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Erschienen in: Journal of Materials Science 7/2019

02.01.2019 | Polymers

Excellent self-healing and antifogging coatings based on polyvinyl alcohol/hydrolyzed poly(styrene-co-maleic anhydride)

verfasst von: Shuai Luo, Xuan Qiao, Qiu-Yu Wang, Yun-Fei Zhang, Ping Fu, Zhi-Dong Lin, Fei-Peng Du, Chun Cheng

Erschienen in: Journal of Materials Science | Ausgabe 7/2019

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Abstract

To develop low-cost and high-performance self-healing antifogging coatings, polyvinyl alcohol/hydrolyzed poly(styrene-co-maleic anhydride) (PVA/H-PSMA) coatings were prepared from a mixed solution of polyvinyl alcohol (PVA) and hydrolyzed poly(styrene-co-maleic anhydride) (H-PSMA) via spin coating and annealing. The microstructure, antifogging behavior, and self-healing ability were investigated. High transparency and low surface roughness were observed when the PVA/H-PSMA film was coated on glass slides. The PVA/H-PSMA coatings showed excellent antifogging performance in a warm, humid environment. The coatings also performed well when transferred from a refrigerator to room temperature. The antifogging coatings showed desirable water resistance due to strong chemical bonding between PVA and H-PSMA, as well as excellent self-healing ability due to hydrogen bonding self-assembly in the PVA/H-PSMA structure. The coatings still exhibited excellent antifogging effects after 20 scratching-repairing cycles, illustrating their potential use in practical applications.

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Literatur
1.
Zurück zum Zitat Li J, Zhu J, Gao X (2014) Bio-inspired high-performance antireflection and antifogging polymer films. Small 10:2578–2582CrossRef Li J, Zhu J, Gao X (2014) Bio-inspired high-performance antireflection and antifogging polymer films. Small 10:2578–2582CrossRef
2.
Zurück zum Zitat Yao B, Zhao H, Wang L, Liu Y, Zheng C, Li H, Sun C (2018) Synthesis of acrylate-based UV/thermal dual-cure coatings for antifogging. J Coat Technol Res 15:149–158CrossRef Yao B, Zhao H, Wang L, Liu Y, Zheng C, Li H, Sun C (2018) Synthesis of acrylate-based UV/thermal dual-cure coatings for antifogging. J Coat Technol Res 15:149–158CrossRef
3.
Zurück zum Zitat Han Z, Feng X, Guo Z, Niu S, Ren L (2018) Flourishing bioinspired antifogging materials with superwettability: progresses and challenges. Adv Mater 30:1704652CrossRef Han Z, Feng X, Guo Z, Niu S, Ren L (2018) Flourishing bioinspired antifogging materials with superwettability: progresses and challenges. Adv Mater 30:1704652CrossRef
4.
Zurück zum Zitat Wang F, Yang X, Zhang L, Xu W, Liu H (2017) Novel macromolecular emulsifiers as coatings with water-tolerant antifogging properties based on coumarin-containing copolymeric micelles. Macromol Mater Eng 302:1700173CrossRef Wang F, Yang X, Zhang L, Xu W, Liu H (2017) Novel macromolecular emulsifiers as coatings with water-tolerant antifogging properties based on coumarin-containing copolymeric micelles. Macromol Mater Eng 302:1700173CrossRef
5.
Zurück zum Zitat Zhao J, Meyer A, Ma L, Ming W (2013) Acrylic coatings with surprising antifogging and frost-resisting properties. Chem Commun 49:11764–11766CrossRef Zhao J, Meyer A, Ma L, Ming W (2013) Acrylic coatings with surprising antifogging and frost-resisting properties. Chem Commun 49:11764–11766CrossRef
6.
Zurück zum Zitat Zhao J, Ma L, Millians W, Wu T, Ming W (2016) Dual-functional antifogging/antimicrobial polymer coating. ACS Appl Mater Interfaces 8:8737–8742CrossRef Zhao J, Ma L, Millians W, Wu T, Ming W (2016) Dual-functional antifogging/antimicrobial polymer coating. ACS Appl Mater Interfaces 8:8737–8742CrossRef
7.
