/acsnano.6b07918 CrossRefPubMed

Feng L, Li S, Li Y, Li H, Zhang L, Zhai J, Song Y, Liu B, Jiang L, Zhu D (2002) Super-hydrophobic surfaces: from natural to artificial. Adv Mater 14:1857–1860. https://doi.org/10.1002/adma.200290020 CrossRef

Gao L, McCarthy TJ (2006) “Artificial lotus leaf” prepared using a 1945 patent and a commercial textile. Langmuir 22:5998–6000. https://doi.org/10.1021/la061237x CrossRefPubMed

Gao QH, Hu JT, Li R, Pang LJ, Xing Z, Xu L, Wang MH, Guo XJ, Wu GZ (2016) Preparation and characterization of superhydrophobic organic-inorganic hybrid cotton fabrics via γ-radiation-induced graft polymerization. Carbohydr Polym 20:308–316. https://doi.org/10.1016/j.carbpol.2016.04.124 CrossRef

Gao SW, Dong XL, Huang JY, Li SH, Li YW, Chen Z, Lai YK (2017) Rational construction of highly transparent superhydrophobic coatings based on a non-particle, fluorine-free and water-rich system for versatile oil/water separation. Chem Eng J 333:621–629. https://doi.org/10.1016/j.cej.2017.10.006 CrossRef

Ghobashy MM, Elhady MA (2017) Radiation crosslinked magnetized wax (PE/Fe₃O₄) nano composite for selective oil adsorption. Compos Commun 3:18–22. https://doi.org/10.1016/j.coco.2016.12.001 CrossRef

Guo F, Wen QY, Peng YB, Guo ZG (2017) Simple one-pot approach toward robust and boiling-water resistant superhydrophobic cotton fabric and the application in oil/water separation. J Mater Chem A 5:21866–21874. https://doi.org/10.1039/c7ta05599d CrossRef

Hou K, Zeng YC, Zhou CL, Chen JH, Chen XF, Xu SP, Cheng J, Pi PH (2018) Facile generation of robust POSS-based superhydrophobic fabrics via thiolene click chemistry. Chem Eng J 332:150–159. https://doi.org/10.1016/j.cej.2017.09.074 CrossRef

Huang JY, Li SH, Ge MZ, Wang LN, Xing TL, Chen GQ, Liu XF, Al-Deyab SS, Zhang KQ, Chen T, Lai YK (2015) Robust superhydrophobic TiO₂@fabrics for UV shielding, self-cleaning and oil–water separation. J Mater Chem A 3:2825–2832. https://doi.org/10.1039/c4ta05332j CrossRef

Ivshina B, Kuyukina MS, Krivoruchko AV, Elkin AA, Makarov SO, Cunningham CJ, Peshkur TA, Atlas RM, Philp JC (2015) Oil spill problems and sustainable response strategies through new technologies. Environ Sci Process Impacts 17:1201–1219. https://doi.org/10.1039/c5em00070j CrossRefPubMed

Jian SZ, Qi ZY, Sun SR, Zeng Y, Liu ZW, Liu YQ, Song LX, Ma GH (2018) Design and fabrication of superhydrophobic/superoleophilic Ni₃S₂-nanorods/Ni-mesh for oil–water separation. Surf Coat Technol 337:370–378. https://doi.org/10.1016/j.surfcoat.2018.01.039 CrossRef

Jin YX, Jiang P, Ke QP, Cheng FH, Zhu YSN, Zhang YX (2015) Superhydrophobic and superoleophilic polydimethylsiloxane-coated cotton for oil–water separation process: an evidence of the relationship between its loading capacity and oil absorption ability. J Hazard Mater 300:175–181. https://doi.org/10.1016/j.jhazmat.2015.07.002 CrossRefPubMed

Li Y, Chen SS, Wu MC, Sun JQ (2014) All spraying processes for the fabrication of robust, self-healing, superhydrophobic coatings. Adv Mater 26:3344–3348. https://doi.org/10.1002/adma.201306136 CrossRefPubMed

Li J, Yan L, Zhao YX, Zha F, Wang QT, Lei ZQ (2015a) One-step fabrication of robust fabrics with both-faced superhydrophobicity for the separation and capture of oil from water. Phys Chem Chem Phys 17:6451–6457. https://doi.org/10.1039/c5cp90057c CrossRefPubMed

Li SH, Huang JY, Ge MZ, Li SW, Xing TL, Chen GQ, Liu YQ, Zhang KQ, Al-Deyab SS, Lai YK (2015b) Controlled grafting superhydrophobic cellulose surface with environmentally-friendly short fluoroalkyl chains by ATRP. Mater Des 85:815–822. https://doi.org/10.1016/j.matdes.2015.07.083 CrossRef

