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Erschienen in: Journal of Materials Science 11/2019

27.02.2019 | Composites

Facile preparation of halloysite nanotube-modified polyvinylidene fluoride composite membranes for highly efficient oil/water emulsion separation

verfasst von: Qianqian Wang, Jiuyun Cui, Siwei Liu, Jia Gao, Jihui Lang, Chunxiang Li, Yongsheng Yan

Erschienen in: Journal of Materials Science | Ausgabe 11/2019

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Abstract

The worldwide oily wastewater is one of the most serious environmental problems. The current membrane separation technology has received an increasing attention toward oil/water emulsions separation. Here, a high-efficient superhydrophilic and underwater superoleophobic membrane with improved antifouling property was fabricated based on modified halloysite nanotubes anchored at polyvinylidene fluoride/graphene oxide membrane surface via polydopamine adhesive. The composite membrane exhibited an outstanding antifouling performance as well as high pure water flux (1500 L m−2 h−1) under gravity driven. Besides, the as-prepared composite membrane could separate both surfactant-free and surfactant-stabilized oil/water emulsions with separation efficiency up to 99.5%. Moreover, this facile preparation and eco-friendly composite membrane provides promising practical application toward environmental remediation.

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Literatur
1.
Zurück zum Zitat Dai J, Chang Z, Xie A, Zhang R, Tian S, Ge W, Yan Y, Li C, Xu W, Shao R (2018) One-step assembly of Fe(III)-CMC chelate hydrogel onto nanoneedle-like CuO@Cu membrane with superhydrophilicity for oil–water separation. Appl Surf Sci 440:560–569CrossRef Dai J, Chang Z, Xie A, Zhang R, Tian S, Ge W, Yan Y, Li C, Xu W, Shao R (2018) One-step assembly of Fe(III)-CMC chelate hydrogel onto nanoneedle-like CuO@Cu membrane with superhydrophilicity for oil–water separation. Appl Surf Sci 440:560–569CrossRef
2.
Zurück zum Zitat Kajitvichyanukul P, Hung YT, Wang LK (2011) Membrane technologies for oil–water separation. Springer, Berlin, pp 639–668 Kajitvichyanukul P, Hung YT, Wang LK (2011) Membrane technologies for oil–water separation. Springer, Berlin, pp 639–668
3.
Zurück zum Zitat Dubansky B, Whitehead A, Miller JT, Rice CD, Galvez F (2013) Multitissue molecular, genomic, and developmental effects of the deepwater horizon oil spill on resident gulf killifish (Fundulus grandis). Environ Sci Technol 47:5074–5082CrossRef Dubansky B, Whitehead A, Miller JT, Rice CD, Galvez F (2013) Multitissue molecular, genomic, and developmental effects of the deepwater horizon oil spill on resident gulf killifish (Fundulus grandis). Environ Sci Technol 47:5074–5082CrossRef
4.
Zurück zum Zitat Diban N, Aguayo AT, Bilbao J, Urtiaga A, Ortiz I (2013) Membrane reactors for in situ water removal: a review of applications. Ind Eng Chem Res 52:10342–10354CrossRef Diban N, Aguayo AT, Bilbao J, Urtiaga A, Ortiz I (2013) Membrane reactors for in situ water removal: a review of applications. Ind Eng Chem Res 52:10342–10354CrossRef
5.
Zurück zum Zitat Coca J, Gutiérrez G, Benito J (2013) Treatment of oily wastewater by membrane hybrid processes. Springer, Dordrecht, pp 35–61 Coca J, Gutiérrez G, Benito J (2013) Treatment of oily wastewater by membrane hybrid processes. Springer, Dordrecht, pp 35–61
6.
Zurück zum Zitat Kwon G, Kota AK, Li Y, Sohani A, Mabry JM, Tuteja A (2012) On-demand separation of oil–water mixtures. Adv Mater 24:3666–3671CrossRef Kwon G, Kota AK, Li Y, Sohani A, Mabry JM, Tuteja A (2012) On-demand separation of oil–water mixtures. Adv Mater 24:3666–3671CrossRef
7.
