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Presence, distribution, and origins of polycyclic aromatic hydrocarbons (PAHs) in sediments from Bahía Blanca estuary, Argentina

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Abstract

This paper is the first comprehensive survey of polycyclic aromatic hydrocarbons (PAHs) in coastal sediments in Bahia Blanca, Argentina, and provides useful information on their levels of concentration, composition, and sources of these pollutants. The total concentrations of PAHs ranged from 15 to 10,260 ng g − 1. The highest contents (mean 3,315 ng g − 1) of total PAHs in marine sediments were found in the inner channels of the estuary, while the lower ones (204 ng g − 1) belong to samples collected far away from contamination sources. The global average recorded in this study (1,500 ng g − 1) indicates that the studied area lies within the referenced category of industrialized coastal zones under chronic pollution. The diagenetic PAH contribution was found to be negligible at all sampled locations; however, the calculation of molecular ratios determined an overimposition of pyrolitic PAHs over the petrogenic input. Further, the use of principal components analysis (PCA) clearly separated ring group compounds and enabled the determination of pyrolitic/combustion PAHs dominancy.

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Authors and Affiliations

  1. Instituto Argentino de Oceanografía (IADO), CCT-CONICET, Bahía Blanca. C.C.N° 804, Bahía Blanca, Argentina

    Andrés H. Arias & Jorge Marcovecchio

  2. Instituto de Ciencias del Mar y Limnología, Universidad Nacional Autónoma de México (UNAM), México D.F., México

    Alfonso Vazquez-Botello & Guadalupe Ponce-Vélez

  3. Química Ambiental, Universidad Nacional del Sur, Av.Alem 1253, Bahía Blanca, Rep. Argentina

    Norma Tombesi & Hugo Freije

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  1. Andrés H. Arias
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  2. Alfonso Vazquez-Botello
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  3. Norma Tombesi
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  4. Guadalupe Ponce-Vélez
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  5. Hugo Freije
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  6. Jorge Marcovecchio
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Correspondence to Andrés H. Arias.

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Arias, A.H., Vazquez-Botello, A., Tombesi, N. et al. Presence, distribution, and origins of polycyclic aromatic hydrocarbons (PAHs) in sediments from Bahía Blanca estuary, Argentina. Environ Monit Assess 160, 301–314 (2010). https://doi.org/10.1007/s10661-008-0696-5

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