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Cellulose

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27.03.2019 | Original Research

Enzymatic production of cello-oligomers with endoglucanases

verfasst von: Stefanie Kluge, Benjamin Bonhage, Jörn Viell, Mari Granström, Alois Kindler, Antje C. Spiess

Erschienen in: Cellulose | Ausgabe 7/2019

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Abstract

Cello-oligomers have a wide application range and are gained from three different cello-oligomer production paths, which show different drawbacks, namely acid or alkaline hydrolysis of cellulose, chemical or enzymatic synthesis, and enzymatic hydrolysis of cellulose using cellulase mixtures. Therefore, this study aims at a novel route towards cello-oligomers using purified endoglucanases. From the renewable raw material cellulose, pretreated by an ionic liquid, cello-oligomers with a weight average degree of polymerization (DP_W) of 65 were directly obtained by enzymatic hydrolysis. During hydrolysis, between 14.1 and 24.5 mass percent of monomeric and dimeric sugars were formed as byproduct. A second ionic liquid pretreatment of the cellulose, remaining after the first hydrolysis, and a second enzymatic hydrolysis resulted in cello-oligomers with a DP of 35. XRD deconvolution and Raman analysis confirmed that crystallinity remained unchanged during enzymatic cellulose hydrolysis.

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Vorheriger Artikel A structural fibrillation parameter from small angle X-ray scattering to quantify pulp refining

Nächster Artikel Adsorption of aromatic compounds by biochar: influence of the type of tropical biomass precursor

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Titel: Enzymatic production of cello-oligomers with endoglucanases
verfasst von: Stefanie Kluge
Benjamin Bonhage
Jörn Viell
Mari Granström
Alois Kindler
Antje C. Spiess
Publikationsdatum: 27.03.2019
Verlag: Springer Netherlands
Erschienen in: Cellulose / Ausgabe 7/2019
Print ISSN: 0969-0239
Elektronische ISSN: 1572-882X
DOI: https://doi.org/10.1007/s10570-019-02390-4

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Abstract

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