Zurück zum Zitat Xie A, Dai J, Ma C, Cui J, Chen Y, Lang J, Gao M, Li C, Yan Y (2018) Construction of caterpillar-like cobalt-nickel hydroxide/carbon cloth hierarchical architecture with reversible wettability towards on-demand oil–water separation. Appl Surf Sci 462:659–668CrossRef Xie A, Dai J, Ma C, Cui J, Chen Y, Lang J, Gao M, Li C, Yan Y (2018) Construction of caterpillar-like cobalt-nickel hydroxide/carbon cloth hierarchical architecture with reversible wettability towards on-demand oil–water separation. Appl Surf Sci 462:659–668CrossRef
8.
Zurück zum Zitat Peng Y, Guo Z (2016) Recent advances in biomimetic thin membranes applied in emulsified oil/water separation. J Mater Chem A 4:15749–15770CrossRef Peng Y, Guo Z (2016) Recent advances in biomimetic thin membranes applied in emulsified oil/water separation. J Mater Chem A 4:15749–15770CrossRef
9.
Zurück zum Zitat Chu Z, Seeger S (2015) Multifunctional hybrid porous micro-/nanocomposite materials. Adv Mater 27:7775CrossRef Chu Z, Seeger S (2015) Multifunctional hybrid porous micro-/nanocomposite materials. Adv Mater 27:7775CrossRef
10.
Zurück zum Zitat Chen L, Wu Y, Dong H, Meng M, Li C, Yan Y, Chen J (2018) An overview on membrane strategies for rare earths extraction and separation. Sep Purif Technol 197:70–85CrossRef Chen L, Wu Y, Dong H, Meng M, Li C, Yan Y, Chen J (2018) An overview on membrane strategies for rare earths extraction and separation. Sep Purif Technol 197:70–85CrossRef
11.
Zurück zum Zitat Cao Y, Liu N, Zhang W, Feng L, Wei Y (2016) One-step coating toward multifunctional applications: oil/water mixtures and emulsions separation and contaminants adsorption. ACS Appl Mater Interfaces 8:3333–3339CrossRef Cao Y, Liu N, Zhang W, Feng L, Wei Y (2016) One-step coating toward multifunctional applications: oil/water mixtures and emulsions separation and contaminants adsorption. ACS Appl Mater Interfaces 8:3333–3339CrossRef
12.
Zurück zum Zitat Zhou C, Cheng J, Hou K, Zhao A, Pi P, Wen X, Xu S (2016) Superhydrophilic and underwater superoleophobic titania nanowires surface for oil repellency and oil/water separation. Chem Eng J 301:249–256CrossRef Zhou C, Cheng J, Hou K, Zhao A, Pi P, Wen X, Xu S (2016) Superhydrophilic and underwater superoleophobic titania nanowires surface for oil repellency and oil/water separation. Chem Eng J 301:249–256CrossRef
13.
Zurück zum Zitat Pearce G (2007) Introduction to membranes: membrane selection. Filtr Sep 44:35–37CrossRef Pearce G (2007) Introduction to membranes: membrane selection. Filtr Sep 44:35–37CrossRef
14.
Zurück zum Zitat Zularisam AW, Ismail AF, Salim MR (2007) Fabrication, fouling and foulant analyses of asymmetric polysulfone (PSF) ultrafiltration membrane fouled with natural organic matter (NOM) source waters. J Membr Sci 299:97–113CrossRef Zularisam AW, Ismail AF, Salim MR (2007) Fabrication, fouling and foulant analyses of asymmetric polysulfone (PSF) ultrafiltration membrane fouled with natural organic matter (NOM) source waters. J Membr Sci 299:97–113CrossRef
15.
Zurück zum Zitat Gao Y, Li Z, Cheng B, Su K (2018) Superhydrophilic poly(p-phenylene sulfide) membrane preparation with acid/alkali solution resistance and its usage in oil/water separation. Sep Purif Technol 192:262–270CrossRef Gao Y, Li Z, Cheng B, Su K (2018) Superhydrophilic poly(p-phenylene sulfide) membrane preparation with acid/alkali solution resistance and its usage in oil/water separation. Sep Purif Technol 192:262–270CrossRef
16.
Zurück zum Zitat Zhao ZP, Wang Z, Wang SC (2003) Formation, charged characteristic and BSA adsorption behavior of carboxymethyl chitosan/PES composite MF membrane. J Membr Sci 217:151–158CrossRef Zhao ZP, Wang Z, Wang SC (2003) Formation, charged characteristic and BSA adsorption behavior of carboxymethyl chitosan/PES composite MF membrane. J Membr Sci 217:151–158CrossRef
17.
Zurück zum Zitat Wu QY, Wan LS, Xu ZK (2013) Centimeter-scale giant spherulites in mixtures of polar polymers and crystallizable diluents: morphology, structure, formation and application. RSc Adv 3:17105–17112CrossRef Wu QY, Wan LS, Xu ZK (2013) Centimeter-scale giant spherulites in mixtures of polar polymers and crystallizable diluents: morphology, structure, formation and application. RSc Adv 3:17105–17112CrossRef
18.
Zurück zum Zitat Cui J, Zhou Z, Xie A, Wang Q, Liu S, Lang J, Yan Y, Dai J (2019) Facile preparation of grass-like structured NiCo-LDH-PVDF composite membrane for efficient oil–water emulsion separation. J Membr Sci 573:226–233CrossRef Cui J, Zhou Z, Xie A, Wang Q, Liu S, Lang J, Yan Y, Dai J (2019) Facile preparation of grass-like structured NiCo-LDH-PVDF composite membrane for efficient oil–water emulsion separation. J Membr Sci 573:226–233CrossRef
19.
Zurück zum Zitat Kim JF, Jung JT, Wang HH, Lee SY, Moore T, Sanguineti A, Drioli E, Lee YM (2016) Microporous PVDF membranes via thermally induced phase separation (TIPS) and stretching methods. J Membr Sci 509:94–104CrossRef Kim JF, Jung JT, Wang HH, Lee SY, Moore T, Sanguineti A, Drioli E, Lee YM (2016) Microporous PVDF membranes via thermally induced phase separation (TIPS) and stretching methods. J Membr Sci 509:94–104CrossRef
20.
Zurück zum Zitat Hu S, Yu L, Yin J, Wang H, Yuan X, Li Q (2014) Effect of different binders on electrochemical properties of LiFePO4/C cathode material in lithium ion batteries. Chem Eng J 237:497–502CrossRef Hu S, Yu L, Yin J, Wang H, Yuan X, Li Q (2014) Effect of different binders on electrochemical properties of LiFePO4/C cathode material in lithium ion batteries. Chem Eng J 237:497–502CrossRef
21.
Zurück zum Zitat Cao Z, Hao T, Wang P, Zhang Y, Cheng B, Yuan T, Meng J (2017) Surface modified glass fiber membranes with superior chemical and thermal resistance for O/W separation. Chem Eng J 309:30–40CrossRef Cao Z, Hao T, Wang P, Zhang Y, Cheng B, Yuan T, Meng J (2017) Surface modified glass fiber membranes with superior chemical and thermal resistance for O/W separation. Chem Eng J 309:30–40CrossRef
22.
Zurück zum Zitat Duong PHH, Nunes SP, Chung TS (2016) Dual-skinned polyamide/poly(vinylidene fluoride)/cellulose acetate membranes with embedded woven. J Membr Sci 520:840–849CrossRef Duong PHH, Nunes SP, Chung TS (2016) Dual-skinned polyamide/poly(vinylidene fluoride)/cellulose acetate membranes with embedded woven. J Membr Sci 520:840–849CrossRef
23.
Zurück zum Zitat Zhang W, Shi Z, Zhang F, Liu X, Jin J, Jiang L (2013) Superhydrophobic and superoleophilic PVDF membranes for effective separation of water-in-oil emulsions with high flux. Adv Mater 25:2071–2076CrossRef Zhang W, Shi Z, Zhang F, Liu X, Jin J, Jiang L (2013) Superhydrophobic and superoleophilic PVDF membranes for effective separation of water-in-oil emulsions with high flux. Adv Mater 25:2071–2076CrossRef
24.
Zurück zum Zitat Shi H, He Y, Pan Y, Di H, Zeng G, Zhang L, Zhang C (2016) A modified mussel-inspired method to fabricate TiO2 decorated superhydrophilic PVDF membrane for oil/water separation. J Membr Sci 506:60–70CrossRef Shi H, He Y, Pan Y, Di H, Zeng G, Zhang L, Zhang C (2016) A modified mussel-inspired method to fabricate TiO2 decorated superhydrophilic PVDF membrane for oil/water separation. J Membr Sci 506:60–70CrossRef
25.
