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Journal of Materials Science
Erschienen in: Journal of Materials Science 1/2019

27.08.2018 | Composites

Preparation of stable and high-efficient poly(m-phenylenediamine)/reduced graphene oxide composites for hexavalent chromium removal

verfasst von: Linfeng Jin, Lei Huang, Lili Ren, Yingjie He, Jingwen Tang, Sheng Wang, Weichun Yang, Haiying Wang, Liyuan Chai

Erschienen in: Journal of Materials Science | Ausgabe 1/2019

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Abstract

Structural instability of polymers under strong acidic condition severely limits their application in the field of environment. A synthetic strategy for the preparation of poly(m-phenylenediamine)/reduced graphene oxide (PmPD/rGO) composites was proposed for Cr(VI) removal in strong acidic solution, which involved in situ reduction of graphene oxide (GO) and assembly of PmPD nanoparticles. Effects of in situ reduction of GO on oxidation polymerization, property and Cr(VI) adsorption capacity of composites were investigated methodically. Compared to pure PmPD, PmPD/rGO composites exhibited favorable stability in strong acidic solution. Moreover, the polymerization yield of PmPD/rGO composites increased from 75 to 91%. The maximum Cr(VI) adsorption capacity of composites calculated by the Langmuir model reached 526.24 mg g−1. The mechanisms of PmPD/rGO composites preparation and Cr(VI) removal were analyzed in detail. The synthetic strategy shows promising prospect to expand application of polymers, especially for Cr(VI) removal in strong acidic solution.
Vorheriger Artikel Facile synthesis of magnetic macroporous polymer/MOF composites as separable catalysts
Nächster Artikel Preparation of graphene/copper composites using solution-combusted porous sheet-like cuprous oxide

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Metadaten
Titel
Preparation of stable and high-efficient poly(m-phenylenediamine)/reduced graphene oxide composites for hexavalent chromium removal
verfasst von
Linfeng Jin
Lei Huang
Lili Ren
Yingjie He
Jingwen Tang
Sheng Wang
Weichun Yang
Haiying Wang
Liyuan Chai
Publikationsdatum
27.08.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 1/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-2844-9

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