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Journal of Materials Science

Erschienen in:

21.06.2019 | Chemical routes to materials

A novel two-stage synthesis for 3C–SiC nanowires by carbothermic reduction and their photoluminescence properties

verfasst von: Zhouzhou Shen, Junhong Chen, Bin Li, Guangqi Li, Jingwei Li, Xinmei Hou

Erschienen in: Journal of Materials Science | Ausgabe 19/2019

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Abstract

A large quantity of 3C–SiC nanowires (SiCnws) with high purity were fabricated via carbothermic reduction method combined with a novel two-stage temperature program. At the first temperature stage, the reactants were kept at 1600 °C for 4 h to promote the formation of SiC nucleus and SiO intermediate gas. Then they were cooled to 1350 °C for 2 h at the second stage for the growth of SiCnws with fewer defects. Compared with the conventional single temperature method at 1600 °C for 6 h, the product prepared by this new strategy exhibits large yield and high purity with a narrow diameter range. As for the reaction mechanism, “solid–solid” and “solid–vapor” reactions occurring between SiO₂, SiO and C dominate at the first stage. While “vapor–vapor” reaction between SiO and CO plays an important role at the second stage. Furthermore, photoluminescence (PL) properties were measured under the room temperature. A sharp violet light emission peak with a significant blue shift is observed at 401 nm compared to bulk 3C–SiC.

Vorheriger Artikel Effect of Al substrate microstructure on layered double hydroxide morphology

Nächster Artikel Preparation of oxygen-deficient 2D WO3−x nanoplates and their adsorption behaviors for organic pollutants: equilibrium and kinetics modeling

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Titel: A novel two-stage synthesis for 3C–SiC nanowires by carbothermic reduction and their photoluminescence properties
verfasst von: Zhouzhou Shen
Junhong Chen
Bin Li
Guangqi Li
Jingwei Li
Xinmei Hou
Publikationsdatum: 21.06.2019
Verlag: Springer US
Erschienen in: Journal of Materials Science / Ausgabe 19/2019
Print ISSN: 0022-2461
Elektronische ISSN: 1573-4803
DOI: https://doi.org/10.1007/s10853-019-03749-5

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