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Determination of lisinopril using β-cyclodextrin/graphene oxide-SO3H modified glassy carbon electrode

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Abstract

An electrochemical method has been successfully demonstrated for sensitive determination of lisinopril with β-cyclodextrin-graphene oxide-SO3H composite modified glassy carbon electrode (β-CD/GO-SO3H/GCE). Cyclic voltammetry, differential pulse voltammetry, and chronocoulometry were used to investigate the electrochemical behavior of lisinopril at β-CD/GO-SO3H/GCE. The cyclic voltammetric results indicate that β-CD/GO-SO3H/GCE can remarkably enhance electroactivity toward the oxidation of lisinopril in buffer solutions. The electrochemical behavior was further exploited as a sensitive detection scheme for the lisinopril determination by differential-pulse voltammetry. Under optimized conditions, the concentration range and detection limit were 0.21–190.4 and 0.11 µM (S/N = 3), respectively. The method was successfully applied to assay the drug in human serum.

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Acknowledgments

This is a report of a database from the thesis entitled “Development of sensitive, routine and reliable methods for determination of cardiovascular drugs in biological samples” registered in Drug Applied Research Center. We gratefully acknowledge the financial support of this work by the Drug Applied Research Center, Tabriz University of Medical Sciences.

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Authors and Affiliations

  1. Drug Applied Research Center and Faculty of Pharmacy, Tabriz University of Medical Sciences, 51664, Tabriz, Iran

    Mohammad Hasanzadeh & Abolghasem Jouyban

  2. Electroanalytical Chemistry Laboratory, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Mohammad Hossein Pournaghi-Azar

  3. Biochemistry Lab, Pasteur Institute of Iran, Tehran, Iran

    Nasrin Shadjou

Authors
  1. Mohammad Hasanzadeh
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  2. Mohammad Hossein Pournaghi-Azar
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  3. Nasrin Shadjou
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  4. Abolghasem Jouyban
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Correspondence to Mohammad Hasanzadeh or Abolghasem Jouyban.

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Hasanzadeh, M., Pournaghi-Azar, M.H., Shadjou, N. et al. Determination of lisinopril using β-cyclodextrin/graphene oxide-SO3H modified glassy carbon electrode. J Appl Electrochem 44, 821–830 (2014). https://doi.org/10.1007/s10800-014-0689-8

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