Zurück zum Zitat Yang X, He Y, Zeng G, Chen X, Shi H, Qing D, Li F, Chen Q (2017) Bio-inspired method for preparation of multiwall carbon nanotubes decorated superhydrophilic poly(vinylidene fluoride) membrane for oil/water emulsion separation. Chem Eng J 321:245–256CrossRef Yang X, He Y, Zeng G, Chen X, Shi H, Qing D, Li F, Chen Q (2017) Bio-inspired method for preparation of multiwall carbon nanotubes decorated superhydrophilic poly(vinylidene fluoride) membrane for oil/water emulsion separation. Chem Eng J 321:245–256CrossRef
26.
Zurück zum Zitat Cui J, Zhou Z, Xie A, Meng M, Cui Y, Liu S, Lu J, Zhou S, Yan Y, Dong H (2018) Bio-inspired fabrication of superhydrophilic nanocomposite membrane based on surface modification of SiO2 anchored by polydopamine towards effective oil–water emulsions separation. Sep Purif Technol 209:434–442CrossRef Cui J, Zhou Z, Xie A, Meng M, Cui Y, Liu S, Lu J, Zhou S, Yan Y, Dong H (2018) Bio-inspired fabrication of superhydrophilic nanocomposite membrane based on surface modification of SiO2 anchored by polydopamine towards effective oil–water emulsions separation. Sep Purif Technol 209:434–442CrossRef
27.
Zurück zum Zitat Han Y, Xu Z, Gao C (2013) Ultrathin graphene nanofiltration membrane for water purification. Adv Funct Mater 23:3693–3700CrossRef Han Y, Xu Z, Gao C (2013) Ultrathin graphene nanofiltration membrane for water purification. Adv Funct Mater 23:3693–3700CrossRef
28.
Zurück zum Zitat Li G, Wang X, Tao L, Li Y, Quan K, Wei Y, Chi L, Yuan Q (2015) Cross-linked graphene membrane for high-performance organics separation of emulsions. J Membr Sci 495:439–444CrossRef Li G, Wang X, Tao L, Li Y, Quan K, Wei Y, Chi L, Yuan Q (2015) Cross-linked graphene membrane for high-performance organics separation of emulsions. J Membr Sci 495:439–444CrossRef
29.
Zurück zum Zitat Jiang Y, Wang WN, Liu D, Nie Y, Li W, Wu J, Zhang F, Biswas P, Fortner JD (2015) Engineered crumpled graphene oxide nanocomposite membrane assemblies for advanced water treatment processes. Environ Sci Technol 49:6846–6854CrossRef Jiang Y, Wang WN, Liu D, Nie Y, Li W, Wu J, Zhang F, Biswas P, Fortner JD (2015) Engineered crumpled graphene oxide nanocomposite membrane assemblies for advanced water treatment processes. Environ Sci Technol 49:6846–6854CrossRef
30.
Zurück zum Zitat Cui J, Xie A, Zhou S, Liu S, Wang Q, Wu Y, Meng M, Lang J, Zhou Z, Yan Y (2019) Development of composite membranes with irregular rod-like structure via atom transfer radical polymerization for efficient oil–water emulsion separation. J Colloid Interface Sci 533:278–286CrossRef Cui J, Xie A, Zhou S, Liu S, Wang Q, Wu Y, Meng M, Lang J, Zhou Z, Yan Y (2019) Development of composite membranes with irregular rod-like structure via atom transfer radical polymerization for efficient oil–water emulsion separation. J Colloid Interface Sci 533:278–286CrossRef
31.
Zurück zum Zitat Xia S, Ni M (2015) Preparation of poly(vinylidene fluoride) membranes with graphene oxide addition for natural organic matter removal. J Membr Sci 473:54–62CrossRef Xia S, Ni M (2015) Preparation of poly(vinylidene fluoride) membranes with graphene oxide addition for natural organic matter removal. J Membr Sci 473:54–62CrossRef
32.
