Abstract
This paper reports novel results regarding the effects of electrospun carbon nanofibers (e-CNF) as a catalyst support by comparison with the commercial Vulcan XC-72R (denoted as XC-72R) as granular particles. The e-CNF was synthesized by stabilizing and carbonizing the electrospun PAN-based fibers. The e-CNF showed an average diameter of 250 nm with a rough surface and was partially aligned along the winding direction of the drum winder. The characteristic morphology was fundamentally dependant on the shape of the carbon materials. The average pore size of the e-CNF was 2.36 nm, while that of the XC-72R was 10.92 nm. The morphology of e-CNF was developed by shallow pores with rough surfaces due to the effects of electrospinning and carbonization, while that of the XC-72R was largely developed by mesopores rather than micropores due to the granular shape. Compared to XC-72R, the performance of the MEA prepared by e-CNF was excellent, owing to the morphology and the enhanced electrical conductivity. The Pt utilization of Pt/e-CNF was 69%, while that of Pt/XC-72R was 35%.
Similar content being viewed by others
References
Fritts SD, Gopal R (1992) J Electrochem Soc 140:3347
Parthasarathy A, Srinivasan S, Appleby J, Martin CR (1992) J Electroanal Chem 339:101
Lemons RA (1990) J Power Sources 29:251
Uchida M, Aoyama Y, Tanabe M, Yanagihara N, Eda N, Ohta A (1995) J Electrochem Soc 142:2572
Roy SC, Christensen PA, Hamnett A, Thomas KM, Trapp V (1996) J Electrochem Soc 143:3073
Uchida M, Fukuoka Y, Sugawara Y, Eda N, Ohta A (1996) J Electrochem Soc 143:2245
Ye S, Vijh AK, Dao LH (1997) J Electrochem Soc 144:90
Liu Z, Gan LM, Hong L, Chen W, Lee JY (2005) J Power Sources 139:73
Park CH, Scibioh MA, Kim HJ, Oh IH, Hong SA, Ha HY (2006) J Power Sources 162:1023
Kim C, Park SH, Lee WJ, Yang KS (2004) Electrochim Acta 50:877
Kim C, Choi YO, Lee WJ, Yang KS (2004) Electrochim Acta 50:883
Oh GY, Ju YW, Kim MY, Jung HR, Kim HJ, Lee WJ (2008) Sci Total Environ 393:341
Ju YW, Choi GR, Jung HR, Kim C, Yang KS, Lee WJ (2007) J Electrochem Soc 154:A192
Oh GY, Ju YW, Jung HR, Lee WJ (2008) J Anal Appl Pyrolysis 81:211
Xu D, Zhang H, Ye W (2007) Catal Commun 8:1767
Li W, Liang C, Qiu J, Zhou W, Han H, Wei Z, Sun G, Xin Q (2002) Carbon 40:791
Huang HX, Chen SX, Yuan C (2008) J Power Sources 175:166
Guha A, Lu W, Zawodzinski TA, Schiraldi DA (2007) Carbon 45:1506
O’Hayre R, Lee SJ, Cha SW, Prinz FB (2002) J Power Sources 109:483
Escribano S, Aldebert P (1995) Solid State Ionics 77:318
Tamizhmani G, Dodelet JP, Guay D (1996) J Electrochem Soc 143:18
Li W, Zhou W, Li H, Zhou Z, Zhou B, Sun G, Xin Q (2004) Electrochim Acta 49:1045
Song S, Wang Y, Shen PK (2007) J Power Sources 170:46
Zeng J, Lee JY, Chen J, Shen PK, Song S (2007) Fuel cells 7:285
Warren BE (1969) X-ray diffraction. Addison-Wesley, Reading
Sreekumar TV, Liu T, Min BG, Guo H, Kumar S, Hauge RH, Smalley RE (2004) Adv Mater 16:58
Acknowledgments
This work was supported by the Korea Foundation for International Cooperation of Science & Technology (KICOS) through a grant provided by the Korean Ministry of Science & Technology (MOST) in K20602000009-07E0200-00910.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Park, JH., Ju, YW., Park, SH. et al. Effects of electrospun polyacrylonitrile-based carbon nanofibers as catalyst support in PEMFC. J Appl Electrochem 39, 1229–1236 (2009). https://doi.org/10.1007/s10800-009-9787-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10800-009-9787-4