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Volatile organic compounds in air at urban and industrial areas in the Tarragona region by thermal desorption and gas chromatography–mass spectrometry

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Abstract

Annual trends of a group of 66 volatile organic compounds (VOCs), containing 20 ozone precursors, were the aim of a sampling campaign carried out for a year in air at urban and industrial areas from Tarragona region. VOCs were determined by active collection on multisorbent tubes, followed by thermal desorption and gas chromatography–mass spectrometry. The analytical method was developed and validated, showing good levels of detection and quantification, recoveries, precision, and linearity for all the compounds in the range being studied. All the industrial and urban samples taken during the sampling campaign were similar in their qualitative composition. The most abundant compound in all urban and industrial sites was i-pentane, with concentrations between 15.2 and 202.1 μg m − 3 in urban sites and between 1.3 and 98.6 μg m − 3 in industrial sites. In urban sites, the following compounds in order of abundance were toluene, n-pentane, m,p-xylene, and o-xylene, with maximum levels of 150.6, 45.8, 42.3, and 31.7 μg m − 3, respectively. In industrial sites, the most abundant compounds depended on the sampled site.

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  1. Departament de Química Analítica i Química Orgànica, Universitat Rovira i Virgili, Campus Sescelades, Marcel·lí Domingo, s/n, 43007, Tarragona, Spain

    Maria Rosa Ras, Rosa Maria Marcé & Francesc Borrull

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  1. Maria Rosa Ras
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  2. Rosa Maria Marcé
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  3. Francesc Borrull
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Correspondence to Rosa Maria Marcé.

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Ras, M.R., Marcé, R.M. & Borrull, F. Volatile organic compounds in air at urban and industrial areas in the Tarragona region by thermal desorption and gas chromatography–mass spectrometry. Environ Monit Assess 161, 389–402 (2010). https://doi.org/10.1007/s10661-009-0755-6

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