Skip to main content
Fachgebiete
Automobil + Motoren Bauwesen + Immobilien Business IT + Informatik Elektrotechnik + Elektronik Energie + Nachhaltigkeit Finance + Banking Management + Führung Marketing + Vertrieb Maschinenbau + Werkstoffe Versicherung + Risiko
DE
EN
Bücher
Zeitschriften
Themenseiten
Organisationspsychologie Projektmanagement Marketing Smart Manufacturing
Weitere Formate
Podcasts Webinare Technik Webinare Wirtschaft Kongresse Veranstaltungskalender Awards
Jetzt Einzelzugang starten
Zugang für Unternehmen
Referenzkunden
SLX-Digitalkonferenz: Zukunftswerkstatt 2024

Mehr Umsatz mit Top-Kontakten

Am 7. Mai erfahren Sie, wie Vertriebsteams Leadgenerierung, Leadnurturing und Leadstrategien effizient steuern können.
Erweiterte Suche
Anmelden
nach oben
Journal of Materials Science
Erschienen in: Journal of Materials Science 4/2019

31.10.2018 | Composites

Investigation of reinforced performance of modified graphene oxide/high solid content polysiloxane nanocomposite coating films

verfasst von: Xinhai Zhang, Xiaohong Ying, Mengmeng Zhang, Xufeng Yu, Gang Sun, Bo You

Erschienen in: Journal of Materials Science | Ausgabe 4/2019

Einloggen

Aktivieren Sie unsere intelligente Suche, um passende Fachinhalte oder Patente zu finden.

search-config
loading …

Abstract

Graphene oxide was modified using long-chain silicone. The modified graphene oxide (MGO) was obtained with a broader spacing of layers (1.45 nm) which means more beneficial to polysiloxane entering into the laminates of MGO sheets. Then, MGO sheets were combined with polysiloxane which synthesized without any organic solvent to prepare nanocomposite coatings via cross-linking curing reaction. The solid content of polysiloxane can be reached up to 86%. Due to strong interfacial interaction and synergistic reinforcing between MGO sheets and polysiloxane, when blended with 1.00 wt% of MGO, the micro-hardness and elastic modulus of coating films were increased by 57% and 24% comparing with pure polysiloxane coating film, respectively. Subsequently, a 48% improvement of macro-scratch resistance can be achieved. Simultaneously, MGO/polysiloxane coating film showed excellent wear resistance due to the unique two-dimensional geometry and low frictional coefficient of MGO sheets at work in homogeneous dispersion system.
Vorheriger Artikel Understanding the cross-linking reactions in highly oxidized graphene/epoxy nanocomposite systems
Nächster Artikel Changes in vibrational properties of compression wood in conifer due to hygrothermal treatment and their relationship with hygrothermal recovery strain

Sie haben noch keine Lizenz? Dann Informieren Sie sich jetzt über unsere Produkte:

Springer Professional "Wirtschaft+Technik"

Online-Abonnement

Mit Springer Professional "Wirtschaft+Technik" erhalten Sie Zugriff auf:

  • über 102.000 Bücher
  • über 537 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Finance + Banking
  • Management + Führung
  • Marketing + Vertrieb
  • Maschinenbau + Werkstoffe
  • Versicherung + Risiko

Jetzt Wissensvorsprung sichern!

Jetzt informieren

Springer Professional "Technik"

Online-Abonnement

Mit Springer Professional "Technik" erhalten Sie Zugriff auf:

  • über 67.000 Bücher
  • über 390 Zeitschriften

aus folgenden Fachgebieten:

  • Automobil + Motoren
  • Bauwesen + Immobilien
  • Business IT + Informatik
  • Elektrotechnik + Elektronik
  • Energie + Nachhaltigkeit
  • Maschinenbau + Werkstoffe




 

Jetzt Wissensvorsprung sichern!

