Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 19/2016

30.06.2016 | Original Paper

Novel hydrophilic PVDF ultrafiltration membranes based on a ZrO2–multiwalled carbon nanotube hybrid for oil/water separation

verfasst von: Xi Yang, Yi He, Guangyong Zeng, Yingqing Zhan, Yang Pan, Heng Shi, Qi Chen

Erschienen in: Journal of Materials Science | Ausgabe 19/2016

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

A novel hydrophilic PVDF composite membrane based on ZrO2–multiwalled carbon nanotubes (MWCNTs) hybrid was prepared by a simple phase-inversion method. ZrO2 nanoparticles were firstly loaded on the surface of MWCNTs via hydrothermal route, which was characterized by Fourier-transform infrared, X-ray diffraction, thermogravimetric analyzer, scanning electron microscopy (SEM), and transmission electron microscopy. It was found that the ZrO2–MWCNTs hybrid formed network structures within the PVDF matrix, avoiding the aggregation of nanofillers. Then, the effects of ZrO2–MWCNTs hybrid on the performances of ultimate PVDF membrane were systematically investigated. The microstructure and surface morphology of novel membranes were observed by SEM and atomic force microscopy. The results indicated that ZrO2 were dispersed homogeneously on the surface of MWCNTs. The as-prepared membrane exhibited enhanced pure water flux and a lower contact angle than those of pure PVDF membrane. Furthermore, the as-prepared membranes processed also improved separation efficiency against oil/water emulsions and achieved better rejection ratio and good durable antifouling performance. In general, ZrO2–MWCNTs/PVDF membrane may provide a potential application against complex oil/water systems.
Vorheriger Artikel Study on the binding strength of polystyrene photonic crystals on polyester fabrics
Nächster Artikel Effects of freeze-drying conditions on aerogel properties