Zurück zum Zitat Zhang J, Pan X, Xue Q, He D, Zhu L, Guo Q (2017) Antifouling hydrolyzed polyacrylonitrile/graphene oxide membrane with spindle-knotted structure for highly effective separation of oil–water emulsion. J Membr Sci 532:38–46CrossRef Zhang J, Pan X, Xue Q, He D, Zhu L, Guo Q (2017) Antifouling hydrolyzed polyacrylonitrile/graphene oxide membrane with spindle-knotted structure for highly effective separation of oil–water emulsion. J Membr Sci 532:38–46CrossRef
33.
Zurück zum Zitat Yu L, Zhang Y, Zhang H, Liu J (2015) Development of a molecular separation membrane for efficient separation of low-molecular-weight organics and salts. Desalination 359:176–185CrossRef Yu L, Zhang Y, Zhang H, Liu J (2015) Development of a molecular separation membrane for efficient separation of low-molecular-weight organics and salts. Desalination 359:176–185CrossRef
34.
Zurück zum Zitat Dai J, Zhang R, Ge W, Xie A, Chang Z, Tian S, Zhou Z, Yan Y (2018) 3D macroscopic superhydrophobic magnetic porous carbon aerogel converted from biorenewable popcorn for selective oil–water separation. Mater Des 139:122–131CrossRef Dai J, Zhang R, Ge W, Xie A, Chang Z, Tian S, Zhou Z, Yan Y (2018) 3D macroscopic superhydrophobic magnetic porous carbon aerogel converted from biorenewable popcorn for selective oil–water separation. Mater Des 139:122–131CrossRef
35.
Zurück zum Zitat Liu M, Jia Z, Jia D, Zhou C (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39:1498–1525CrossRef Liu M, Jia Z, Jia D, Zhou C (2014) Recent advance in research on halloysite nanotubes-polymer nanocomposite. Prog Polym Sci 39:1498–1525CrossRef
36.
Zurück zum Zitat Xie A, Dai J, Chen X, Ma P, He J, Li C, Zhou Z, Yan Y (2016) Ultrahigh adsorption of typical antibiotics onto novel hierarchical porous carbons derived from renewable lignin via halloysite nanotubes-template and in situ activation. Chem Eng J 304:609–620CrossRef Xie A, Dai J, Chen X, Ma P, He J, Li C, Zhou Z, Yan Y (2016) Ultrahigh adsorption of typical antibiotics onto novel hierarchical porous carbons derived from renewable lignin via halloysite nanotubes-template and in situ activation. Chem Eng J 304:609–620CrossRef
37.
Zurück zum Zitat Liu Y, Tu W, Chen M, Ma L, Yang B, Liang Q, Chen Y (2017) A mussel-induced method to fabricate reduced graphene oxide/halloysite nanotubes membranes for multifunctional applications in water purification and oil/water separation. Chem Eng J 336:263–277CrossRef Liu Y, Tu W, Chen M, Ma L, Yang B, Liang Q, Chen Y (2017) A mussel-induced method to fabricate reduced graphene oxide/halloysite nanotubes membranes for multifunctional applications in water purification and oil/water separation. Chem Eng J 336:263–277CrossRef
38.
Zurück zum Zitat Chen Y, Zhang Y, Zhang H, Liu J, Song C (2013) Biofouling control of halloysite nanotubes-decorated polyethersulfone ultrafiltration membrane modified with chitosan-silver nanoparticles. Chem Eng J 228:12–20CrossRef Chen Y, Zhang Y, Zhang H, Liu J, Song C (2013) Biofouling control of halloysite nanotubes-decorated polyethersulfone ultrafiltration membrane modified with chitosan-silver nanoparticles. Chem Eng J 228:12–20CrossRef
39.
Zurück zum Zitat Xie A, Chen Y, Cui J, Lang J, Li C, Yan Y, Dai J (2019) Facile and green fabrication of superhydrophobic sponge for continuous oil/water separation from harsh environments. Colloid Surf A 563:120–129CrossRef Xie A, Chen Y, Cui J, Lang J, Li C, Yan Y, Dai J (2019) Facile and green fabrication of superhydrophobic sponge for continuous oil/water separation from harsh environments. Colloid Surf A 563:120–129CrossRef
40.