Jetzt informieren
Anhänge
Nur mit Berechtigung zugänglich
Literatur
1.
Nemeth S, Liu Y (2009) Mechanical properties of hybrid sol–gel derived films as a function of composition and thermal treatment. Thin Solid Films 517:4888–4891CrossRef
2.
Ballarre J, López DA, Cavalieri AL (2009) Frictional and adhesive behavior of organic–inorganic hybrid coatings on surgical grade stainless steel using nano-scratching technique. Wear 266:1165–1170CrossRef
3.
Chen X, Zhou SX, You B, Wu LM (2011) Ambient-curable polysiloxane coatings: structure and mechanical properties. J Sol-Gel Sci Technol 58:490–500CrossRef
4.
Barletta M, Gisario A, Puopolo M, Vesco S (2015) Scratch, wear and corrosion resistant organic inorganic hybrid materials for metals protection and barrier. Mater Des 69:130–140CrossRef
5.
Guyot A, Chu F, Schneider M, Graillat C, Mckenna TF (2002) High solid content latexes. Prog Polym Sci 27:1573–1615CrossRef
6.
Herk AV (2013) Chemistry and technology of emulsion polymerisation. Wiley, New York, pp 46–78CrossRef
7.
Martí M, Molina L, Alemán C, Armelin C (2013) Novel epoxy coating based on DMSO as a green solvent, reducing drastically the volatile organic compound content and using conducting polymers as a nontoxic anticorrosive pigment. ACS Sustain Chem Eng 1:1609–1618CrossRef
8.
9.
Pinheiro CT, Quina MJ, Gando-Ferreira LM (2018) New methodology of solvent selection for the regeneration of waste lubricant oil using greenness criteria. ACS Sustain Chem Eng 6:6820–6828CrossRef
10.
11.
12.
Hu H, Zhao SY, Sun G, Zhong YJ, You B (2018) Evaluation of scratch resistance of functionalized graphene oxide/polysiloxane nanocomposite coatings. Prog Org Coat 117:118–129CrossRef
13.
Berman D, Deshmukh SA, Sankaranarayanan SK, Erdemir K, Sumant AV (2015) Macroscale superlubricity enabled by graphene nanoscroll formation. Science 348:1118–1122CrossRef
14.
Berman D, Erdemir A, Sumant AV (2013) Reduced wear and friction enabled by graphene layers on sliding steel surfaces in dry nitrogen. Carbon 59:167–175CrossRef
15.
Berman D, Erdemir A, Sumant AV (2013) Few layer graphene to reduce wear and friction on sliding steel surfaces. Carbon 54:454–459CrossRef
16.
Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1339CrossRef
17.
Stankovich S, Piner RD, Nguyen SBT, Rouff RS (2006) Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon 44:3342–3347CrossRef
18.
Lotya M, Hernandez Y, King PJ, Smith RJ, Nicolosi V, Karlsson LS, Blighe FM, De S, Wang ZM, McGovern IT, Duesberg GS, Coleman JN (2009) Liquid phase production of graphene by exfoliation of graphite in surfactant/water solutions. J Am Chem Soc 131:3611–3620CrossRef
19.
Peng L, Xu Z, Liu Z, Wei Y, Sun HY, Li Z, Zhao XL, Gao C (2015) An iron-based green approach to 1-h production of single-layer graphene oxide. Nat Commun 6:5716CrossRef
20.
Lei D, Chen Z, Zhao X, Ma J, Lin S, Li M, Bao Y, Chu L, Leng K, Lu H, Loh KP (2018) A non-dispersion strategy for large-scale production of ultra-high concentration graphene slurries in water. Nat Commun 9:76CrossRef
21.
Papageorgiou DG, Kinloch IA, Young RJ (2017) Mechanical properties of graphene and graphene-based nanocomposites. Prog Polym Sci 90:75–127
22.
Qi B, Yuan Z, Liu S, Yang L, Yu J (2014) Mechanical and thermal properties of epoxy composites containing graphene oxide and liquid crystalline epoxy. Fiber Polym 15:326–333CrossRef
23.
