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Trace Metal Distribution and Enrichment in Benthic, Estuarine Sediments: Southport Broadwater, Australia

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Abstract

The distribution and enrichment of selected trace metals (Cd, Cr, Cu, Ni, Pb, Sn, Zn) in benthic sediments of the Southport Broadwater, a semi-enclosed coastal body of water adjacent to the Gold Coast city, south-eastern Queensland, Australia, was studied with the objective of assessing the extent and degree of sediment contamination. Sediment samples from the 0–10 cm and 10–20 cm depth intervals of 32 sites within the Southport Broadwater and surrounding residential canals were analysed for particle size distribution, pH, organic C and ‘near-total’ major (Al, Ca, Fe, Mn) and trace (Cd, Cr, Cu, Ni, Pb, Sn, Zn) metal contents. Sediment contamination for each trace metal was assessed by (1) comparison with Australian sediment quality guidelines, (2) calculation of the index of geoaccumulation based on regional background values, and (3) geochemical normalisation against Al (i.e. the abundance of alumino-silicate clay minerals). Based on this approach, the results indicate that submerged sediments in the study area are not presently enriched with Cd, Cr or Ni, with the spatial distribution of these metals being very well explained by the abundance of alumino-silicate clay minerals. However, several sites were strongly enriched with Cu, Pb, Sn and Zn, arising from sources related to either urban runoff or vessel maintenance activities. The study indicates that several varying approaches are needed for a satisfactory assessment of contaminant enrichment in estuarine sediments.

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References

  • M. Aloupi MO. Angelidis (2001) ArticleTitleGeochemistry of natural and anthropogenic metals in the coastal sediments of the island of Levos, Aegean Sea Environ pollut 113 211–219 Occurrence Handle10.1016/S0269-7491(00)00173-1

    Article  Google Scholar 

  • ANZECC/ARMCANZ. (2000) Australian and New Zealand Guidelines for Fresh and Marine Water Quality . Australian and New Zealand Environment and Conservation Council, and Agriculture and Resource Management Council of Australia and New Zealand, pp. 3.5–1 to 3.5–2

  • GF Birch D. Evenden ME. Teutsch (1996) ArticleTitleDominance of point sources in heavy metal distributions in sediments of a major Sydney estuary (Australia) Environ Geol 28 169–174 Occurrence Handle10.1007/s002540050090

    Article  Google Scholar 

  • G. Birch S. Taylor (1999) ArticleTitleSource of heavy metals in sediments of the Port Jackson estuary, Australia Science of the Total Environment 227 123–138 Occurrence Handle10.1016/S0048-9697(99)00007-8

    Article  Google Scholar 

  • RA. Berner (1981) ArticleTitleA new geochemical classification of sedimentary environments Jour Sediment Petrol 51 359–369

    Google Scholar 

  • WJ. BryanGW Langston (1992) ArticleTitleBioavailability, accumulation and effects of heavy metals in sediments with special reference to United Kingdom estuaries: a review Environ Pollut 80 89–131 Occurrence Handle10.1016/0269-7491(92)90099-V

    Article  Google Scholar 

  • E Carral X Puente A. VillaresR Carballeira (1995) ArticleTitleBackground heavy metals in estuarine sediments and organisms in Galicia (northwest Spain) as determined by modal analysis Sci Total Environ 172 175–188 Occurrence Handle10.1016/0048-9697(95)04788-3

    Article  Google Scholar 

  • SDW Comber MJ Gardner C. GunnAM Whalley (1996) ArticleTitleKinetics of trace metal sorption to estuarine suspended particulate matter Chemosphere 33 1027–1040 Occurrence Handle10.1016/0045-6535(96)00244-5

    Article  Google Scholar 

  • PR. Cosser (1989) ArticleTitleWater quality, sediments and the macroinvertebrate community of residential canal estates in south-east Queensland, Australia: A multivariate analysis Water Res 23 1087–1097 Occurrence Handle10.1016/0043-1354(89)90152-8

    Article  Google Scholar 

  • A. Danielsson (2000) ArticleTitleSpatial scales for metals and nutrient concentrations in sediments Environmetrics 11 523–539 Occurrence Handle10.1002/1099-095X(200009/10)11:5<523::AID-ENV454>3.0.CO;2-8

    Article  Google Scholar 

  • W Dannecker M Au H. Stechmann (1990) ArticleTitleSubstance load in rainwater runoff from different streets in Hamburg Sci Total Environ 93 385–395 Occurrence Handle10.1016/0048-9697(90)90129-I

