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Journal of Materials Science
Erschienen in: Journal of Materials Science 1/2019

20.08.2018 | Polymers

A Salen-based covalent organic polymer as highly selective and sensitive fluorescent sensor for detection of Al3+, Fe3+ and Cu2+ ions

verfasst von: Pengyao Ju, Qing Su, Ziqian Liu, Xiaodong Li, Bixuan Guo, Wanting Liu, Guanghua Li, Qiaolin Wu

Erschienen in: Journal of Materials Science | Ausgabe 1/2019

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Abstract

A novel covalent organic polymer (Salen-COP) based on Salen-type Schiff base was synthesized by one-pot protocol involving the self-condensation of 3-formyl-4-hydroxyphenylboronic acid and the subsequent aldehyde–amine condensation with benzene-1,2-diamine. The Salen-COP was characterized by 13C CP/MAS NMR, Fourier transform infrared spectroscopy, thermogravimetric analysis, X-ray photoelectron spectroscopy and X-ray powder diffraction spectrometry analysis. The morphological features of Salen-COP were also analyzed using scanning electron microscopy. The Salen-COP exhibited the significant fluorescence enhancing for the sensing of Al3+, while the obtained polymer also exhibited the dramatic fluorescence quenching for the sensing of Fe3+ and Cu2+. The detection limits were calculated to be 0.248 µM for Salen-COP@Al3+, 0.545 µM for Salen-COP@Fe3+ and 0.140 µM for Salen-COP@Cu2+, respectively. Furthermore, the Salen-COP was founded to be a reversible chemosensor for Al3+, Fe3+ and Cu2+ ions, which provided a unique opportunity in the development of multi-response polymer-based sensors.
Vorheriger Artikel Response of microstructure to annealing in in situ Cu–Nb microcomposite
Nächster Artikel Thermomechanical characterization of leathers under tension using infrared thermography

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Metadaten
Titel
A Salen-based covalent organic polymer as highly selective and sensitive fluorescent sensor for detection of Al3+, Fe3+ and Cu2+ ions
verfasst von
Pengyao Ju
Qing Su
Ziqian Liu
Xiaodong Li
Bixuan Guo
Wanting Liu
Guanghua Li
Qiaolin Wu
Publikationsdatum
20.08.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 1/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2821-3

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