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Journal of Materials Science

Erschienen in:

01.03.2014

Decoration of surface-carboxylated graphene oxide with luminescent Sm³⁺-complexes

verfasst von: Xianzhong Fan, Kun Shang, Bing Sun, Lijian Chen, Shiyun Ai

Erschienen in: Journal of Materials Science | Ausgabe 6/2014

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Abstract

A Sm³⁺ complex, tris-(2-thenoyltrifluoroacetone) mono-1,10-phenanthroline-Sm³⁺ [Sm(TTA)₃(Phen)], can be easily integrated in situ via covalent functionalization to surface-carboxylated graphene oxide (GO-COOH) from a ethanol solution. The Sm³⁺ containing material has been comprehensively characterized via Fourier transform infrared spectra, X-ray photoelectron spectroscopy, UV–Vis absorption spectra, luminescence spectra, transmission electron microscopy, powder X-ray diffraction, thermogravimetric analysis (TG and DTG). The integration of rare earth complexes (RE) onto GO-COOH, as well as the individual nature of the hybrids, is confirmed. The GO-COOH with high load capacity can integrate more RE than GO. The brilliant optical properties of the GO-COOH-RE complex hybrids make them promising candidates applying in many practical fields, such as biomedical applications.

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Titel: Decoration of surface-carboxylated graphene oxide with luminescent Sm3+-complexes
verfasst von: Xianzhong Fan
Kun Shang
Bing Sun
Lijian Chen
Shiyun Ai
Publikationsdatum: 01.03.2014
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 6/2014
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-013-7975-4

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