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Effects of various factors on capacitive properties of VO x ·nH2O powders in aqueous electrolyte

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Abstract

In this work, effects of drying temperature, pH of aqueous electrolyte and current density on capacitive performance of VO x ·nH2O material were firstly investigated. VO x ·nH2O powders were prepared by a melt quenching method. The samples were characterized by X-ray diffraction analysis (XRD) and Fourier transform infrared (FTIR). The capacitive properties of VO x ·nH2O samples were examined by cyclic voltammetry and galvanostatic charge/discharge test. VO x ·nH2O sample which was obtained at the drying temperature of 80 °C, delivers a maximum specific capacitance of 227.3 F g−1 and exhibits excellent capacity retention in the potential range of −0.3 to 0.7 V at a current density of 200 mA g−1 in NaNO3 solution with pH 2.

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Acknowledgments

This work was financially supported by the National Natural Science Foundation of China (No. 20701029) and the Key Program of the China West Normal University (No. 412374).

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Correspondence to Qiong Yu Lai.

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Chen, L.M., Lai, Q.Y., Zeng, H.M. et al. Effects of various factors on capacitive properties of VO x ·nH2O powders in aqueous electrolyte. J Appl Electrochem 41, 299–305 (2011). https://doi.org/10.1007/s10800-010-0238-z

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  • DOI: https://doi.org/10.1007/s10800-010-0238-z

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