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Literatur
1.
Blanco J, Malato S, Fernández-Ibañez P, Alarcón D, Gernjak W, Maldonado MI (2009) Review of feasible solar energy applications to water processes. Renew Sustain Energy Rev 13:1437–1445CrossRef
2.
de Araki MS, de Coutinho CM, Gonçalves LAG, Viotto LA (2010) Solvent permeability in commercial ultrafiltration polymeric membranes and evaluation of the structural and chemical stability towards hexane. Sep Purif Technol 71:13–21CrossRef
3.
Yuan T, Meng J, Hao T, Wang Z, Zhang Y (2015) A scalable method toward superhydrophilic and underwater superoleophobic pvdf membranes for effective oil/water emulsion separation. ACS Appl Mater Interfaces 7:14896–14904CrossRef
4.
Drioli E, Macedonio F (2012) Membrane engineering for water engineering. Ind Eng Chem Res 51:10051–10056CrossRef
5.
Francis L, Ghaffour N, Alsaadi AS, Nunes SP, Amy GL (2013) PVDF hollow fiber and nanofiber membranes for fresh water reclamation using membrane distillation. J Mater Sci 49:2045–2053. doi:10.​1007/​s10853-013-7894-4 CrossRef
6.
7.
8.
Ng LY, Mohammad AW, Leo CP, Hilal N (2013) Polymeric membranes incorporated with metal/metal oxide nanoparticles: a comprehensive review. Desalination 308:15–33CrossRef
9.
Wang X-M, Li X-Y, Shih K (2011) In situ embedment and growth of anhydrous and hydrated aluminum oxide particles on polyvinylidene fluoride (PVDF) membranes. J Membr Sci 368:134–143CrossRef
10.
Yu S, Zuo X, Bao R, Xu X, Wang J, Xu J (2009) Effect of SiO2 nanoparticle addition on the characteristics of a new organic–inorganic hybrid membrane. Polymer 50:553–559CrossRef
11.
Yu L-Y, Xu Z-L, Shen H-M, Yang H (2009) Preparation and characterization of PVDF–SiO2 composite hollow fiber UF membrane by sol–gel method. J Membr Sci 337:257–265CrossRef
12.
Qin A, Li X, Zhao X, Liu D, He C (2015) Engineering a highly hydrophilic PVDF membrane via binding TiO2(2)nanoparticles and a pva layer onto a membrane surface. ACS Appl Mater Interfaces 7:8427–8436CrossRef
13.
Razmjou A, Mansouri J, Chen V (2011) The effects of mechanical and chemical modification of TiO2 nanoparticles on the surface chemistry, structure and fouling performance of PES ultrafiltration membranes. J Membr Sci 378:73–84CrossRef
14.
Zhou S, Xue A, Zhang Y, Li M, Wang J, Zhao Y, Xing W (2014) Fabrication of temperature-responsive ZrO2 tubular membranes, grafted with poly (N-isopropylacrylamide) brush chains, for protein removal and easy cleaning. J Membr Sci 450:351–361CrossRef
15.
Paiman SH, Rahman MA, Othman MHD, Ismail AF, Jaafar J, Aziz AA (2015) Morphological study of yttria-stabilized zirconia hollow fibre membrane prepared using phase inversion/sintering technique. Ceram Int 41:12543–12553CrossRef
16.
Pang R, Li X, Li J, Lu Z, Sun X, Wang L (2014) Preparation and characterization of ZrO2/PES hybrid ultrafiltration membrane with uniform ZrO2 nanoparticles. Desalination 332:60–66CrossRef
17.
Zheng Y-M, Zou S-W, Nanayakkara KGN, Matsuura T, Chen JP (2011) Adsorptive removal of arsenic from aqueous solution by a PVDF/zirconia blend flat sheet membrane. J Membr Sci 374:1–11CrossRef
18.
He J, Siah TS, Paul Chen J (2014) Performance of an optimized Zr-based nanoparticle-embedded PSF blend hollow fiber membrane in treatment of fluoride contaminated water. Water Res 56:88–97CrossRef
19.
Zhang Y, Ting JWY, Rohan R, Cai W, Li J, Xu G, Chen Z, Lin A, Cheng H (2014) Fabrication of a proton exchange membrane via blended sulfonimide functionalized polyamide. J Mater Sci 49:3442–3450. doi:10.​1007/​s10853-014-8055-0 CrossRef
20.
Li H, Zhao X, Wu P, Zhang S, Geng B (2015) Facile preparation of superhydrophobic and superoleophilic porous polymer membranes for oil/water separation from a polyarylester polydimethylsiloxane block copolymer. J Mater Sci 51:3211–3218. doi:10.​1007/​s10853-015-9632-6 CrossRef
21.
Du C-H, Zhu B-K, Xu Y-Y (2006) The effects of quenching on the phase structure of vinylidene fluoride segments in PVDF-HFP copolymer and PVDF-HFP/PMMA blends. J Mater Sci 41:417–421. doi:10.​1007/​s10853-005-2182-6 CrossRef
22.
Qiu S, Wu L, Shi G, Zhang L, Chen H, Gao C (2010) Preparation and pervaporation property of chitosan membrane with functionalized multiwalled carbon nanotubes. Ind Eng Chem Res 49:11667–11675CrossRef
23.
Murali RS, Sridhar S, Sankarshana T, Ravikumar YVL (2010) Gas permeation behavior of Pebax-1657 nanocomposite membrane incorporated with multiwalled carbon nanotubes. Ind Eng Chem Res 49:6530–6538CrossRef
24.
López-Lorente ÁI, Polo-Luque ML, Valcárcel M (2013) Sequential preconcentration and on-membrane raman determination of carboxylic single-walled carbon nanotubes in river water samples. Anal Chem 85:10338–10343CrossRef
25.
Xie X, Mai Y, Zhou X (2005) Dispersion and alignment of carbon nanotubes in polymer matrix: a review. Mater Sci Eng R 49:89–112CrossRef
26.
Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B (2012) Novel antibifouling nanofiltration polyethersulfone membrane fabricated from embedding TiO2 coated multiwalled carbon nanotubes. Sep Purif Technol 90:69–82CrossRef
27.
Choi J-H, Jegal J, Kim W-N (2006) Fabrication and characterization of multi-walled carbon nanotubes/polymer blend membranes. J Membr Sci 284:406–415CrossRef
28.
Kraytsberg A, Ein-Eli Y (2014) Review of advanced materials for proton exchange membrane fuel cells. Energy Fuels 28:7303–7330CrossRef
29.