Wang Q, Kaminska I, Niedziolka JJ, Opallo M, Li M, Boukherroub R, Szunerits S (2013) Sensitive sugar detection using 4-aminophenylboronic acid modified graphene. Biosens Bioelectron 50:331–337CrossRef
24.
Zhao HY, Wu LG, Zhou ZJ, Zhang L, Chen HL (2013) Improving the antifouling property of polysulfone ultrafiltration membrane by incorporation of isocyanate-treated graphene oxide. Phys Chem Chem Phys 15:9084–9092CrossRef
25.
Stankovich S, Piner RD, Nguyen SBT, Ruoff RS (2006) Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets. Carbon 44:3342–3347CrossRef
26.
Chen KL, Zhou SX (2015) Fabrication of ultraviolet-responsive microcapsules via Pickering emulsion polymerization using modified nano-silica/nano-titania as Pickering agents. RSC Adv 5:13850–13856CrossRef
27.
Han J, Browning R, Sue HJ (2009) Understanding of scratch-induced damage mechanisms in polymers. Polymer 50:4056–4065CrossRef
28.
Karaduman Y, Onal L (2013) Dynamic mechanical and thermal properties of enzyme-treated jute/polyester composites. J Compos Mater 47:2361–2370CrossRef
29.
Huang T, Xin Y, Li TS, Nutt S, Su C, Chen HM, Liu P, Lai ZL (2013) Modified graphene/polyimide nanocomposites: reinforcing and tribological effects. ACS Appl Mater Interfaces 5:4878–4891CrossRef
30.
Huang T, Lu RG, Su C, Wang HN, Guo Z, Liu P, Huang ZY, Chen HM, Li TS (2012) Chemically modified graphene/polyimide composite films based on utilization of covalent bonding and oriented distribution. ACS Appl Mater Interfaces 4:2699–2708CrossRef
31.
Li C, Xiang M, Ye L (2016) Intercalation behavior and orientation structure of graphene oxide/polyethylene glycol hybrid material. RSC Adv 6:72193–72200CrossRef
32.
Zhou Y, Bao QL, Tang LAL, Zhong YL, Loh KP (2009) Hydrothermal dehydration for the “green” reduction of exfoliated graphene oxide to graphene and demonstration of tunable optical limiting properties. Chem Mater 21:2950–2956CrossRef
33.
Ramanathan T, Abdala AAA, Stankovich S, Dikin DA, Herrera-alonso M, Piner RD, Adamson DH, Schniepp HC, Chen X, Ruoff RS, Nguyen ST, Aksay IA, Prud’homme RK, Brinson LC (2008) Functionalized graphene sheets for polymer nanocomposites. Nat Nanotechnol 6:327–331CrossRef
34.
Slinckx M, Henry N, Krebs A, Uytterhoeven G (2000) High-solids automotive coatings. Prog Org Coat 38:163–173CrossRef
35.
Schiavon M, Martini LM, Corrà C, Scapinello M, Coller G, Tosi P, Ragazzi M (2017) Characterisation of volatile organic compounds (VOCs) released by the composting of different waste matrices. Environ Pollut 231:845–853CrossRef
36.
Ho J, Mudraboyina B, Spence-Elder C, Resendes R, Cunningham MF, Jessop PG (2018) Water-borne coatings that share the mechanism of action of oil-based coatings. Green Chem 20:1899–1905CrossRef
37.
Wang J, Li C, Xu B (2009) Basic principle, advance and current application situation of sol–gel method. Chem Ind Eng 26:273–277
38.
Vidal L, Gharzouni A, Joussein E, Colas JM, Cornette J, AbsiS J, Rossignol S (2017) Determination of the polymerization degree of various alkaline solutions: Raman investigation. J Sol-Gel Sci Technol 83:1–11CrossRef
39.
Lee S, Cho IS, Ji HL, Kim DH, Kim DW, Kim JY, Shin H, Lee JK, Jung HS, Park NG, Kim K, Ko MJ, Hong KS (2010) Two-step sol−gel method-based TiO2 nanoparticles with uniform morphology and size for efficient photo-energy conversion devices. Chem Mater 22:1958–1965CrossRef
40.
Min CY, Nie P, Ying L, Shen D, Zeng M, Li N (2014) Preparation and tribological properties of high temperature resistance graphene oxide/polyimide nanocomposites. J Solid Rocket Technol 4:569–573