Zurück zum Zitat Li C, Li X, Tao C, Ren L, Zhao Y, Bai S, Yuan X (2017) Amphiphilic antifogging/anti-icing coatings containing POSS-PDMAEMA-b-PSBMA. ACS Appl Mater Interfaces 9:22959–22969CrossRef Li C, Li X, Tao C, Ren L, Zhao Y, Bai S, Yuan X (2017) Amphiphilic antifogging/anti-icing coatings containing POSS-PDMAEMA-b-PSBMA. ACS Appl Mater Interfaces 9:22959–22969CrossRef
8.
Zurück zum Zitat Tao C, Bai S, Li X, Li C, Ren L, Zhao Y, Yuan X (2018) Formation of zwitterionic coatings with an aqueous lubricating layer for antifogging/anti-icing applications. Prog Org Coat 115:56–64CrossRef Tao C, Bai S, Li X, Li C, Ren L, Zhao Y, Yuan X (2018) Formation of zwitterionic coatings with an aqueous lubricating layer for antifogging/anti-icing applications. Prog Org Coat 115:56–64CrossRef
9.
Zurück zum Zitat Zhang L, Qiao ZA, Zheng M, Huo Q, Sun J (2010) Rapid and substrate-independent layer-by-layer fabrication of antireflection- and antifogging-integrated coatings. J Mater Chem 20:6125–6130CrossRef Zhang L, Qiao ZA, Zheng M, Huo Q, Sun J (2010) Rapid and substrate-independent layer-by-layer fabrication of antireflection- and antifogging-integrated coatings. J Mater Chem 20:6125–6130CrossRef
10.
Zurück zum Zitat Zhang T, Yu Q, Wang J, Wu T (2018) Design and fabrication of a renewable and highly transparent multilayer coating on poly (lactic acid) film capable of UV-shielding and antifogging. Ind Eng Chem Res 57:4577–4584CrossRef Zhang T, Yu Q, Wang J, Wu T (2018) Design and fabrication of a renewable and highly transparent multilayer coating on poly (lactic acid) film capable of UV-shielding and antifogging. Ind Eng Chem Res 57:4577–4584CrossRef
13.
Zurück zum Zitat Wang Y, Li T, Li S, Sun J (2015) Antifogging and frost-resisting polyelectrolyte coatings capable of healing scratches and restoring transparency. Chem Mater 27:8058–8065CrossRef Wang Y, Li T, Li S, Sun J (2015) Antifogging and frost-resisting polyelectrolyte coatings capable of healing scratches and restoring transparency. Chem Mater 27:8058–8065CrossRef
14.
Zurück zum Zitat Xu F, Li X, Li Y, Sun J (2017) Oil-repellent antifogging films with water-enabled functional and structural healing ability. ACS Appl Mater Interfaces 9:27955–27963CrossRef Xu F, Li X, Li Y, Sun J (2017) Oil-repellent antifogging films with water-enabled functional and structural healing ability. ACS Appl Mater Interfaces 9:27955–27963CrossRef
15.
Zurück zum Zitat Li Y, Fang X, Wang Y, Ma B, Sun J (2016) Highly transparent and water-enabled healable antifogging and frost-resisting films based on poly(vinyl alcohol)-Nafion complexes. Chem Mater 28:6975–6984CrossRef Li Y, Fang X, Wang Y, Ma B, Sun J (2016) Highly transparent and water-enabled healable antifogging and frost-resisting films based on poly(vinyl alcohol)-Nafion complexes. Chem Mater 28:6975–6984CrossRef
16.
Zurück zum Zitat Zhang X, He J (2015) Hydrogen-bonding-supported self-healing antifogging thin films. Sci Rep 5:9227CrossRef Zhang X, He J (2015) Hydrogen-bonding-supported self-healing antifogging thin films. Sci Rep 5:9227CrossRef
17.
Zurück zum Zitat England MW, Urata C, Dunderdale GJ, Hozumi A (2016) Anti-fogging/self-healing properties of clay-containing transparent nanocomposite thin films. ACS Appl Mater Interfaces 8:4318–4322CrossRef England MW, Urata C, Dunderdale GJ, Hozumi A (2016) Anti-fogging/self-healing properties of clay-containing transparent nanocomposite thin films. ACS Appl Mater Interfaces 8:4318–4322CrossRef
18.
Zurück zum Zitat Hu B, Chen L, Lan S, Ren P, Wu S, Liu X, Shi X, Li H, Du Y, Ding F (2018) Layer-by-layer assembly of polysaccharide films with self-healing and antifogging properties for food packaging applications. ACS Appl Nano Mater 1:3733–3740CrossRef Hu B, Chen L, Lan S, Ren P, Wu S, Liu X, Shi X, Li H, Du Y, Ding F (2018) Layer-by-layer assembly of polysaccharide films with self-healing and antifogging properties for food packaging applications. ACS Appl Nano Mater 1:3733–3740CrossRef
19.
Zurück zum Zitat Manabe K, Matsuda M, Nakamura C, Takahashi K, Kyung K-H, Shiratori S (2017) Antifibrinogen, antireflective, antifogging surfaces with biocompatible nano-ordered hierarchical texture fabricated by layer-by-layer self-assembly. Chem Mater 29:4745–4753CrossRef Manabe K, Matsuda M, Nakamura C, Takahashi K, Kyung K-H, Shiratori S (2017) Antifibrinogen, antireflective, antifogging surfaces with biocompatible nano-ordered hierarchical texture fabricated by layer-by-layer self-assembly. Chem Mater 29:4745–4753CrossRef
20.
Zurück zum Zitat Chevallier P, Turgeon S, Sarrabournet C, Turcotte R, Laroche G (2011) Characterization of multilayer anti-fog coatings. ACS Appl Mater Interfaces 3:750–758CrossRef Chevallier P, Turgeon S, Sarrabournet C, Turcotte R, Laroche G (2011) Characterization of multilayer anti-fog coatings. ACS Appl Mater Interfaces 3:750–758CrossRef
21.
Zurück zum Zitat Lee H, Mensire R, Cohen RE, Rubner MF (2011) Strategies for hydrogen bonding based layer-by-layer assembly of poly(vinyl alcohol) with weak polyacids. Macromolecules 45:347–355CrossRef Lee H, Mensire R, Cohen RE, Rubner MF (2011) Strategies for hydrogen bonding based layer-by-layer assembly of poly(vinyl alcohol) with weak polyacids. Macromolecules 45:347–355CrossRef
22.
Zurück zum Zitat Ricciardi R, Auriemma F, De Rosa C, Lauprêtre F (2004) X-ray diffraction analysis of poly(vinyl alcohol) hydrogels, obtained by freezing and thawing techniques. Macromolecules 37:1921–1927CrossRef Ricciardi R, Auriemma F, De Rosa C, Lauprêtre F (2004) X-ray diffraction analysis of poly(vinyl alcohol) hydrogels, obtained by freezing and thawing techniques. Macromolecules 37:1921–1927CrossRef
23.
Zurück zum Zitat Gui W, Yang Y, Zhu XJ (2016) High-efficiency recovery of rare earth ions by hydrolyzed poly(styrene-co-maleic anhydride). J Appl Polym Sci 133:43676CrossRef Gui W, Yang Y, Zhu XJ (2016) High-efficiency recovery of rare earth ions by hydrolyzed poly(styrene-co-maleic anhydride). J Appl Polym Sci 133:43676CrossRef
24.
Zurück zum Zitat Brown PS, Atkinson QDLA, Badyal JPS (2014) Ultrafast oleophobic-hydrophilic switching surfaces for antifogging, self-cleaning, and oil-water separation. ACS Appl Mater Interfaces 6:7504–7511CrossRef Brown PS, Atkinson QDLA, Badyal JPS (2014) Ultrafast oleophobic-hydrophilic switching surfaces for antifogging, self-cleaning, and oil-water separation. ACS Appl Mater Interfaces 6:7504–7511CrossRef
25.
Zurück zum Zitat Tang C, Ye S, Liu H (2007) Electrospinning of poly(styrene-co-maleic anhydride) (SMA) and water-swelling behavior of crosslinked/hydrolyzed SMA hydrogel nanofibers. Polymer 48:4482–4491CrossRef Tang C, Ye S, Liu H (2007) Electrospinning of poly(styrene-co-maleic anhydride) (SMA) and water-swelling behavior of crosslinked/hydrolyzed SMA hydrogel nanofibers. Polymer 48:4482–4491CrossRef
26.
Zurück zum Zitat Kumari S, Nigam D, Agarwal D, Nigam I (2007) Synthesis and characterization of alkali-modified styrene-maleic anhydride copolymer for dispersion of TiO2. J Appl Polym Sci 103:3194–3205CrossRef Kumari S, Nigam D, Agarwal D, Nigam I (2007) Synthesis and characterization of alkali-modified styrene-maleic anhydride copolymer for dispersion of TiO2. J Appl Polym Sci 103:3194–3205CrossRef
27.
Zurück zum Zitat Chen YN, Peng L, Liu T, Wang Y, Shi S, Wang H (2016) Poly(vinyl alcohol)-tannic acid hydrogels with excellent mechanical properties and shape memory behaviors. ACS Appl Mater Interfaces 8:27199–27206CrossRef Chen YN, Peng L, Liu T, Wang Y, Shi S, Wang H (2016) Poly(vinyl alcohol)-tannic acid hydrogels with excellent mechanical properties and shape memory behaviors. ACS Appl Mater Interfaces 8:27199–27206CrossRef
28.
Zurück zum Zitat Mansur HS, Sadahira CM, Souza AN, Mansur AAP (2008) FTIR spectroscopy characterization of poly (vinyl alcohol) hydrogel with different hydrolysis degree and chemically crosslinked with glutaraldehyde. Mater Sci Eng, C 28:539–548CrossRef Mansur HS, Sadahira CM, Souza AN, Mansur AAP (2008) FTIR spectroscopy characterization of poly (vinyl alcohol) hydrogel with different hydrolysis degree and chemically crosslinked with glutaraldehyde. Mater Sci Eng, C 28:539–548CrossRef
29.
Zurück zum Zitat Pompe T, Zschoche S, Herold N, Salchert K, Gouzy MF, Sperling C, Werner C (2003) Maleic anhydride copolymers-A versatile platform for molecular biosurface engineering. Biomacromol 4:1072–1079CrossRef Pompe T, Zschoche S, Herold N, Salchert K, Gouzy MF, Sperling C, Werner C (2003) Maleic anhydride copolymers-A versatile platform for molecular biosurface engineering. Biomacromol 4:1072–1079CrossRef
30.
Zurück zum Zitat Al-Sabagh AM, El-Din MRN, Morsi RE, Elsabee MZ (2009) Styrene-maleic anhydride copolymer esters as flow improvers of waxy crude oil. J Dispersion Sci Technol 30:420–426CrossRef Al-Sabagh AM, El-Din MRN, Morsi RE, Elsabee MZ (2009) Styrene-maleic anhydride copolymer esters as flow improvers of waxy crude oil. J Dispersion Sci Technol 30:420–426CrossRef
31.
Zurück zum Zitat Rhim JW, Park HB, Lee CS, Jun JH, Kim DS, Lee YM (2004) Crosslinked poly(vinyl alcohol) membranes containing sulfonic acid group: proton and methanol transport through membranes. J Membr Sci 238:143–151CrossRef Rhim JW, Park HB, Lee CS, Jun JH, Kim DS, Lee YM (2004) Crosslinked poly(vinyl alcohol) membranes containing sulfonic acid group: proton and methanol transport through membranes. J Membr Sci 238:143–151CrossRef
32.
