Abstract
The Yanqi Basin in Xinjiang Province is an important agricultural area with a high population density. The extensive agricultural activities in the Yanqi Basin started in the 1950s with flood irrigation techniques. Since then, the groundwater table was raised because of the absence of an efficient drainage system. This obstacle is a crucial factor that restricts sustainable socioeconomic development. Hydrochemical investigations were conducted in the Yanqi Basin, Northwestern China, to determine the chemical composition of groundwater. Sixty groundwater samples were collected from different wells to monitor the water chemistry of various ions. The results of the chemical analysis indicate that the groundwater in the area is generally neutral to slightly alkaline and predominantly contains Na+ and Ca2+ cations as well as HCO3 − and SO4 2+ anions. High positive correlations between HCO3 −–Mg2+ + Ca2+, SO 4 2−–Mg2+, SO4 2−–Na+ + K+, and Cl−–Na+ + K+ were obtained. The total dissolved solids (TDS) mainly depend on the concentration of major ions such as HCO3 −, SO4 2−, Cl−, Ca2+, Mg2+, and Na+ + K+. The dominant hydrochemical facies for groundwater are Ca2+–Mg2+–HCO3 −, Mg2+–Ca2+–SO4 2−–Cl−, Na+–K+–Cl−–SO4 2−, and Na+–K+–Mg2+–Cl−–HCO3 − types. The hydrochemical processes are the main factors that determine the water quality of the groundwater system. These processes include silicate mineral weathering, dissolution, ion exchange, and, to a lesser extent, evaporation, which seem to be more pronounced downgradient of the flow system. The saturation index (SI), which is calculated according to the ionic ratio plot, indicates that the gypsum–halite dissolution reactions occur during a certain degree of rock weathering. SI also indicates that evaporation is the dominant factor that determines the major ionic composition in the study area. The assessment results of the water samples using various methods indicate that the groundwater in the study area is generally hard, fresh to brackish, high to very high saline, and low alkaline in nature. The high total hardness and TDS of the groundwater in several places indicate the unsuitability of the groundwater for drinking and irrigation. These areas require particular attention, particularly in the construction of adequate drainage as well as in the introduction of an alternative salt tolerance cropping.
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Adomako, D., Osae, S., Akiti, T. T., et al. (2011). Geochemical and isotopic studies of groundwater conditions in the Densu River Basin of Ghana. Environmental Earth Sciences, 62, 1071–1084. doi:10.1007/s12665-010-0595-2.
Anupam, S., Abhay, K. S., & Kamlesh, K. (2012). Environmental geochemistry and quality assessment of surface and subsurface water of Mahi River basin, western India. Environmental Earth Sciences, 65, 1231–1250. doi:10.1007/s12665-011-1371-7.
Banoeng-Yakubo, B., Yidana, S. M., & Nti, E. (2009). An evaluation of the genesis and suitability of groundwater for irrigation in the Volta Region, Ghana. Environmental Geology, 57, 1005–1010. doi:10.1007/s00254-008-1385-y.
Brunner, P., Li, H. T., Kinzelbach, W., Li, W. P., et al. (2008). Extracting phreatic evaporation from remotely sensed maps of evapotranspiration. Water Resources Research, 44, W08428. doi:10.1029/2007WR006063.
Cloutier, V., Lefebvre, R., Therrien, R., et al. (2008). Multivariate statistical analysis of geochemical data as indicative of the hydrogeochemical evolution of groundwater in a sedimentary rock aquifer. Journal of Hydrology, 353, 294–313.
Deutsch, W. J. (1997). Groundwater geochemistry: fundamentals and application to contamination. Boca Raton: CRC.
Dong, X., Jiang, T., & Jiang, H. (2001). Study on the pattern of water resources utilisation and environmental conservation of Yanqi basin. In G. Li (Ed.), Development, planning and management of surface and groundwater resources, IAHR congress proceedings, vol. A (pp. 333–340). Beijing: Tsinghua University Press.
Eaton, F. M. (1950). Significance of carbonate in irrigation water. Soil Science, 69(2), 123–133.
Giridharan, L., Venugopal, T., & Jayaprakash, M. (2008). Evaluation of the seasonal variation on the geochemical parameters and quality assessment of the groundwater in the proximity of River Cooum, Chennai, India. Environmental Monitoring and Assessment, 143, 161–178.
