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Journal of Materials Science
Erschienen in: Journal of Materials Science 2/2018

02.10.2017 | Energy materials

Local degradation pathways in lithium-rich manganese–nickel–cobalt oxide epitaxial thin films

verfasst von: Aaron C. Johnston-Peck, Saya Takeuchi, K. Kamala Bharathi, Andrew. A. Herzing, Leonid A. Bendersky

Erschienen in: Journal of Materials Science | Ausgabe 2/2018

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Abstract

The electrochemical performance and microstructure of positive electrodes are intimately linked. As such, developing batteries resistance to capacity and voltage fade requires understanding these underlying structure–property relationships and their evolution with operation. Epitaxial films of a Li-rich manganese–nickel–cobalt oxide cathode material were deposited on (100)- and (111)-oriented SrRuO3/SrTiO3 substrates. Cyclic voltammetry and impedance spectroscopy tracked the response of these positive electrode materials, while the microstructure of the pristine and cycled films was characterized using transmission electron microscopy. Energy-dispersive X-ray spectroscopy identifies compositional fluctuations in as-deposited films. Phase transformations and dissolution were observed after electrochemical testing. There is a correlation between both local composition and substrate orientation (i.e., surface faceting) and what degradation pathways are active. Regions with comparatively higher concentrations of Ni and Co were more resistant to dissolution and unfavorable phase transformations than those with relatively more Mn. As such, a global composition metric may not be an accurate predictor of degradation and performance. Rather possessing the synthetic ability to engineer the chemical profile as well as characterizing it, pose a challenge and opportunity.
Vorheriger Artikel Porous layer assembled hierarchical Co3O4 as anode materials for lithium-ion batteries
Nächster Artikel Effect of annealing temperature on the luminescence of Ce1−x PO4: Tb x 3+ nanocrystals: A novel theoretical model and experimental verification

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Metadaten
Titel
Local degradation pathways in lithium-rich manganese–nickel–cobalt oxide epitaxial thin films
verfasst von
Aaron C. Johnston-Peck
Saya Takeuchi
K. Kamala Bharathi
Andrew. A. Herzing
Leonid A. Bendersky
Publikationsdatum
02.10.2017
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 2/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-017-1593-5

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