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Journal of Materials Science
Erschienen in: Journal of Materials Science 7/2017

29.12.2016 | Original Paper

The effect of molten salt on oxygen removal from titanium and its alloys using calcium

verfasst von: Yang Xia, Zhigang Zak Fang, Pei Sun, Ying Zhang, Tuoyang Zhang, Michael Free

Erschienen in: Journal of Materials Science | Ausgabe 7/2017

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Abstract

The sensitivity of titanium to increasing oxygen content and the high cost of reducing oxygen content in titanium have prevented its broader applications. Here we report a low-temperature de-oxygenation process, which can remove oxygen from titanium powders to less than 1000 ppm from original oxygen levels of over 20,000 ppm. The effect of molten salt on de-oxygenation was investigated in this study. The calcium halide-bearing molten salt facilitates the dissolution of solid calcium and creates a metal-molten solution condition by forming intermediate Ca+ ions and finally Ca2+ ions and electrons (e −). The molten salt enables the de-oxygenation of Ti at temperatures lower than the melting point of calcium. It will be shown that the de-oxygenation temperature can be as low as 873 K (600 °C).
Vorheriger Artikel High-temperature transformation pathways for metastable ferromagnetic binary Heusler (Al–55 at.%Mn) alloy
Nächster Artikel Synthesis of Ti matrix composites reinforced with TiC particles: thermodynamic equilibrium and change in microstructure

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Literatur
1.
Froes FH, Gungor MN, Imam MA (2007) Cost-affordable titanium: the component fabrication perspective. JOM 59:28–31CrossRef
2.
Hartman AD, Gerdemann SJ, Hansen JS (1998) Producing lower-cost titanium for automotive applications. JOM 50:16–19CrossRef
3.
Neikov OD, Naboychenko SS, Murashova IV, Gopienko VG, Frishberg IV, Lotsko DV (2009) Handbook of non-ferrous metal powders—technologies and applications. Elsevier, Oxford
4.
Conrad H (1998) Effect of interstitial solutes on the strength and ductility of titanium. Prog Mater Sci 26:123–403CrossRef
5.
Yan M, Xu W, Dargusch MS, Tang HP, Brandt M, Qian M (2014) Review of effect of oxygen on room temperature ductility of titanium and titanium alloys. Powder Metall 57:251–257CrossRef
6.
Liu ZG, Welsch G (1988) Effects of oxygen and heat treatment on the mechanical properties of alpha and beta titanium alloys. Metall Trans A 19:527–542CrossRef
7.
Chase MW, NIST-JANAF Thermochemical Tables (1998) Fourth Edition, Monograph No. 9, Journal of Physical and Chemical Reference Data. American Institute of Physics, New York
8.
Mah AD, Kelley KK, Gellert NL, King EG, O’Brien CJ (1957) Thermodynamic properties of titanium-oxygen solutions and compounds. U.S. Department of the Interior, Bureau of Mines
9.
Kubaschewski O, Dench WA (1953) The free-energy diagram of the system titanium–oxygen. J Inst Met 82:87–91
10.
McCracken CG, Robison JW, Motchenbacher CA (2009) Manufacturing of HDH low oxygen titanium–6Aluminium–4Vanadium (Ti-6-4) powder incorporating a novel powder de-oxidation step. Euro PM2009-Powder Manufacturing I, pp 197–192
11.
Fisher RL, Ohio W (1991) Deoxidation of a refractory metal. US patent 5022935
12.
Okabe TH, Oishi T, Ono K (1992) Preparation and characterization of extra low oxygen titanium. J Alloys and Compd 184:43–56CrossRef
13.
Oh JM, Lee BK, Suh CY, Cho SW, Lim JW (2012) Deoxidation of Ti powder and preparation of Ti ingot with low oxygen concentration. Mat Trans 53:1075–1077CrossRef
14.
Oh JM, Lee BK, Suh CY, Cho SW, Lim JW (2012) Method for preparing titanium powder with low oxygen concentration. US patent 8449646 B1
15.
Lutjering G, Willams JC (2007) Titanium, 2nd edn. Springer, Berlin
16.
Mehrer H (1990) Diffusion in solid metals and alloys, Landolt BoÈrnstein. Springer, BerlinCrossRef
17.
Suzuki RO, Inou S (2003) Calciothermic reduction of titanium oxide in molten CaCl2. Metall Mat Tran B 34:277–285CrossRef
18.
Ono K, Suzuki RO (2002) A new concept for producing Ti sponge: Calciothermic reduction. JOM 54:59–61CrossRef
19.
Suzuki RO (2005) Calciothermic reduction of TiO2 and in situ electrolysis of CaO in the molten CaCl2. J Phys Chem Solids 66:461–465CrossRef
20.
Sun P, Fang ZZ, Xia Y, Zhang Y, Zhou C (2016) A novel method for production of spherical Ti–6Al–4V powder for additive manufacturing. Powder Technol 301:331–335CrossRef
21.
Oh JM, Lee BK, Suh CY, Cho SW, Lim JW (2012) Deoxidation of Ti powder and preparation of Ti ingot with low oxygen concentration. Mater Trans 53(6):1075–1077CrossRef
22.
Andreeva VV (1996) Behavior and nature of thin oxide films on some metals in gaseous media and in electrolyte solutions. Corrosion 20:35–46CrossRef
23.
Bronstein HR, Bredig MA (1958) Electrical conductivity of solutions of alkali metals in their molten halides. J Am Chem Soc 80:2077–2081CrossRef
24.
25.
Bredig MA (1963) Mixtures of metals with molten salts, ORNL-3391. Oak Ridge National Laboratory, Oak RidgeCrossRef
26.
27.
Haarberg GM, Osen KS, Heus RJ, Egan J (1990) Electrochemical properties of metal-molten salt mixtures. J Electrochem Soc 137:2777–2781CrossRef
28.
Park I, Abiko T, Okabe TH (2005) Production of titanium powder directly from TiO2 in CaCl2 through an electronically mediated reaction (EMR). J Phys Chem Solids 66(2–4):410–413CrossRef
29.
Dworkin AS, Bronstein HR, Bredig MA (1961) Ionic melts as solvents for electronic conductors. Discuss Faraday Soci 32:188CrossRef
30.
Vanysek P (2000) Electrochemical series. CRC Press LLC, Boca Raton
31.
Shaw S, Watson R (2009) Solubility of calcium in CaCl2–CaO. ECS Trans 16:301–308CrossRef
Metadaten
Titel
The effect of molten salt on oxygen removal from titanium and its alloys using calcium
verfasst von
Yang Xia
Zhigang Zak Fang
Pei Sun
Ying Zhang
Tuoyang Zhang
Michael Free
Publikationsdatum
29.12.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2017
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-0674-1

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