    Article  Google Scholar 

  • J. Deely (1993) ArticleTitleThe impact of Christchurch City (New Zealand) on heavy metals in sediments of the Avon-Heathcote estuary Water Sci Technol 28 369–382

    Google Scholar 

  • SJ Mora ParticleDe C Stewart D. Phillips (1995) ArticleTitleSources and rate of degradation of tri(n -butyl)tin in marine sediments near Auckland, New Zealand Mar Pollut Bull 30 50–57 Occurrence Handle10.1016/0025-326X(94)00178-C

    Article  Google Scholar 

  • SJ Mora ParticleDe E. Pelletier (1997) ArticleTitleEnvironmental tributyltin research: past, present, future Environ Technol 18 1169–1179

    Google Scholar 

  • FCF Paula ParticleDe AA. Mozeto (2001) ArticleTitleBiogeochemical evolution of␣trace elements in a pristine watershed in the Brazilian southeastern coastal region Appl Geochem 16 1139–1151 Occurrence Handle10.1016/S0883-2927(00)00084-6

    Article  Google Scholar 

  • EF Doyle HP Dokkum Particlevan CJW Vermulst DL. Anderson Moss (1995) ArticleTitleDevice for sampling unconsolidated soft-bottom sediments in moderately deep waters J Environ Qual. 24 786–788

    Google Scholar 

  • KR. Dyer (1973) Estuaries: A Physical Introduction John Wiley and Sons NewYork

    Google Scholar 

  • U Forstner GTW. Wittmann (1979) Metal Pollution in the Marine Environment Springer-Verlag Berlin

    Google Scholar 

  • RW Furness PS. Rainbow (1990) Heavy Metals in the Marine Environment CRC Press Boca Raton

    Google Scholar 

  • BD Honeyman PH. Santschi (1988) ArticleTitleMetals in aquatic systems Environ Sci Technol 22 862–871 Occurrence Handle10.1021/es00173a002

    Article  Google Scholar 

  • RJ Huggett MA Unger PF Seligman AO. Valkirs (1992) ArticleTitleThe marine biocide tributyltin: assessing and managing the environmental risks Environ Sci Technol 26 232–237 Occurrence Handle10.1021/es00026a001

    Article  Google Scholar 

  • RJ Gibbs (1993) ArticleTitleMetals of the bottom muds in Townsville harbor, Australia Environ Pollut 81 297–300 Occurrence Handle10.1016/0269-7491(93)90212-7

    Article  Google Scholar 

  • ED Goldberg (1986) ArticleTitleTBT: An environmental dilemma Environment 28 17–44

    Google Scholar 

  • CK Jain D. Ram (1997) ArticleTitleAdsorption of lead and zinc on bed sediments of the River Kali Water Res 31 154–162 Occurrence Handle10.1016/S0043-1354(96)00232-1

    Article  Google Scholar 

  • A Karageorgis C Anagnostou A Sioulas G Chronis E Papathanassiou (1998) ArticleTitleSediment geochemistry and mineralogy in Milos bay, SW Kyklades, Aegean Sea, Greece J Mar Syst 16 269–281 Occurrence Handle10.1016/S0924-7963(97)00020-1

    Article  Google Scholar 

  • J. Liebens (2001) ArticleTitleHeavy metal contamination of sediments in stormwater management systems: the effect of land use, particle size, and age Environ Geol 41 341–351 Occurrence Handle10.1007/s002540100392

    Article  Google Scholar 

  • WN Lindall L. Trent (1975) ArticleTitleHousing development canals in the coastal zone of the Gulf of Mexico: ecological consequences, regulations, and recommendations Mar Fish Rev 37 19–24

    Google Scholar 

  • KL Linge CE. Oldham (2002) ArticleTitleArsenic remobilisation in a shallow lake: The role of sediment resuspension J Environ Quality 31 822–828 Occurrence Handle10.2134/jeq2002.0822

    Article  Google Scholar 

  • ER Long DD MacDonald SL Smith ED Calder (1995) ArticleTitleIncidence of adverse biological effects within ranges of chemical concentrations in marine and estuarine sediments Environ Manage 19 81–97

    Google Scholar 

  • DH Loring RTT. Rantala (1992) ArticleTitleManual for the geochemical analyses of marine sediments and suspended particulate matter Earth Sci Rev 32 235–283 Occurrence Handle10.1016/0012-8252(92)90001-A