Xu H-P, Lang W-Z, Yan X, Zhang X, Guo Y-J (2014) Preparation and characterizations of poly(vinylidene fluoride)/oxidized multi-wall carbon nanotube membranes with bi-continuous structure by thermally induced phase separation method. J Membr Sci 467:142–152CrossRef
30.
Wang S, Liang S, Liang P, Zhang X, Sun J, Wu S, Huang X (2015) In-situ combined dual-layer CNT/PVDF membrane for electrically-enhanced fouling resistance. J Membr Sci 491:37–44CrossRef
31.
Reddy ALM, Shaijumon MM, Gowda SR, Ajayan PM (2009) Coaxial MnO2/carbon nanotube array electrodes for high-performance lithium batteries. Nano Lett 9:1002–1006CrossRef
32.
Wang Z, Xia J, Xia Y, Lu C, Shi G, Zhang F, Zhu F, Li Y, Xia L, Tang J (2013) Fabrication and characterization of a zirconia/multi-walled carbon nanotube mesoporous composite. Mater Sci Eng C 33:3931–3934CrossRef
33.
Liu F, Hashim NA, Liu Y, Abed MRM, Li K (2011) Progress in the production and modification of PVDF membranes. J Membr Sci 375:1–27CrossRef
34.
Zeng G, He Y, Zhan Y, Zhang L, Shi H, Yu Z (2016) Preparation of a novel poly(vinylidene fluoride) ultrafiltration membrane by incorporation of 3-aminopropyltriethoxysilane-grafted halloysite nanotubes for oil/water separation. Ind Eng Chem Res 55:1760–1767CrossRef
35.
Shi H, He Y, Pan Y, Di H, Zeng G, Zhang L, Zhang C (2016) A modified mussel-inspired method to fabricate TiO2 decorated superhydrophilic PVDF membrane for oil/water separation. J Membr Sci 506:60–70CrossRef
36.
Madaeni SS, Zinadini S, Vatanpour V (2013) Preparation of superhydrophobic nanofiltration membrane by embedding multiwalled carbon nanotube and polydimethylsiloxane in pores of microfiltration membrane. Sep Purif Technol 111:98–107CrossRef
37.
Zhou S, Xue A, Zhao Y, Li M, Wang H, Xing W (2013) Grafting polyacrylic acid brushes onto zirconia membranes: fouling reduction and easy-cleaning properties. Sep Purif Technol 114:53–63CrossRef
38.
Kim UJ, Furtado CA, Liu X, Chen G, Eklund PC (2005) Raman and IR spectroscopy of chemically processed single-walled carbon nanotubes. J Am Chem Soc 127:15437–15445CrossRef
39.
Ali SD, Hussain ST, Gilani SR (2013) Synthesis, characterization and magnetic properties of carbon nanotubes decorated with magnetic MIIFe2O4 nanoparticles. Appl Surf Sci 271:118–124CrossRef
40.
Kardimi K, Tsoufis T, Tomou A, Kooi BJ, Prodromidis MI, Gournis D (2012) Synthesis and characterization of carbon nanotubes decorated with Pt and PtRu nanoparticles and assessment of their electrocatalytic performance. Int J Hydrog Energy 37:1243–1253CrossRef
41.
Buonomenna MG, Macchi P, Davoli M, Drioli E (2007) Poly(vinylidene fluoride) membranes by phase inversion: the role the casting and coagulation conditions play in their morphology, crystalline structure and properties. Eur Polym J 43:1557–1572CrossRef
42.
Li T, Zhong G, Fu R, Yang Y (2010) Synthesis and characterization of Nafion/cross-linked PVP semi-interpenetrating polymer network membrane for direct methanol fuel cell. J Membr Sci 354:189–197CrossRef
43.
Azambre B, Zenboury L, Koch A, Weber JV (2009) Adsorption and desorption of NOx on commercial ceria-zirconia (CexZr1−xO2) mixed oxides: a combined TGA, TPD-MS, and DRIFTS study. J Phys Chem C 113:13287–13299CrossRef
44.
Addo Ntim S, Mitra S (2012) Adsorption of arsenic on multiwall carbon nanotube–zirconia nanohybrid for potential drinking water purification. J Colloid Interface Sci 375:154–159CrossRef
45.
Eder D (2010) Carbon nanotube—inorganic hybrids. Chem Rev 110:1348–1385CrossRef
46.
Jian P, Yahui H, Yang W, Linlin L (2006) Preparation of polysulfone—Fe3O4 composite ultrafiltration membrane and its behavior in magnetic field. J Membr Sci 284:9–16CrossRef
47.
Daraei P, Madaeni SS, Ghaemi N, Ahmadi Monfared H, Khadivi MA (2013) Fabrication of PES nanofiltration membrane by simultaneous use of multi-walled carbon nanotube and surface graft polymerization method: comparison of MWCNT and PAA modified MWCNT. Sep Purif Technol 104:32–44CrossRef
48.
Le-Clech P, Chen V, Fane TAG (2006) Fouling in membrane bioreactors used in wastewater treatment. J Membr Sci 284:17–53CrossRef
49.
Tijing LD, Choi J-S, Lee S, Kim S-H, Shon HK (2014) Recent progress of membrane distillation using electrospun nanofibrous membrane. J Membr Sci 453:435–462CrossRef
Metadaten
Titel
Novel hydrophilic PVDF ultrafiltration membranes based on a ZrO2–multiwalled carbon nanotube hybrid for oil/water separation
verfasst von
Xi Yang
Yi He
Guangyong Zeng
Yingqing Zhan
Yang Pan
Heng Shi
Qi Chen
Publikationsdatum
30.06.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 19/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0147-6

Weitere Artikel der Ausgabe 19/2016

Journal of Materials Science 19/2016 Zur Ausgabe

Original Paper

Improvements of lanthanum complex on the thermal-oxidative stability of natural rubber

Original Paper

PVP-modulated synthesis of NaV6O15 nanorods as cathode materials for high-capacity sodium-ion batteries

Original Paper

Growth kinetics of ellipsoidal ω-precipitates in a Ti–20 wt%Mo alloy under compressive stress

Editorial

The art of being found: crafting the right title

Original Paper

Graphene nanoplatelet-modified epoxy: effect of aspect ratio and surface functionality on mechanical properties and toughening mechanisms

Original Paper

Plasma treatment in conjunction with EGM-2 medium increases endothelial and osteogenic marker expressions of bone marrow mesenchymal stem cells

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise