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Journal of Materials Science
Erschienen in: Journal of Materials Science 13/2018

26.03.2018 | Electronic materials

Photoactive multi-walled carbon nanotubes: synthesis and utilization of benzoin functional MWCNTs

verfasst von: Neşe Kaynak, Ayşen Önen, Müfide Karahasanoğlu

Erschienen in: Journal of Materials Science | Ausgabe 13/2018

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Abstract

This study describes a facile method for the synthesis of functionalized multi-walled carbon nanotubes (MWCNTs) carrying photoactive group. The synthesis of MWCNTs-based macro-photoinitiator was achieved by the esterification reaction between benzoin moiety and acyl chloride functional MWCNTs. Synthesized MWCNT-based photoinitiator (MWCNTs–benzoin) was used in the photopolymerization of styrene to yield polystyrene (PS)-grafted MWCNTs (MWCNTs–PS) by “grafting from” method. The efficiency of MWCNTs–benzoin photoinitiator was determined by evaluating the effect of initiator to monomer ratio and reaction period on photopolymerization of styrene. Fourier transform infrared spectroscopy, Raman and X-ray photoelectron spectroscopy analyses confirmed the covalent bonding for functionalization of MWCNTs and determined the final structures. Thermogravimetric analysis, gel permeation chromatography and UV spectroscopy were performed to evaluate the grafting efficiency of PS that covalently grafted to MWCNTs, and high efficiency of MWCNTs–benzoin as a macro-photoinitiator was also confirmed. Scanning electron microscopy was used to determine the surface morphology of functionalized MWCNTs and MWCNTs–PS.
Vorheriger Artikel Transparent and flexible tactile sensors based on graphene films designed for smart panels
Nächster Artikel Theoretical investigations of Ge1−xSn x alloys (x = 0, 0.333, 0.667, 1) in P42/ncm phase

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Literatur
1.
Iijima S (1991) Helical microtubules of graphitic carbon. Nature 354:56–58CrossRef
2.
Dresselhaus MS, Dresselhaus G, Charlier JC, Hernandez E (2004) Electronic, thermal and mechanical properties of carbon nanotubes. Philos Trans A Math Phys Eng Sci 362:2065–2098CrossRef
3.
Tang Y, Allen BL, Kauffman DR, Star A (2009) Electrocatalytic activity of nitrogen-doped carbon nanotube cups. J Am Chem Soc 131:13200–13201CrossRef
4.
Tasis D, Tagmatarchis N, Bianco A, Prato M (2006) Chemistry of carbon nanotubes. Chem Rev 106:1105–1136CrossRef
5.
Prasek J, Drbohlavova J, Chomoucka J, Hubalek J, Jasek O, Adam V, Kizek R (2011) Methods for carbon nanotubes synthesis—review. J Mater Chem 21:15872–15884CrossRef
6.
Belin T, Epron F (2005) Characterization methods of carbon nanotubes: a review. Mater Sci Eng B119:105–118CrossRef
7.
Lehman JH, Terrones M, Mansfield E, Hurst KE, Meunier V (2011) Evaluating the characteristics of multiwall carbon nanotubes. Carbon 49:2581–2602CrossRef
8.
Niyogi S, Hamon MA, Hu H, Zhao B, Bhowmik P, Sen R, Itkis ME, Haddon RC (2002) Chemistry of single-walled carbon nanotubes. Acc Chem Res 35:1105–1113CrossRef
9.
Spitalsky Z, Tasis D, Papagelis K, Galiotis C (2010) Carbon nanotube–polymer composites: chemistry, processing, mechanical and electrical properties. Prog Polym Sci 35:357–401CrossRef
10.
Sahoo NG, Rana S, Cho JW, Li L, Chan SH (2010) Polymer nanocomposites based on functionalized carbon nanotubes. Prog Polym Sci 35:837–867CrossRef
11.
Richard C, Balavoine F, Schultz P, Ebbesen TW, Mioskowski C (2003) Supramolecular self-assembly of lipid derivatives on carbon nanotubes. Science 300:775–778CrossRef
12.
Martin CR, Kohli P (2003) The emerging field of nanotube biotechnology. Nat Rev 2:29–37
13.
Wepasnick K, Smith B, Bitter J, Fairbrother DH (2010) Chemical and structural characterization of carbon nanotube surfaces. Anal Bioanal Chem 396:1003–1014CrossRef
14.
Hirsch A (2002) Functionalization of single-walled carbon nanotubes. Angew Chem Int Ed 41:1853–1859CrossRef
15.
Tasis D, Tagmatarchis N, Georgakilas V, Prato M (2003) Soluble carbon nanotubes. Chem Eur J 9:4000–4008CrossRef
16.
Dyke CA, Tour JM (2003) Solvent-free functionalization of carbon nanotubes. J Am Chem Soc 125:1156–1157CrossRef
17.
Qin Y, Liu L, Shi J, Wu W, Zhang J, Guo ZX, Yongfang L, Daoban Z (2003) Large scale preparation of solubilized carbon nanotubes. Chem Mater 15:3256–3260CrossRef
18.
Grady BP (2010) Recent developments concerning the dispersion of carbon nanotubes in polymers. Macromol Rapid Commun 31:247–257CrossRef
19.
Li CY, Li L, Cai W, Kodjie SL, Tenneti KK (2005) Nanohybrid shish-kebabs: periodically functionalized carbon nanotubes. Adv Mater 17:1198–1202CrossRef
20.
Eitan A, Jiang K, Dukes D, Andrews R, Schadler LS (2003) Surface modification of multiwalled carbon nanotubes: toward the tailoring of the interface in polymer composites. Chem Mater 15:3198–3201CrossRef
21.
Zhao B, Hu H, Haddon RC (2004) Synthesis and properties of a water-soluble single-walled carbon nanotube–poly(m-aminobenzene sulfonic acid) graft copolymer. Adv Funct Mater 14:71–76CrossRef
22.
Peng H, Alemany LB, Margrave JL, Khabashesku VN (2003) Sidewall carboxylic acid functionalization of single-walled carbon nanotubes. J Am Chem Soc 125:15174–15182CrossRef
23.
Rosca ID, Watari F, Uo M, Akasaka T (2005) Oxidation of multiwalled carbon nanotubes by nitric acid. Carbon 43:3124–3131CrossRef
24.
Smith B, Wepasnick K, Schrote KE, Bertele AR, Ball WP, O’Melia C, Fairbrother DH (2009) Colloidal properties of aqueous suspensions of acid-treated, multi-walled carbon nanotubes. Environ Sci Technol 43:819–825CrossRef
25.
Bergeret C, Cousseau J, Fernandez V, Mevellec J-Y, Lefrant S (2008) Spectroscopic evidence of carbon nanotubes’ metallic character loss induced by covalent functionalization via nitric acid purification. J Phys Chem C 112:16411–16416CrossRef
26.
Moniruzzaman M, Winey KI (2006) Polymer nanocomposites containing carbon nanotubes. Macromolecules 39:5194–5205CrossRef
27.
28.
Gao C, Duan CV, Jin YZ, Li W, Armes SP (2005) Multihydroxy polymer-functionalized carbon nanotubes: synthesis, derivatization, and metal loading. Macromolecules 38:8634–8648CrossRef
29.
Cheng J, Fernando KAS, Veca LM, Sun Y-P, Lamond AI, Lam YW, Cheng SH (2008) Reversible accumulation of PEGylated singlewalled carbon nanotubes in the mammalian nucleus. ACS Nano 2:2085–2094CrossRef
30.
Khun NW, Troconis BCR, Frankel GS (2014) Effects of carbon nanotube content on adhesion strength and wear and corrosion resistance of epoxy composite coatings on AA2024-T3. Prog Org Coat 77:72–80CrossRef
31.
Chen TK, Tien YI, Wei KH (2000) Synthesis and characterization of novel segmented polyurethane/clay nanocomposites. Polymer 41:1345–1353CrossRef
32.
De Volder MF, Tawfick SH, Baughman RH, Hart AJ (2013) Carbon nanotubes: present and future commercial applications. Science 339:535–539CrossRef
33.
Akbar S, Beyou E, Cassagnau P, Chaumont P, Farzi G (2009) Radical grafting of polyethylene onto MWCNTs: a model compound. Polymer 50:2535–2543CrossRef
34.
Pramanik NB, Singha NK (2015) Direct functionalization of multi-walled carbon nanotubes (MWCNTs) via grafting of poly(furfuryl methacrylate) using Diels–Alder “click chemistry” and its thermoreversibility. RSC Adv 5:94321–94327CrossRef
35.
Yang C, Guenzi M, Cicogna F, Gambarotti C, Filippone G, Pinzino C, Passaglia E, Dintcheva NT et al (2016) Grafting of polymer chains on the surface of carbon nanotubes via nitroxide radical coupling reaction. Polymer 65:48–56
36.
Ernould B, Bertrand O, Minoia A, Lazzaroni R, Vlad A, Gohy JF (2017) Electroactive polymer/carbon nanotube hybrid materials for energy storage synthesized via a “grafting to” approach. RSC Adv 7:17301–17310CrossRef
37.
Xu Y, Gao C, Kong H, Yan D, Jin YZ, Watts PCP (2004) Growing multihydroxyl hyperbranched polymers on the surfaces of carbon nanotubes by in situ ring-opening polymerization. Macromolecules 37:8846–8853CrossRef
38.
39.
Baskaran D, Mays JW, Bratcher MS (2004) Polymer-grafted multiwalled carbon nanotubes through surface-initiated polymerization. Angew Chem Int Ed 43:2138–2142CrossRef
40.
Liu Y, Adronov A (2004) Preparation and utilization of catalyst-functionalized single-walled carbon nanotubes for ring-opening metathesis polymerization. Macromolecules 37:4755–4760CrossRef
41.
Qu L, Veca LM, Lin Y, Kitaygorodskiy A, Chen B, McCall AM, Connell JW, Sun YP (2005) Soluble nylon-functionalized carbon nanotubes from anionic ring-opening polymerization from nanotube surface. Macromolecules 38:10328–10331CrossRef
42.
Plambeck L Jr (1956) Photographic preparation of relief images. US Patent 2760863
43.
Esen DS, Arsu N, Silva JP, Jockusch S, Turro NJ (2013) Benzoin type photoinitiator for free radical polymerization. J Polym Sci Polym Chem 51:1865–1871CrossRef
44.
Frick E, Schweigert C, Noble BB, Ernst HA, Lauer A, Liang Y, Dominik V, Coote ML et al (2016) Toward a quantitative description of radical photoinitiator structure–reactivity correlations. Macromolecules 49:80–89CrossRef
45.
Yağcı Y, Önen A, Schnabel W (1991) Block copolymers by combination of radical and promoted cationic polymerization routes. Macromolecules 24:4620–4623CrossRef
46.
Fu K, Huang W, Lin Y, Riddle LA, Carroll DL, Sun YP (2001) Defunctionalization of functionalized carbon nanotubes. Nano Lett 8:439–441CrossRef
47.
Tucureanu V, Matei A, Avram AM (2016) FTIR spectroscopy for carbon family study. Crit Rev Anal Chem 46:502–520CrossRef
48.
Ma PC, Kim JK (2011) Carbon nanotubes for polymer reinforcement. CRC Press, Boca Raton
49.
Jorio A, Pimenta MA, Filho AGS, Saito R, Dresselhaus G, Dresselhaus MS (2003) Characterizing carbon nanotube samples with resonance raman scattering. New J Phys 139:1–17
50.
Datsyuk V, Kalyva M, Papagelis K, Parthenios J, Tasis D, Siokou A, Kallitsis I, Galiotis C et al (2008) Chemical oxidation of multiwalled carbon nanotubes. Carbon 46:833–840CrossRef
51.
Zhaoa Z, Yanga Z, Huc Y, Li J, Fana X (2013) Multiple functionalization of multi-walled carbon nanotubes with carboxyl and amino groups. Appl Surf Sci 276:476–481CrossRef
Metadaten
Titel
Photoactive multi-walled carbon nanotubes: synthesis and utilization of benzoin functional MWCNTs
verfasst von
Neşe Kaynak
Ayşen Önen
Müfide Karahasanoğlu
Publikationsdatum
26.03.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 13/2018
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2233-4

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