Abstract
In the study, the pre-strain effect on hydrogen embrittlement property of the ultra-high-strength transformation-induced plasticity (TRIP)-aided bainitic ferrite (TBF) steel was investigated towards application for automobile frame parts. Specifically, 3–10% tensile pre-strain suppressed hydrogen-induced mechanical degradation relative to total elongation (pre-strain \(+\) elongation after hydrogen charging) while 12–15% pre-strained specimen did not exhibit elongation after hydrogen charging. The advantageous effect of the 3–10% pre-strain was attributed to the suppression of crack initiation related to retained austenite. Specifically, the TRIP by pre-straining decreased the volume fraction of retained austenite before hydrogen charging, thereby reducing existing probabilities of preferential crack initiation sites and propagation paths. Conversely, high pre-strain such as 12–15% does not effectively work due to work hardening resulting in increases in hydrogen embrittlement susceptibility and a significant increase in hydrogen content due to the multiplication of dislocations.
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References
Caballero FG, GarcÍa-Mateo C, Chao J, Santofimia MJ, Capdevila C, AndrÉs CGD (2008) Effects of morphology and stability of retained austenite on the ductility of TRIP-aided bainitic steels. ISIJ Int 48:1256–1262. https://doi.org/10.2355/isijinternational.48.1256
Caballero FG, Roelofs H, Hasler S, Capdevila C, Chao J, Cornide J, Garcia-Mateo C (2013) Influence of bainite morphology on impact toughness of continuously cooled cementite free bainitic steels. Mater Sci Technol 28:95–102. https://doi.org/10.1179/1743284710Y.0000000047
Chan SLI, Lee HL, Yang JR (1991) Effect of retained austenite on the hydrogen content and effective diffusivity of martensitic structure. Metall Trans A 22A:2579–2586. https://doi.org/10.1007/BF02851351
Choo WY, Lee JY (1982) Thermal analysis of trapped hydrogen in pure iron. Metall Mater Trans A 13A:135–140. https://doi.org/10.1007/BF02642424
Dyson DJ, Holmes B (1970) Effect of alloying additions on the lattice parameter of austenite. J Iron Steel Inst 208:469–474
Hojo T, Sugimoto K-I, Mukai Y, Ikeda S (2008) Effects of aluminum on delayed fracture properties of ultra high strength low alloy TRIP-aided steels. ISIJ Int 48:824–829. https://doi.org/10.2355/isijinternational.48.824
Hojo T, Kobayashi J, Sugimoto K (2016) Impact properties of low-alloy transformation-induced plasticity-steels with different matrix. Mater Sci Technol 32:1035–1042. https://doi.org/10.1080/02670836.2015.1110665
Hojo T, Ukai Y, Akiyama E (2017) Effects of hydrogen on tensile properties at slow strain rate of ultra high-strength TRIP-aided bainitic ferrite steels. Procedia Eng 207:1868–1873. https://doi.org/10.1016/j.proeng.2017.10.953
Hojo T, Kikuchi R, Waki H, Nishimura F, Ukai Y, Akiyama E (2018) Effect of strain rate on the hydrogen embrittlement property of ultra high-strength low alloy TRIP-aided steel. ISIJ Int 58:751–759. https://doi.org/10.2355/isijinternational.ISIJINT-2017-576
Hojo T, Koyama M, Terao N, Tsuzaki K, Akiyama E (2019) Transformation-assisted hydrogen desorption during deformation in steels: examples of \(\alpha ^{\prime }\) - and \(\varepsilon \)-martensite. Int J Hydrog Energy 44:30472–30477. https://doi.org/10.1016/j.ijhydene.2019.09.171
Koyama M, Yamasaki D, Ikeda A, Hojo T, Akiyama E, Takai K, Tsuzaki K (2019) Detection of hydrogen effusion before, during, and after martensitic transformation: example of multiphase transformation-induced plasticity steel. Int J Hydrog Energy 44:26028–26035. https://doi.org/10.1016/j.ijhydene.2019.07.254
Laureys A, Depover T, Petrov R, Verbeken K (2016) Microstructural characterization of hydrogen induced cracking in TRIP-assisted steel by EBSD. Mater Charact 112:169–179. https://doi.org/10.1016/j.matchar.2015.12.017
Marchi CS, Somerday BP, Tang X, Schiroky GH (2008) Effects of alloy composition and strain hardening on tensile fracture of hydrogen-precharged type 316 stainless steels. Int J Hydrog Energy 33:889–904. https://doi.org/10.1016/j.ijhydene.2007.10.046