Li Y, He LL, Zhang XF, Zhang N, Tian DL (2017a) External-field-induced gradient wetting for controllable liquid transport: from movement on the surface to penetration into the surface. Adv Mater 29:1703802. https://doi.org/10.1002/adma.201703802 CrossRef

Li YM, Li Q, Zhang CQ, Cai P, Bai NN, Xu X (2017b) Intelligent self-healing superhydrophobic modification of cotton fabrics via surface-initiated ARGET ATRP of styrene. Chem Eng J 323:134–142. https://doi.org/10.1016/j.cej.2017.04.080 CrossRef

Li MF, Li YQ, Chang KQ, Cheng P, Liu K, Liu QZ, Wang YD, Lu ZT, Wang D (2018) The poly(vinyl alcohol-co-ethylene) nanofiber/silica coated composite membranes for oil/water and oil-in-water emulsion separation. Compos Commun 7:69–73. https://doi.org/10.1016/j.coco.2018.01.001 CrossRef

Liu H, Huang JY, Chen Z, Chen GQ, Zhang KQ, Al-Deyab SS, Lai YK (2017) Robust translucent superhydrophobic PDMS/PMMA film by facile one-step spray for self-cleaning and efficient emulsion separation. Chem Eng J 330:26–35. https://doi.org/10.1016/j.cej.2017.07.114 CrossRef

Nyström D, Lindqvist J, Östmark E, Antoni P, Carlmark A, Hult A, Malmström E (2009) Superhydrophobic and self-cleaning bio-fiber surfaces via ATRP and subsequent postfunctionalization. ACS Appl Mater Interfaces 1:816–823. https://doi.org/10.1021/am800235e CrossRefPubMed

Ouyang SS, Wang T, Jia XY, Chen Y, Yao JM, Wang S (2016) Self-indicating and recyclable superhydrophobic membranes for effective oil/water separation in harsh conditions. Mater Des 96:357–363. https://doi.org/10.1016/j.matdes.2016.02.032 CrossRef

Piltan S, Seyfi J, Hejazi I, Davachi SM, Khonakdar HA (2016) Superhydrophobic filter paper via an improved phase separation process for oil/water separation: study on surface morphology, composition and wettability. Cellulose 23:3913–3924. https://doi.org/10.1007/s10570-016-1059-y CrossRef

Roach P, Shirtcliffe NJ, Newton MI (2008) Progress in superhydrophobic surface development. Soft Matter 4:224–240. https://doi.org/10.1039/b712575p CrossRef

Sasaki K, Tenjimbayashi M, Manaba K, Shiratori S (2016) Asymmetric superhydrophobic/superhydrophilic cotton fabrics designed by spraying polymer and nanoparticles. ACS Appl Mater Interfaces 8:651–659. https://doi.org/10.1021/acsami.5b09782 CrossRefPubMed

Si YF, Guo ZG, Liu WM (2016) A robust epoxy resins @ stearic acid-Mg(OH)₂ micronanosheet superhydrophobic omnipotent protective coating for real-life applications. ACS Appl Mater Interfaces 8:16511–16520. https://doi.org/10.1021/acsami.6b04668 CrossRefPubMed

Sun X, Xue B, Tian Y, Qin S, Xie L (2018) 3D porous poly(l-lactic acid) materials with controllable multi-scale microstructures and their potential application in oil–water separation. Appl Surf Sci 462:633–640. https://doi.org/10.1016/j.apsusc.2018.08.119 CrossRef

Wang ZJ, Wang Y, Liu GJ (2013) Rapid and efficient separation of oil from oil-in-water emulsions using a janus cotton fabric. Angew Chem Int Ed 55:1291–1294. https://doi.org/10.1002/anie.201507451 CrossRef

Wang B, Liang WX, Guo ZG, Liu WM (2015a) Biomimetic super-lyophobic and super-lyophilic materials applied for oil/water separation: a new strategy beyond nature. Chem Soc Rev 44:336–361. https://doi.org/10.1039/c4cs00220b CrossRefPubMed

Wang G, He Y, Wang H, Zhang L, Yu QY, Peng SS, Wu XD, Ren TH, Zeng ZX, Xue QJ (2015b) A cellulose sponge with robust superhydrophilicity and under-water superoleophobicity for highly effective oil/water separation. Green Chem 17:3093–3099. https://doi.org/10.1039/c5gc00025d CrossRef

Wu MC, Ma BH, Pan TZ, Chen SS, Sun JQ (2016a) Silver-nanoparticle-colored cotton fabrics with tunable colors and durable antibacterial and self-healing superhydrophobic properties. Adv Funct Mater 26:569–576. https://doi.org/10.1002/adfm.201504197 CrossRef

Wu YQ, Jia SS, Qing Y, Luo S, Liu M (2016b) A versatile and efficient method to fabricate durable superhydrophobic surfaces on wood, lignocellulosic fiber, glass, and metal substrates. J Mater Chem A 4:14111–14121. https://doi.org/10.1039/c6ta05259b CrossRef