Guler, C., Thyne, G. D., McCray, E. J., et al. (2002). Evaluation of graphical and multivariate statistical methods for classification of water chemistry data. Hydrogeology Journal, 10, 455–474.
Han, D. M., Liang, X., Jin, M., et al. (2009). Hydrogeochemical indicators of groundwater flow systems in the Yangwu River Alluvial Fan, Xinzhou Basin, Shanxi, China. Environmental Management, 44, 243–255.
Han, D. M., Liang, X., Jin, M. G., et al. (2010). Evaluation of groundwater hydrochemical characteristics and mixing behavior in the Daying and Qicun geothermal systems, Xinzhou Basin. Journal of Volcanology and Geothermal Research, 189, 92–104.
Haritash, A. K., Kaushik, C. P., & Kaushik. (2008). Suitability assessment of groundwater for drinking, irrigation and industrial use in some North Indian villages. Environmental Monitoring and Assessment, 145, 397–408.
Jiang, Y., Wu, Y., & Groves, C. (2009). Natural and anthropogenic factors affecting groundwater quality in the Nandong karst underground river system in Yunan, China. Journal of Contaminant Hydrology, 109, 49–61. doi:10.1016/j.jconhyd.2009.08.001.
Karanth, K. R. (1987). Groundwater assessment, development and management (p. 720). New Delhi: Tata McGraw Hill.
Kumar, M., Ramanathan, A. L., Rao, M. S., & Kumar, B. (2006). Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India. Journal of Environmental Geology, 50, 1025–1039. doi:10.1007/s00254-006-0275-4.
Li, H. T., Kinzelbach, W., Brunner, P., Li, W. P., et al. (2008). Topography representation methods for improving evaporation simulation in groundwater modeling. Journal of Hydrology, 356, 199–208.
Li, H. T., Brunner, P., Kinzelbach, W., Li, W. P., et al. (2009). Calibration of a groundwater model using pattern information from remote sensing data. Journal of Hydrology. doi:10.1016/j.jhydrol.2009.08.012.
Mahlnecht, J., Steinch, B., & Navarro de León, I. (2004). Groundwater chemistry and mass transfers in the Independence aquifer, central Mexico, by using multivariate statistics and mass-balance models. Environmental Geology, 45, 781–795. doi:10.1007/s00254-003-0938-3.
Nosrat Aghazadeh, & Mogaddam, A. A. (2011). Investigation of hydrochemical characteristics of groundwater in the Harzandat aquifer, northwest of Iran. Environmental Monitoring and Assessment, 176, 183–195. doi:10.1007/s10661-010-1575-4.
Parkhurst, D. L., Appelo, C. A. J. (1999). Users guide to PHREEQC (version 2)—a computer program for speciation, batch reaction, one dimensional transport and inverse geochemical calculations. U.S. Geological Survey, Water-Resources Investigations pp 99–4259.
Ragunath, H. M. (1987). Groundwater (p. 563). New Delhi: Wiley.
Raju, N. J. (2007). Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin, Cuddapah District, Andhara Pradesh, South India. Environmental Geology, 52, 1067–1074.
Raju, N. J., Ram, P., & Dey, S. (2009). Groundwater quality in the lower Varuna river basin, Varanasi district, Uttar Pradesh. Journal Geological Society of India, 73, 178–192.
Ravikumar, P., Venkatesharaju, K., & Somashekar, R. K. (2010). Major ion chemistry and hydrochemical studies of groundwater of Bangalore South Taluk, India. Environmental Monitoring and Assessment, 163, 643–653. doi:10.1007/s10661-009-0865-1.
Richards, L. A. (1954). Diagnosis and improvement of saline alkali soils: Agriculture, vole 160. Handbook 60. Washington: US Department of Agriculture.
Sami, K. (1992). Recharge mechanisms and geochemical processes in a semi-arid sedimentary basin, Eastern Cape, South Africa. Journal of Hydrology, 139, 27–48.
Sandow, M. Y., Banoeng-Yakubo, B., & Akabzaa, T. (2011). Characterization of the groundwater flow regime and hydrochemistry of groundwater from the Buem formation, Eastern Ghana. Hydrological Processes, 25, 2288–2301. doi:hyp./hyp.7992.
