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Erschienen in: Journal of Materials Science 10/2016

16.02.2016 | Original Paper

Ionic liquid-assisted synthesis and improved photocatalytic activity of p-n junction g-C3N4/BiOCl

verfasst von: Sheng Yin, Jun Di, Ming Li, Yilin Sun, Jiexiang Xia, Hui Xu, Wenmin Fan, Huaming Li

Erschienen in: Journal of Materials Science | Ausgabe 10/2016

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Abstract

The g-C3N4/BiOCl microsphere photocatalysts have been successfully synthesized in the presence of the reactable ionic liquid [C16mim]Cl. The p-n junction between p-type BiOCl and n-type g-C3N4 has been successfully constructed with g-C3N4 dispersed on the surface of BiOCl microspheres. The g-C3N4/BiOCl microspheres were characterized by XRD, XPS, SEM, FT-IR, and DRS. Rhodamine B (RhB) was used as a target pollutant to evaluate the photocatalytic activity of the as-prepared g-C3N4/BiOCl microsphere photocatalysts. The g-C3N4/BiOCl material exhibited superior photocatalytic performance when compared with pure BiOCl. The formed p-n junction was responsible for the improved separation efficiency of photogenerated electron–hole pairs, and thus the higher photocatalytic activity. The possible photocatalytic mechanism was proposed based on relative band positions of these two semiconductors.

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Metadaten
Titel
Ionic liquid-assisted synthesis and improved photocatalytic activity of p-n junction g-C3N4/BiOCl
verfasst von
Sheng Yin
Jun Di
Ming Li
Yilin Sun
Jiexiang Xia
Hui Xu
Wenmin Fan
Huaming Li
Publikationsdatum
16.02.2016
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 10/2016
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-016-9746-5

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