Wu H, Wu LH, Lu SC, Lin XX, Xiao H, Ouyang XH, Cao SL, Chen LH, Huang LL (2018) Robust superhydrophobic and superoleophilic filter paper via atom transfer radical polymerization for oil/water separation. Carbohydr Polym 181:419–425. https://doi.org/10.1016/j.carbpol.2017.08.078 CrossRefPubMed

Xie WY, Song F, Wang XL, Wang YZ (2017) Development of copper phosphate nanoflowers on soy protein toward a superhydrophobic and self-cleaning film. ACS Sustain Chem Eng 5:869–875. https://doi.org/10.1021/acssuschemeng.6b02199 CrossRef

Xu ZG, Zhao Y, Wang HX, Wang XG, Lin TA (2015) A superamphiphobic coating with an ammonia-triggered transition to superhydrophilic and superoleophobic for oil–water separation. Angew Chem Int Ed 54:4527–4530. https://doi.org/10.1002/anie.201411283 CrossRef

Xue CH, Ma JZ (2013) Long-lived superhydrophobic surfaces. J Mater Chem A 1:4146–4161. https://doi.org/10.1039/C2TA01073A CrossRef

Yang MP, Liu WQ, Jiang C, He S, Xie YK, Wang ZF (2018) Fabrication of superhydrophobic cotton fabric with fluorinated TiO₂ sol by a green and one-step sol–gel process. Carbohydr Polym 197:75–82. https://doi.org/10.1016/j.carbpol.2018.05.075 CrossRefPubMed

Zeng Q, Ding C, Li QS, Yuan W, Peng Y, Hu JC, Zhang KQ (2017) Rapid fabrication of robust, washable, self-healing superhydrophobic fabrics with non-iridescent structural color by facile spray coating. RSC Adv 7:8443–8452. https://doi.org/10.1039/c6ra26526j CrossRef

Zhang L, Li HQ, Lai XJ, Su XJ, Liang T, Zeng XR (2017) Thiolated graphene-based superhydrophobic sponges for oil–water separation. Chem Eng J 316:736–743. https://doi.org/10.1016/j.cej.2017.02.030 CrossRef

Zheng X, Guo ZY, Tian DL, Zhang XF, Li WX, Jiang L (2015) Underwater self-cleaning scaly fabric membrane for oily water separation. ACS Appl Mater Interfaces 7:4336–4343. https://doi.org/10.1021/am508814g CrossRefPubMed

Zhou XY, Zhang ZZ, Xu XH, Guo F, Zhu XT, Men XH, Ge B (2013) Robust and durable superhydrophobic cotton fabrics for oil/water separation. ACS Appl Mater Interfaces 5:7208–7214. https://doi.org/10.1021/am4015346 CrossRefPubMed

Zhou S, Liu P, Wang M, Zhao H, Yang J, Xu F (2016) Sustainable, reusable, and superhydrophobic aerogels from microfibrillated cellulose for highly effective oil/water separation. ACS Sustain Chem Eng 4:6409–6416. https://doi.org/10.1021/acssuschemeng.6b01075 CrossRef

Zhou CL, Chen ZD, Yang H, Hou K, Zeng XJ, Zheng YF, Cheng J (2017) Nature-inspired strategy toward superhydrophobic fabrics for versatile oil/water separation. ACS Appl Mater Interfaces 9:9184–9194. https://doi.org/10.1021/acsami.7b00412 CrossRefPubMed

Titel: Robust and durable superhydrophobic cotton fabrics via a one-step solvothermal method for efficient oil/water separation
verfasst von: Quan-Yong Cheng
Cheng-Shu Guan
Yi-Dong Li
Jiang Zhu
Jian-Bing Zeng
Publikationsdatum: 24.01.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 4/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02267-6

Springer Professional

Abstract

Bitte loggen Sie sich ein, um Zugang zu Ihrer Lizenz zu erhalten.

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Technik"

Springer Professional "Wirtschaft+Technik"

Weitere Artikel der Ausgabe 4/2019

Dimethyl sulfoxide assisted dissolution of cellulose in 1-ethyl-3-methylimidazoium acetate: small angle neutron scattering and rheological studies

Esterified cellulose nanocrystals as reinforcement in poly(lactic acid) nanocomposites

Review on cellulosic fibers extracted from date palms (Phoenix Dactylifera L.) and their applications

Flexible and recyclable SERS substrate fabricated by decorated TiO2 film with Ag NPs on the cotton fabric

Synergistic effect of hetero- and homo-catalysts on the ‘green’ synthesis of 5-hydroxymethylfurfural from chitosan biomass

Reactive Blue-25 dye/TiO2 coated cotton fabrics with self-cleaning and UV blocking properties