    Article  Google Scholar 

  • DK Makepeace DW Smith SJ. Stanley (1995) ArticleTitleUrban stormwater quality: Summary of contaminant data Critic Rev Environ Sci Technol 25 93–139 Occurrence Handle10.1080/10643389509388476

    Article  Google Scholar 

  • JV Marcias-Zamora JA Villaescusa-Celaya A Munoz-Barbosa G. Gold-Bouchot (1999) ArticleTitleTrace metals in sediment cores from the Campeche shelf, Gulf of Mexico Environ Pollut 104 69–77 Occurrence Handle10.1016/S0269-7491(98)00153-5

    Article  Google Scholar 

  • RJ Morrison SP Narayan P. Gangaiya (2001) ArticleTitleTrace element studies in Laucala Bay, Suva, Fiji Mar Pollut Bull 42 397–404 Occurrence Handle10.1016/S0025-326X(00)00169-7

    Article  Google Scholar 

  • Moss A, Costanzo S. (1998) Levels of heavy metals in the sediments of Queensland rivers, estuaries and coastal waters. Department of Environment, Queensland Government. Environment technical report No. 20. Brisbane, Australia

  • Moss A, Cox M. (1999) Southport Broadwater and adjacent Pacific Ocean: water quality study 1979–1998. Environmental Protection Agency, Queensland Government. Environmental Technical Report No. 31. Brisbane, Australia

  • G. Muller (1979) ArticleTitleSchwermetalle in den sedimenten des Rheins-Veranderungen seitt 1971 Umschan 79 778–783

    Google Scholar 

  • F Mwanuzi F. De Smedt (1999) ArticleTitleHeavy metal distribution model under estuarine mixing Hydrol Processes 13 789–804 Occurrence Handle10.1002/(SICI)1099-1085(19990415)13:5<789::AID-HYP781>3.0.CO;2-F

    Article  Google Scholar 

  • Nelson DW, Sommers, LE. (1996) Total carbon, organic carbon, and organic matter. In Sparks DL. ed. Methods of Soil Analysis. Part 3. Chemical methods. Madison, Wisconsin, USA: Soil Science Society of America and American Society of Agronomy

  • PM Nuttal BJ. Richardson (1988) ArticleTitleEnvironmental effects of canal estates in Australia Water 14 14–17

    Google Scholar 

  • RB Owen N. Sandhu (2000) ArticleTitleHeavy metal accumulation and anthropogenic impacts on Tolo Harbour, Hong Kong Mar Pollut Bull 40 174–180 Occurrence Handle10.1016/S0025-326X(99)00201-5

    Article  Google Scholar 

  • MAA Paalman CH Weijden Particlevan der JPG. Loch (1994) ArticleTitleSorption of cadmium on suspended matter under estuarine conditions: competition and complexation with major sea-water ions Water Air Soil Pollut. 73 49–60 Occurrence Handle10.1007/BF00477975

    Article  Google Scholar 

  • E Pelletier C. Normandeau (1997) ArticleTitleDistribution of butyltin residues in mussels and sea stars of the St Lawrence estuary Environ Technol 18 1203–1209 Occurrence Handle10.1080/09593331808616641

    Article  Google Scholar 

  • JB Percival PJ. Lindsay (1997) Measurement of physical properties of sediments A Mudrock JM Azcue P Mudrock (Eds) Manual of physico-chemical analysis of aquatic sediments CRC Press Lewis Publishers New York USA 56–56

    Google Scholar 

  • GF Riedel JG Sanders RW. Osman (1997) ArticleTitleBiogeochemical control on the flux of trace elements from estuarine sediments: water column oxygen concentrations and benthic infauna Estuarine Coast Shelf Sci 44 23–38 Occurrence Handle10.1006/ecss.1996.0114

    Article  Google Scholar 

  • BL Rhoads RA. Cahill (1999) ArticleTitleGeomorphological assessment of sediment contamination in an urban stream system Appl Geochem 14 459–483 Occurrence Handle10.1016/S0883-2927(98)00061-4

    Article  Google Scholar 

  • Rothery E. (1986) Analytical Methods for Zeeman Graphite Tube Atomisers. Publication No. 85–100650–00, Victoria, Australia: Varian Techtron Pty Ltd

  • B Rubio MA Nombela F. Vilas (2000) ArticleTitleGeochemistry of major and trace elements in sediments of the Ria de Vigo (NW Spain): an assessment of metal pollution Mar. Pollut Bull 40 968–980 Occurrence Handle10.1016/S0025-326X(00)00039-4