Sarin, M. M., Krishnaswamy, S., & Dilli, K. (1989). Major ion chemistry of the Ganga–Brahmaputra river system: weathering processes and fluxes to the Bay of Bengal. Geochimica et Cosmochimica Acta, 53, 997–1009.
Sawyer, C. N., & McCarty, P. L. (1967). Chemistry of sanitary engineers (2nd ed., p. 518). New York: McGraw Hill.
Schoeller, H. (1977). Geochemistry of groundwater. In Groundwater studies—an international guide for research and practice (pp. 1–18). Paris: UNESCO. Ch. 15.
Spears, D. A. (1986). Mineralogical control of the chemical evolution of groundwater. In S. T. Trudgill (Ed.), Solute processes (p. 512). Chichester: Wiley.
Stumm, W., & Morgan, J. J. (1981). Aquatic chemistry. New York: Wiley Interscience.
Stuyfzand, P. J. (1989). Nonpoint source of trace element in potable groundwater in Netherland. In Proceedings of the 18th TWSA Water Working, Testing and Research Institute. Nieuwegein: KIWA
Subba Rao, N. (2008). Factors controlling the salinity in groundwater in parts of Guntur district, Andhra Pradesh, India. Environmental Monitoring and Assessment, 138, 327–341.
Subramani, T., Elango, L., & Damodarasamy, S. R. (2005). Groundwater quality and its suitability for drinking and agricultural use in Chithar River Basin, Tamil Nadu, India. Environmental Geology, 47, 1099–1110.
Swan, A. R. H., Sandilands, M., & McCabe, P. (1995). Introduction to geological data analysis. Oxford: Blackwell Science.
Tayfur, G., Kirer, T., & Baba, A. (2008). Groundwater quality and hydrogeochemical properties of Torbali Region, Izmir, Turkey. Environmental Monitoring and Assessment, 146, 157–169.
Wang, G., & Cheng, G. (1999). Water resource development and its influence on the environment in arid areas of China—the case of the Hei River basin. Journal of Arid Environments, 43, 121–131.
Wang, S., Dong, X., & Liu, Y. (2009). Spatio-temporal variation of subsurface hydrology and groundwater and salt evolution of the Oasis area of Yanqi Basin in 50 years recently. Geological Science and Technology Information, 28(5), 101–108.
Wang, S., Wu, B., & Yang, P. (2011). Determination of the ecological groundwater depth considering ecological integrity over oasis irrigation areas in the Yanqi Basin. Resources Science, 33(3), 422–430.
WHO (1997). Guidelines for drinking-water quality, V. 2. Recommendations. World Health Organization
Wilcox, L. V. (1955). Classification and use of irrigation waters, US Dept of Agricul Cir 969. Washington, DC.
Yamanaka, T., Tsujimura, M., & Oyunbaatar. (2006). Isotopic variation of precipitation over eastern Mongolia and continental-scale atmospheric water cycle. Journal of Hydrology. doi:10.1016/j.jhydrol.2006.07.022.
Yidana, S., Yiran, G., Sakyi, P., & Nude, P. (2011). Groundwater evolution in the Voltaian Basin, Ghana—an application of multivariate statistical analyses to hydrochemical data. Natural Science, 3, 837–854.
Zhu, G. F., Su, Y. H., & Feng, Q. (2008). The hydrochemical characteristics and evolution of groundwater and surface water in the Heihe River Basin, northwest China. Hydrogeology Journal, 16, 167–182. doi:10.1007/s10040-007-0216-7.
Acknowledgments
This work has been supported by: Special Fund for Agro-scientific Research in the Public Interest (No. 201203006) and a project of National Natural Science Foundation, China (NO. 91125010), the Fundamental Research Funds for the Central Universities in Lanzhou University (lzujbky-2012-141) and the Supervision of Ph D. Degree Fund of Chinese Ministry of Education (2012021111018). The authors wish to thank the anonymous reviewers for their reading of the manuscript, and for their suggestions and critical comments.
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Wang, S. Groundwater quality and its suitability for drinking and agricultural use in the Yanqi Basin of Xinjiang Province, Northwest China. Environ Monit Assess 185, 7469–7484 (2013). https://doi.org/10.1007/s10661-013-3113-7
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DOI: https://doi.org/10.1007/s10661-013-3113-7