Nagao A, Smith CD, Dadfarnia M, Sofronis P, Robertson IM (2012) The role of hydrogen in hydrogen embrittlement fracture of lath martensitic steel. Acta Materialia 60:5182–5189. https://doi.org/10.1016/j.actamat.2012.06.040
Peet MJ, Hojo T (2016) Hydrogen susceptibility of nanostructured bainitic steels. Metall Mater Trans A 47A:718–725. https://doi.org/10.1007/s11661-015-3221-9
Ronevich JA, Cooman BCD, Speer JG, Moor ED, Matlock DK (2012) Hydrogen effects in prestrained transformation induced plasticity steel. Metall Mater Trans A 43A:2293–2301. https://doi.org/10.1007/s11661-011-1075-3
Senuma T, Takemoto Y (2010) Influence of thermal history on microstructure and mechanical properties of steels for hot stamping. Mater Sci Forum 654–656:330–333. https://doi.org/10.4028/www.scientific.net/MSF.654-656.330
Song S-M, Sugimoto K-I, Kandaka S, Futamura A, Kobayashi M, Masuda S (2003) Effects of prestraining on high-cycle fatigue strength of high-strength low alloy TRIP-aided steels. Mater Sci Res Int 52:223–229. https://doi.org/10.2472/jsms.52.9Appendix_223
Sugimoto K-I, Nakano K, Song S-M, Kashima T (2002) Retained austenite characteristics and stretch-flangeability of high-strength low-alloy TRIP type bainitic sheet steels. ISIJ Int 42:450–455. https://doi.org/10.2355/isijinternational.42.450
Sugimoto K, Tsunezawa M, Hojo T, Ikeda S (2004) Ductility of 0.1-0.6C-1.5Si-1.5Mn ultra high-strength TRIP-aided sheet steels with bainitic ferrite matrix. ISIJ Int 44:1608–1614. https://doi.org/10.2355/isijinternational.44.1608
Takagi S, Toji Y, Yoshino M, Hasegawa K (2012) Hydrogen embrittlement resistance evaluation of ultra high strength steel sheets for automobiles. ISIJ Int 52:316–322. https://doi.org/10.2355/isijinternational.52.316
Takagi S, Hagihara Y, Hojo T, Urushihara W, Kawasaki K (2016) Comparison of hydrogen embrittlement resistance of high strength steel sheets evaluated by several methods. ISIJ Int 56:685–692. https://doi.org/10.2355/isijinternational.ISIJINT-2015-566
Tamura I (1970) Steel material study on the strength. Nikkan-Kogyo Shinbun Ltd., Tokyo
Wang M, Tasan CC, Koyama M, Ponge D, Raabe D (2015) Enhancing hydrogen embrittlement resistance of lath martensite by introducing nano-films of interlath austenite. Metall Mater Trans A 46A:3793–3802. https://doi.org/10.1007/s11661-015-3009-y
Yoshikawa N, Kobayashi J, Sugimoto K-I (2012) Notch-fatigue properties of advanced TRIP-aided bainitic ferrite steels. Metall Mater Trans A 43A:4129–4136. https://doi.org/10.1007/s11661-012-1246-x
Zackay VF, Parker ER, Fahr D, Bush R (1967) The enhancement of ductility in high-strength steels. Trans Am Soc Met 60:252–259
Zhou J, Wang B, Huang M-D, Cui D (2014) Effect of hot stamping parameters on the mechanical properties and microstructure of cold-rolled 22MnB5 steel strips. Int J Miner Metall Mater 21:544–555. https://doi.org/10.1007/s12613-014-0940-7
Zhu X, Zhang K, Li W, Jin X (2016) Effect of retained austenite stability and morphology on the hydrogen embrittlement susceptibility in quenching and partitioning treated steels. Mater Sci Eng A 658:400–408. https://doi.org/10.1016/j.msea.2016.02.026
Acknowledgements
The study was supported by JSPS KAKENHI Grant-in-Aid for Scientific Research on Innovative Areas “Hydrogenomics”, Nos. JP18H05513 and JP18H05514 and Grant-in-Aid for Scientific Research (C), No. JP18K04743. Furthermore, the part of the study was financially supported by the Amada Foundation. Additionally, a part of this work was supported by the QST Advanced Characterization Nanotechnology Platform under the remit of “Nanotechnology Platform” of the Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan (Proposal Nos. A-17-QS-0024 and A-18-QS-0034). The synchrotron radiation experiments were performed using a QST experimental station at QST (JAEA) beamline BL14B1, SPring-8, with the approval of the Japan Synchrotron Radiation Research Institute (JASRI) (Proposal Nos. 2017B3681 and 2018B3681).
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Hojo, T., Kumai, B., Koyama, M. et al. Hydrogen embrittlement resistance of pre-strained ultra-high-strength low alloy TRIP-aided steel. Int J Fract 224, 253–260 (2020). https://doi.org/10.1007/s10704-020-00451-5
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DOI: https://doi.org/10.1007/s10704-020-00451-5