41.
Lakshmi RV, Bharathidasan T, Basu BJ (2011) Superhydrophobic sol–gel nanocomposite coatings with enhanced hardness. Appl Surf Sci 257:10421–10426CrossRef
42.
Zhou SX, Ding X, Wu LM (2013) Fabrication of ambient-curable superhydrophobic fluoropolysiloxane/TiO2 nanocomposite coatings with good mechanical properties and durability. Prog Org Coat 76:563–570CrossRef
43.
Ding X, Zhou SX, Gu GX, Wu LM (2011) Facile fabrication of superhydrophobic polysiloxane/magnetite nanocomposite coatings with electromagnetic shielding property. J Coat Technol Res 8:757–764CrossRef
44.
Li CJ, Xiang M, Zhao XW, Ye L (2017) In situ synthesis of monomer casting nylon-6/graphene-polysiloxane nano-composites: intercalation structure, synergistic reinforcing and friction-reducing effect. ACS Appl Mater Interfaces 9:33176–33190CrossRef
45.
Li CJ, Xiang M, Ye L (2017) Intercalation structure and highly enhancing tribological performance of monomer casting nylon-6/graphene nano-composites. Compos A Appl Sci Manuf 95:274–285CrossRef
46.
Wu P, Li XM, Zhang CH, Lin SY, Sun HY, Lin CT, Zhu HW, Liu JB (2017) Self-assembled graphene film as low friction solid lubricant in macroscale contact. ACS Appl Mater Interfaces 9:21554–21562CrossRef
47.
Arif T, Colas G, Filleter T (2018) Effect of humidity and water intercalation on the tribological behavior of graphene and graphene oxide. ACS Appl Mater Interfaces 10:22537–22544CrossRef
48.
Liang JJ, Huang Y, Zhang L, Wang Y, Ma YF, Guo TY, Chen YS (2010) Molecular-level dispersion of graphene into poly(vinyl alcohol) and effective reinforcement of their nanocomposites. Adv Funct Mater 19:2297–2302CrossRef
49.
EI-Ghazaly A, Anis G, Salem HG (2017) Effect of graphene addition on the mechanical and tribological behaviorof nanostructured AA2124 self-lubricating metal matrix composite. Compos A Appl Sci Manuf 95:325–336CrossRef
Metadaten
Titel
Investigation of reinforced performance of modified graphene oxide/high solid content polysiloxane nanocomposite coating films
verfasst von
Xinhai Zhang
Xiaohong Ying
Mengmeng Zhang
Xufeng Yu
Gang Sun
Bo You
Publikationsdatum
31.10.2018
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 4/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-018-3077-7

Weitere Artikel der Ausgabe 4/2019

Journal of Materials Science 4/2019 Zur Ausgabe

Electronic materials

Accurate change of carrier types within ultrathin MoTe2 field-effect transistors with the time exposed to ambient air

Materials for life sciences

Bioluminescence-initiated photodynamic therapy bridged on high-luminescent carbon dots-conjugated protoporphyrin IX

Metals

Effect of U and Th trace additions on the precipitation strengthening of Al–0.09Sc (at.%) alloy

Electronic materials

A hybrid thermal diode based on phase transition materials

Electronic materials

A facile room-temperature synthesis of three-dimensional coral-like Ag2S nanostructure with enhanced photocatalytic activity

Materials for life sciences

Flexible substrate-based thermo-responsive valve applied in electromagnetically powered drug delivery system

Premium Partner

    Marktübersichten

    Die im Laufe eines Jahres in der „adhäsion“ veröffentlichten Marktübersichten helfen Anwendern verschiedenster Branchen, sich einen gezielten Überblick über Lieferantenangebote zu verschaffen. 

    Zur Marktübersicht
    Bildnachweise