Zurück zum Zitat Chua CK, Leong KF, Tan KH, Wiria FE, Cheah CM (2004) Development of tissue scaffolds using selective laser sintering of polyvinyl alcohol/hydroxyapatite biocomposite for craniofacial and joint defects. J Mater Sci Mater Med 15:1113–1121CrossRef Chua CK, Leong KF, Tan KH, Wiria FE, Cheah CM (2004) Development of tissue scaffolds using selective laser sintering of polyvinyl alcohol/hydroxyapatite biocomposite for craniofacial and joint defects. J Mater Sci Mater Med 15:1113–1121CrossRef
33.
Zurück zum Zitat Yang CC (2004) Chemical composition and XRD analyses for alkaline composite PVA polymer electrolyte. Mater Lett 58:33–38CrossRef Yang CC (2004) Chemical composition and XRD analyses for alkaline composite PVA polymer electrolyte. Mater Lett 58:33–38CrossRef
34.
Zurück zum Zitat Zare EN, Lakouraj MM, Moghadam PN, Hasanzadeh R (2015) Novel conducting nanocomposite based on polypyrrole and modified poly(styrene-alt-maleic anhydride) via emulsion polymerization: synthesis, characterization, antioxidant, and heavy metal sorbent activity. Polym Compos 36:138–144CrossRef Zare EN, Lakouraj MM, Moghadam PN, Hasanzadeh R (2015) Novel conducting nanocomposite based on polypyrrole and modified poly(styrene-alt-maleic anhydride) via emulsion polymerization: synthesis, characterization, antioxidant, and heavy metal sorbent activity. Polym Compos 36:138–144CrossRef
35.
Zurück zum Zitat Heydari M, Moghadam PN, Fareghi AR, Bahram M, Movagharnezhad N (2015) Synthesis of water-soluble conductive copolymer based on polyaniline. Polym Adv Technol 26:250–254CrossRef Heydari M, Moghadam PN, Fareghi AR, Bahram M, Movagharnezhad N (2015) Synthesis of water-soluble conductive copolymer based on polyaniline. Polym Adv Technol 26:250–254CrossRef
36.
Zurück zum Zitat Dinunzio JC, Miller DA, Yang W (2008) Amorphous compositions using concentration enhancing polymers for improved bioavailability of itraconazole. Mol Pharm 5:968–980CrossRef Dinunzio JC, Miller DA, Yang W (2008) Amorphous compositions using concentration enhancing polymers for improved bioavailability of itraconazole. Mol Pharm 5:968–980CrossRef
37.
Zurück zum Zitat Roy PK, Rawat AS, Choudhary V, Rai PK (2004) Synthesis and analytical application of a chelating resin based on a crosslinked styrene/maleic acid copolymer for the extraction of trace-metal ions. J Appl Polym Sci 94:1771–1779CrossRef Roy PK, Rawat AS, Choudhary V, Rai PK (2004) Synthesis and analytical application of a chelating resin based on a crosslinked styrene/maleic acid copolymer for the extraction of trace-metal ions. J Appl Polym Sci 94:1771–1779CrossRef
38.
Zurück zum Zitat Ping ZH, Nguyen QT, Chen SM, Zhou JQ, Ding YD (2001) States of water in different hydrophilic polymers-DSC and FTIR studies. Polymer 42:8461–8467CrossRef Ping ZH, Nguyen QT, Chen SM, Zhou JQ, Ding YD (2001) States of water in different hydrophilic polymers-DSC and FTIR studies. Polymer 42:8461–8467CrossRef
Metadaten
Titel
Excellent self-healing and antifogging coatings based on polyvinyl alcohol/hydrolyzed poly(styrene-co-maleic anhydride)
verfasst von
Shuai Luo
Xuan Qiao
Qiu-Yu Wang
Yun-Fei Zhang
Ping Fu
Zhi-Dong Lin
Fei-Peng Du
Chun Cheng
Publikationsdatum
02.01.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 7/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-03279-6

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