    Article  Google Scholar 

  • W Salomons U. Forstner (1984) Metals in the Hydrocycle Springer-Verlag Berlin

    Google Scholar 

  • I Saulnier A. Mucci (2000) ArticleTitleTrace metal remobilisation following the resuspension of estuarine sediments: saguenay Fjord, Canada Appl Geochem 15 203–222 Occurrence Handle10.1016/S0883-2927(99)00034-7

    Article  Google Scholar 

  • TR. Schueler (1994) ArticleTitlePollutant dynamics of pond muck Watershed Protect Technol 1 39–46

    Google Scholar 

  • V Simeonov DL Massart G Andreev S. Tsakovski (2000) ArticleTitleAssessment of metal pollution based on multivariate statistical modelling of ‘hot-spot’ sediments from the Black Sea Chemosphere 41 1411–1417 Occurrence Handle10.1016/S0045-6535(99)00540-8

    Article  Google Scholar 

  • C Stewart SJ. Mora Particlede (1992) ArticleTitleElevated tri(n -butyl)tin concentrations in shellfish and sediments from Suva Harbour, Fiji Appl Organomet Chem 6 507–512 Occurrence Handle10.1002/aoc.590060606

    Article  Google Scholar 

  • NFY Tam MWY. Yao (1998) ArticleTitleNormalisation and heavy metal contamination in mangrove sediments Sci. Total Environ. 216 33–39 Occurrence Handle10.1016/S0048-9697(98)00132-6

    Article  Google Scholar 

  • B Thamdrup H Fossing BB. Jorgensen (1994) ArticleTitleManganese, iron␣and sulfur cycling in a coastal marine sediment, Aarhus Bay, Denmark Geochimica et Cosmochim Acta 58 5115–5129 Occurrence Handle10.1016/0016-7037(94)90298-4

    Article  Google Scholar 

  • AV Tkalin BJ Presley PN. Boothe (1996) ArticleTitleSpatial and temporal variations of trace metals in bottom sediments of Peter the Great Bay, the Sea of Japan Environ Pollut 92 3–78 Occurrence Handle10.1016/0269-7491(95)00083-6

    Article  Google Scholar 

  • Tomlinson R, Phillips I. (2001) Contaminant loadings in submerged sediments from marinas and coastal waterways in south-east Queensland. Annual Report-Project No. 22004. Prepared for the Cooperative Research Centre for Sustainable Tourism

  • Townsend, SA. (1993) Inputs of nutrient, suspended solid and metal loads from point and non-point sources in Darwin Harbour. Proceedings of AWWA 15th Federal Convention, Gold Coast, April 1993.

  • CB Tuit GE Ravizza MH. Bothner (2000) ArticleTitleAnthropogenic platinum and palladium in the sediments of Boston Harbor Environ Sci Technol 34 927–932 Occurrence Handle10.1021/es990666x

    Article  Google Scholar 

  • KK Turekian KH. Wedepohl (1961) ArticleTitleDistribution of the elements in some major units of the earth’s crust Bull Geol Soc Am 72 175–192

    Google Scholar 

  • USEPA (United States Environmental Protection Agency): (1986) Acid digestion of sediment, sludge and soils. In Test Methods for Evaluating Solid Wastes . EPA SW-846. Washington, DC: US Government Printing Office

  • USEPA (United States Environmental Protection Agency) (1997) The Incidence and Severity of Sediment Contamination in Surface Waters of the United States. Volume 1: National Sediment Quality Survey . EPA 823-R-97–006. Washington, DC: US Government Printing Office

  • USEPA (United States Environmental Protection Agency) (2001) Methods for Collection, Storage and Manipulation of Sediments for Chemical and Toxicological Analyses: Technical Manual. EPA 823-B-01–002. Washington, DC: US Government Printing Office

  • X Wen HE. Allen (1999) ArticleTitleMobilization of heavy metals from Le An River sediment Sci Total Environ 227 101–108 Occurrence Handle10.1016/S0048-9697(99)00002-9

    Article  Google Scholar 

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Burton, E.D., Phillips, I.R. & Hawker, D.W. Trace Metal Distribution and Enrichment in Benthic, Estuarine Sediments: Southport Broadwater, Australia. Environ Geochem Health 27, 369–383 (2005). https://doi.org/10.1007/s10653-004-7086-x

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