Zurück zum Zitat Ma L, Qin H, Cheng C, Xia Y, He C, Nie C, Wang L, Zhao C (2013) Mussel-inspired self-coating at macro-interface with improved biocompatibility and bioactivity via dopamine grafted heparin-like polymers and heparin. J Mater Chem B 2:363–375CrossRef Ma L, Qin H, Cheng C, Xia Y, He C, Nie C, Wang L, Zhao C (2013) Mussel-inspired self-coating at macro-interface with improved biocompatibility and bioactivity via dopamine grafted heparin-like polymers and heparin. J Mater Chem B 2:363–375CrossRef
41.
Zurück zum Zitat Cheng C, Sun S, Zhao C (2014) Progress in heparin and heparin-like/mimicking polymer-functionalized biomedical membranes. J Mater Chem B 2:7649–7672CrossRef Cheng C, Sun S, Zhao C (2014) Progress in heparin and heparin-like/mimicking polymer-functionalized biomedical membranes. J Mater Chem B 2:7649–7672CrossRef
42.
Zurück zum Zitat Cheng C, Li S, Zhao J, Li X, Liu Z, Ma L, Zhang X, Sun S, Zhao C (2013) Biomimetic assembly of polydopamine-layer on graphene: mechanisms, versatile 2D and 3D architectures and pollutant disposal. Chem Eng J 228:468–481CrossRef Cheng C, Li S, Zhao J, Li X, Liu Z, Ma L, Zhang X, Sun S, Zhao C (2013) Biomimetic assembly of polydopamine-layer on graphene: mechanisms, versatile 2D and 3D architectures and pollutant disposal. Chem Eng J 228:468–481CrossRef
43.
Zurück zum Zitat Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1399CrossRef Hummers WS, Offeman RE (1958) Preparation of graphitic oxide. J Am Chem Soc 80:1399CrossRef
44.
Zurück zum Zitat Cai Y, Chen D, Li N, Xu Q, Li H, He J, Lu J (2017) Nanofibrous metal–organic framework composite membrane for selective efficient oil/water emulsion separation. J Membr Sci 543:10–17CrossRef Cai Y, Chen D, Li N, Xu Q, Li H, He J, Lu J (2017) Nanofibrous metal–organic framework composite membrane for selective efficient oil/water emulsion separation. J Membr Sci 543:10–17CrossRef
45.
Zurück zum Zitat Liu Y, Su Y, Cao J, Guan J, Zhang R, He M, Fan L, Zhang Q, Jiang Z (2017) Antifouling, high-flux oil/water separation carbon nanotube membranes by polymer-mediated surface charging and hydrophilization. J Membr Sci 542:254–263CrossRef Liu Y, Su Y, Cao J, Guan J, Zhang R, He M, Fan L, Zhang Q, Jiang Z (2017) Antifouling, high-flux oil/water separation carbon nanotube membranes by polymer-mediated surface charging and hydrophilization. J Membr Sci 542:254–263CrossRef
46.
Zurück zum Zitat Wang M, Liu G, Yu H, Lee SH, Wang L, Zheng J, Wang T, Yun Y, Lee JK (2018) ZnO nanorod array modified PVDF membrane with superhydrophobic surface for vacuum membrane distillation application. ACS Appl Mater Interfaces 10:13452–13461CrossRef Wang M, Liu G, Yu H, Lee SH, Wang L, Zheng J, Wang T, Yun Y, Lee JK (2018) ZnO nanorod array modified PVDF membrane with superhydrophobic surface for vacuum membrane distillation application. ACS Appl Mater Interfaces 10:13452–13461CrossRef
47.
Zurück zum Zitat Wang J, Wang H (2018) Easily enlarged and coating-free underwater superoleophobic fabric for oil/water and emulsion separation via a facile NaClO2 treatment. Sep Purif Technol 195:358–366CrossRef Wang J, Wang H (2018) Easily enlarged and coating-free underwater superoleophobic fabric for oil/water and emulsion separation via a facile NaClO2 treatment. Sep Purif Technol 195:358–366CrossRef
Metadaten
Titel
Facile preparation of halloysite nanotube-modified polyvinylidene fluoride composite membranes for highly efficient oil/water emulsion separation
verfasst von
Qianqian Wang
Jiuyun Cui
Siwei Liu
Jia Gao
Jihui Lang
Chunxiang Li
Yongsheng Yan
Publikationsdatum
27.02.2019
Verlag
Springer US
Erschienen in
Journal of Materials Science / Ausgabe 11/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI
https://doi.org/10.1007/s10853-019-03482-z

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